Advanced search
Publication Cover
Molecular Physics
An International Journal at the Interface Between Chemistry and Physics
Volume 42, 1981 - Issue 4
Submit an article Journal homepage
34
Views
40
CrossRef citations to date
0
Altmetric
Original Articles

Theory of fluids of non-axial quadrupolar molecules

I. Thermodynamic properties

K.E. Gubbins Physical Chemistry Laboratory, South Parks Road, Oxford, OX1 3QZ, England; School of Chemical Engineering, Cornell University, Ithaca, New York, 14853, U.S.A.
,
C.G. Gray Department of Physics, University of Guelph, Guelph, Ontario, Canada
&
J.R.S. Machado School of Chemical Engineering, Cornell University, Ithaca, New York, 14853, U.S.A.
Pages 817-841 | Received 20 May 1980, Accepted 18 Sep 1980, Published online: 23 Aug 2006

Citations (40)

Keep up to date with the latest research on this topic with citation updates for this article.

Subscribe to citation updates

Read on this site (6)

KeithE. Gubbins. (2013) The theory of non-electrolyte solutions: an historical review. Molecular Physics 111:24, pages 3666-3697.
Read now
PETERT. CUMMINGS, GEORGE JACKSON & JOHNS. ROWLINSON. (2002) Keith E. Gubbins: A celebration of statistical mechanics. Molecular Physics 100:13, pages 2003-2016.
Read now
T. KRASKA. (1997) The structure and volume of ion clusters in the restricted primitive model. Molecular Physics 90:2, pages 165-177.
Read now
C.G. Joslin, C.G. Gray & K.E. Gubbins. (1985) Renormalized perturbation theory for dipolar and quadrupolar polarizable liquids. Molecular Physics 54:5, pages 1117-1128.
Read now
S.L. Carnie & G.N. Patey. (1982) Fluids of polarizable hard spheres with dipoles and tetrahedral quadrupoles Integral equation results with application to liquid water. Molecular Physics 47:5, pages 1129-1151.
Read now
C.G. Gray & K.E. Gubbins. (1981) Theory of fluids of non-axial quadrupolar molecules. Molecular Physics 42:4, pages 843-860.
Read now

Articles from other publishers (34)

Zoltán Szakács, Mariusz Tasior, Daniel T. Gryko & Eric Vauthey. (2020) Change of Quadrupole Moment upon Excitation and Symmetry Breaking in Multibranched Donor‐Acceptor Dyes. ChemPhysChem 21:15, pages 1718-1730.
Crossref
Taylor A. Barnes, Jakub W. Kaminski, Oleg Borodin & Thomas F. MillerIIIIII. (2015) Ab Initio Characterization of the Electrochemical Stability and Solvation Properties of Condensed-Phase Ethylene Carbonate and Dimethyl Carbonate Mixtures . The Journal of Physical Chemistry C 119:8, pages 3865-3880.
Crossref
Clare McCabe & Amparo Galindo. 2010. Applied Thermodynamics of Fluids. Applied Thermodynamics of Fluids 215 279 .
Dong Nguyen-Huynh, T. K. S. Tran, S. Tamouza, J.-P. Passarello, P. Tobaly & J.-C. de Hemptinne. (2008) Modeling Phase Equilibria of Asymmetric Mixtures Using a Group-Contribution SAFT (GC-SAFT) with a k ij Correlation Method Based on Londonʼs Theory. 2. Application to Binary Mixtures Containing Aromatic Hydrocarbons, n -Alkanes, CO 2 , N 2 , and H 2 S . Industrial & Engineering Chemistry Research 47:22, pages 8859-8868.
Crossref
D. NguyenHuynh, J.-P. Passarello, P. Tobaly & J.-C. de Hemptinne. (2008) Application of GC-SAFT EOS to polar systems using a segment approach. Fluid Phase Equilibria 264:1-2, pages 62-75.
Crossref
A. J. Palace Carvalho, J. P. Prates Ramalho & Luís F. G. Martins. (2007) Excess Thermodynamics of Mixtures Involving Xenon and Light Linear Alkanes by Computer Simulation. The Journal of Physical Chemistry B 111:23, pages 6437-6443.
Crossref
Jonggu Jeon & Hyung J. Kim. (2003) A continuum theory of solvation in quadrupolar solvents. I. Formulation. The Journal of Chemical Physics 119:16, pages 8606-8625.
Crossref
M. B. Zimmt & D. H. Waldeck. (2003) Exposing Solvent's Roles in Electron Transfer Reactions:  Tunneling Pathway and Solvation. The Journal of Physical Chemistry A 107:19, pages 3580-3597.
Crossref
Mazdak Khajehpour & John F. Kauffman. (2000) Emission Peak Shifts of a Dipolar Solute Dissolved in Nondipolar Solvents:  A Quantitative Measure of Quadrupole−Dipole Interactions in Supercritical CO 2 . The Journal of Physical Chemistry A 104:42, pages 9512-9517.
Crossref
I. Read, A. Napper, M. B. Zimmt & D. H. Waldeck. (2000) Electron Transfer in Aromatic Solvents:  The Importance of Quadrupolar Interactions. The Journal of Physical Chemistry A 104:41, pages 9385-9394.
Crossref
Kenji Kamada, Minoru Ueda, Koji Ohta, Yan Wang, Kiminori Ushida & Yasunori Tominaga. (1998) Molecular dynamics of thiophene homologues investigated by femtosecond optical Kerr effect and low frequency Raman scattering spectroscopies. The Journal of Chemical Physics 109:24, pages 10948-10957.
Crossref
L. Reynolds, J. A. Gardecki, S. J. V. Frankland, M. L. Horng & M. Maroncelli. (1996) Dipole Solvation in Nondipolar Solvents:  Experimental Studies of Reorganization Energies and Solvation Dynamics. The Journal of Physical Chemistry 100:24, pages 10337-10354.
Crossref
Yong Joon Chang & Edward W. Castner. (1996) Intermolecular Dynamics of Substituted Benzene and Cyclohexane Liquids, Studied by Femtosecond Nonlinear-Optical Polarization Spectroscopy. The Journal of Physical Chemistry 100:9, pages 3330-3343.
Crossref
Keshawa Shukla. (1994) Phase equilibria and thermodynamic properties of molecular fluids from perturbation theory. Fluid Phase Equilibria 94, pages 19-49.
Crossref
Klaus LucasKlaus Lucas. 1991. Applied Statistical Thermodynamics. Applied Statistical Thermodynamics 446 508 .
Klaus LucasKlaus Lucas. 1991. Applied Statistical Thermodynamics. Applied Statistical Thermodynamics 309 445 .
J. Winkelmann. (1989) Application of perturbation theory to VLE calculation for dipolar/quadrupolar fluids. Fluid Phase Equilibria 48, pages 67-81.
Crossref
Lloyd L. Lee. 1988. Molecular Thermodynamics of Nonideal Fluids. Molecular Thermodynamics of Nonideal Fluids 297 330 .
Ratan Mohan, D. Prahlada Rao & S.V. Babu. (1986) Equation of state calculations for CO2, C2H4 and N2 using perturbation theory. Effect of damping the quadrupole—quadrupole and induced-quadrupole series at small intermolecular separations. Fluid Phase Equilibria 25:2, pages 171-193.
Crossref
Klaus LucasKlaus Lucas. 1986. Angewandte Statistische Thermodynamik. Angewandte Statistische Thermodynamik 419 491 .
Klaus LucasKlaus Lucas. 1986. Angewandte Statistische Thermodynamik. Angewandte Statistische Thermodynamik 306 418 .
Maxwell L McGlashan. (1985) Phase equilibria in fluid mixtures. The Journal of Chemical Thermodynamics 17:4, pages 301-319.
Crossref
K.E. Gubbins. (1985) Theory and computer simulation studies of liquid mixtures. Fluid Phase Equilibria 20, pages 1-25.
Crossref
S. Murad, C.G. Gray, K.E. Gubbins & S.M. Thompson. (1984) The effect of non-axial quadrupole forces on the anisotropy of mean-squared force and torque. Chemical Physics Letters 104:4, pages 407-408.
Crossref
K.P. Shukla, K. Lucas & B. Moser. (1984) Molecular thermodynamics on the basis of an equation of state for argon. III. Systems of appreciably nonspherical linear molecules. Fluid Phase Equilibria 17:2, pages 153-186.
Crossref
K.P. Shukla, K. Lucas & B. Moser. (1983) Molecular thermodynamics on the basis of an equation of state for argon. I. Pure fluids of weakly nonspherical molecules. Fluid Phase Equilibria 15:2, pages 125-172.
Crossref
S. Singh, U.P. Singh & Y. Singh. (1983) Perturbation theory for non-axial molecular fluids. Physica A: Statistical Mechanics and its Applications 121:3, pages 563-575.
Crossref
C.G. Gray, K.E. Gubbins, S. Murad & K.S. Shing. (1983) The effect of non-axial quadrupole forces on liquid properties. Chemical Physics Letters 95:6, pages 541-543.
Crossref
Keith E. Gubbins. (1983) Equations of state - new theories. Fluid Phase Equilibria 13, pages 35-57.
Crossref
C.G. Joslin. (1982) The dielectric constant of water: influence of the quadrupole moment. Chemical Physics Letters 91:6, pages 452-455.
Crossref
J S Rowlinson & F L Swinton. 1982. Liquids and Liquid Mixtures. Liquids and Liquid Mixtures 279 315 .
J S Rowlinson & F L Swinton. 1982. Liquids and Liquid Mixtures. Liquids and Liquid Mixtures 230 278 .
Sohail Murad. (1981) Second-order perturbation theory for the angular correlation function of non-linear molecules. Chemical Physics Letters 84:1, pages 114-118.
Crossref
J. S. Rowlinson. (2010) Molecular Theory of Liquids and Liquid Mixtures. Berichte der Bunsengesellschaft für physikalische Chemie 85:11, pages 970-979.
Crossref

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Order Reprints Request Corporate Permissions

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

Request Academic Permissions

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.

Related research

People also read lists articles that other readers of this article have read.

Recommended articles lists articles that we recommend and is powered by our AI driven recommendation engine.

Cited by lists all citing articles based on Crossref citations.
Articles with the Crossref icon will open in a new tab.