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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 39, 2009 - Issue 17
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Original Articles

Green, Catalyst-Free Protocol for the Efficient Synthesis of N-Sulfonyl Aldimines and Ketimines in Ionic Liquid [Bmim]Br

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Pages 3156-3165 | Received 07 Dec 2008, Published online: 03 Aug 2009

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Read on this site (7)

Shrikant M. Ghodse & Pallavi D. Barde. (2023) Catalyst free, one-pot green synthesis of 2-aryl-2-oxazoline derivatives from aryl nitrile using ionic liquid. Synthetic Communications 53:19, pages 1616-1622.
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Abderrehmane Djemili, Salah Lakrout, Zinelaabidine Cheraiet, Malika Berredjem & Nour-Eddine Aouf. (2015) A simple and highly efficient solvent- and catalyst-free synthesis of novel N-sulfamoyl imines. Green Chemistry Letters and Reviews 8:1, pages 48-53.
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Ahmad Reza Moosavi-Zare, Mohammad Ali Zolfigol, Ehsan Noroozizadeh, Vahid Khakyzadeh, Abdolkarim Zare & Mahsa Tavasoli. (2014) Di-Sulfonic Acid Imidazolium Chloroaluminate, Efficiently Catalyzed the Synthesis of N-Sulfonyl Imines in Solventless Media with High TOF. Phosphorus, Sulfur, and Silicon and the Related Elements 189:2, pages 149-156.
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Alireza Hasaninejad, Abdolkarim Zare, Mohsen Shekouhy & Nooshin Golzar. (2011) Efficient Synthesis of 4,4′-(Arylmethylene)-bis(3-methyl-1-phenylpyrazol-5-ol) Derivatives in PEG-400 under Catalyst-free Conditions. Organic Preparations and Procedures International 43:1, pages 131-137.
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Liqiang Wu, Xiaojuan Yang, Xiao Wang & Fulin Yan. (2010) Cyanuric chloride-catalyzed synthesis of N-sulfonyl imines. Journal of Sulfur Chemistry 31:6, pages 509-513.
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Alireza Hasaninejad, Abdolkarim Zare, Mohammad Reza Mohammadizadeh & Mohsen Shekouhy. (2010) Lithium bromide as an efficient, green, and inexpensive catalyst for the synthesis of quinoxaline derivatives at room temperature. Green Chemistry Letters and Reviews 3:2, pages 143-148.
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Mohammad Ali Zolfigol, Ardeshir Khazaei, Ahmad Reza Moosavi-Zare & Abdolkarim Zare. (2010) Ionic Liquid 3-Methyl-1-sulfonic Acid Imidazolium Chloride as a Novel and Highly Efficient Catalyst for the Very Rapid Synthesis of bis(Indolyl)methanes under Solvent-free Conditions. Organic Preparations and Procedures International 42:1, pages 95-102.
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Articles from other publishers (25)

Ahmad Reza Moosavi-Zare, Mohammad Rezaei-Gohar, Mahsa Tavasoli & Hamid Goudarziafshar. (2023) [Pyridine–SO3H]ZnCl3: A Multipurpose Catalyst for A3 Coupling Synthesis of Propargylamines under Mild Conditions. Synlett 35:07, pages 816-820.
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Muhammad Siddique Ahmad & Atique Ahmad. (2021) Cu-catalyzed cyanomethylation of imines and α,β-alkenes with acetonitrile and its derivatives. RSC Advances 11:10, pages 5427-5431.
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Jahanbakhsh Ashtarian, Reza Heydari, Malek-Taher Maghsoodlou & Afshin Yazdani-Elah-Abadi. (2019) Bronsted Acidic Ionic Liquids (BAILs)-Catalyzed Synthesis of 1,8-Dioxo-Octahydroxanthene and 2,2′-Arylmethylene Bis(3-Hydroxy-5,5-Dimethyl-2-Cyclohexene-1-One) Derivatives Under Eco-Friendly Conditions. Iranian Journal of Science and Technology, Transactions A: Science 44:1, pages 51-64.
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Eshagh Rezaee Nezhad, Sami Sajjadifar, Fariba Heidarizadeh & Saaid Karimian. (2019) Task specific ionic liquid as solvent, catalyst and reagent for regioselective ring opening of epoxides in water. Arabian Journal of Chemistry 12:8, pages 2098-2103.
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Hanan A. Soliman, Mahmoud El-Shahat & Abdel-Ghany Soliman. (2019) Silica-supported Zinc Chloride (ZnCl2/SiO2)-induced Efficient Protocol for the Synthesis of N-sulfonyl imines and 2-Arylbenzothiazole. Letters in Organic Chemistry 16:7, pages 584-591.
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Navjeet Kaur. (2019) Ionic Liquids: A Versatile Medium for the Synthesis of Six-membered Two Nitrogen- Containing Heterocycles. Current Organic Chemistry 23:1, pages 76-96.
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Ahmad Reza Moosavi-Zare, Mohammad Ali Zolfigol, Ehsan Noroozizadeh, Mahmoud Zarei, Roya Karamian & Mostafa Asadbegy. (2016) Synthesis and characterization of acetic acid functionalized poly (4-vinylpyridinium) salt as new catalyst for the synthesis of spiropyran derivatives and their biological activity. Journal of Molecular Catalysis A: Chemical 425, pages 217-228.
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Sobhan Rezayati, Elaheh Salehi, Rahimeh Hajinasiri & Saeid Afshari Sharif Abad. (2016) Acetic acid functionalized ionic liquid systems: An efficient and recyclable catalyst for the regioselective ring opening of epoxides with NaN3. Comptes Rendus. Chimie 20:5, pages 554-558.
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Ahmad Reza Moosavi-Zare, Mohammad Ali Zolfigol, Ehsan Noroozizadeh, Omid Khaledian & Behzad Shirmardi Shaghasemi. (2015) Cyclocondensation-Knoevenagel–Michael Domino reaction of phenyl hydrazine, acetoacetate derivatives and aryl aldehydes over acetic acid functionalized ionic liquid. Research on Chemical Intermediates 42:5, pages 4759-4772.
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Pablo Ortiz, Juan F. Collados & Syuzanna R. Harutyunyan. (2016) Direct Synthesis of Enolizable N ‐Sulfonyl Ketimines Under Microwave Irradiation . European Journal of Organic Chemistry 2016:7, pages 1247-1250.
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Ahmad Reza Moosavi-Zare, Mohammad Ali Zolfigol, Omid Khaledian, Vahid Khakyzadeh, Majid Darestani farahani, Mohammad Hassan Beyzavi & Hendrik Gerhardus Kruger. (2014) Tandem Knoevenagel–Michael–cyclocondensation reaction of malononitrile, various aldehydes and 2-naphthol over acetic acid functionalized ionic liquid. Chemical Engineering Journal 248, pages 122-127.
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Ahmad Reza Moosavi-Zare, Mohammad Ali Zolfigol, Omid Khaledian & Vahid Khakyzadeh. (2014) Condensation of 2-naphtol with arylaldehydes using acetic acid functionalized ionic liquids as highly efficient and reusable catalysts. Chinese Journal of Catalysis 35:4, pages 573-578.
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Ahmad Reza Moosavi-Zare, Mohammad Ali Zolfigol, Omid Khaledian, Vahid Khakyzadeh, Majid Darestani Farahani & Hendrik Gerhardus Kruger. (2014) Tandem Knoevenagel–Michael-cyclocondensation reactions of malononitrile, various aldehydes and dimedone using acetic acid functionalized ionic liquid. New Journal of Chemistry 38:6, pages 2342.
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Daqing Li, Hongjun Zang, Changchun Wu & NianQin Yu. (2013) 1-Methylimidazolium hydrogen sulfate catalyzed convenient synthesis of 2,5-dimethyl-N-substituted pyrroles under ultrasonic irradiation. Ultrasonics Sonochemistry 20:5, pages 1144-1148.
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Mohammad Ali Zolfigol, Mahsa Tavasoli, Ahmad Reza Moosavi-Zare, Parastoo Arghavani-Hadi, Abdolkarim Zare & Vahid Khakyzadeh. (2013) Solvent-free synthesis of N-sulfonyl imines using WCl6 as a novel, highly efficient and reusable catalyst. RSC Advances 3:21, pages 7692.
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Farhad Shirini, Nader Ghaffari Khaligh & Somayeh Akbari-Dadamahaleh. (2012) Preparation, characterization and use of 1,3-disulfonic acid imidazolium hydrogen sulfate as an efficient, halogen-free and reusable ionic liquid catalyst for the trimethylsilyl protection of hydroxyl groups and deprotection of the obtained trimethylsilanes. Journal of Molecular Catalysis A: Chemical 365, pages 15-23.
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Mohammad Ali Zolfigol, Vahid Khakyzadeh, Ahmad Reza Moosavi-Zare, Abdolkarim Zare, Seyedeh Bahareh Azimi, Zhila Asgari & Alireza Hasaninejad. (2012) Preparation of various xanthene derivatives over sulfonic acid functionalized imidazolium salts (SAFIS) as novel, highly efficient and reusable catalysts. Comptes Rendus. Chimie 15:8, pages 719-736.
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Abdolkarim Zare, Ahmad Reza Moosavi-Zare, Maria Merajoddin, Mohammad Ali Zolfigol, Tahereh Hekmat-Zadeh, Alireza Hasaninejad, Ardeshir Khazaei, Mohammad Mokhlesi, Vahid Khakyzadeh, Fatemeh Derakhshan-Panah, Mohammad Hassan Beyzavi, Esmael Rostami, Azam Arghoon & Razieh Roohandeh. (2012) Ionic liquid triethylamine-bonded sulfonic acid {[Et3N–SO3H]Cl} as a novel, highly efficient and homogeneous catalyst for the synthesis of β-acetamido ketones, 1,8-dioxo-octahydroxanthenes and 14-aryl-14H-dibenzo[a,j]xanthenes. Journal of Molecular Liquids 167, pages 69-77.
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A. Khazaei, M.A. Zolfigol, A.R. Moosavi-Zare, A. Zare, E. Ghaemi, V. Khakyzadeh, Zh. Asgari & A. Hasaninejad. (2011) Sulfonic acid functionalized imidazolium salts/ FeCl3 as novel and highly efficient catalytic systems for the synthesis of benzimidazoles at room temperature. Scientia Iranica 18:6, pages 1365-1371.
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Nader Ghaffari Khaligh. (2011) Preparation, characterization and use of 3-methyl-1-sulfonic acid imidazolium hydrogen sulfate as an eco-benign, efficient and reusable ionic liquid catalyst for the chemoselective trimethylsilyl protection of hydroxyl groups. Journal of Molecular Catalysis A: Chemical 349:1-2, pages 63-70.
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Mohammad Ali Zolfigol, Ardeshir Khazaei, Ahmad Reza Moosavi-Zare, Abdolkarim Zare & Vahid Khakyzadeh. (2011) Rapid synthesis of 1-amidoalkyl-2-naphthols over sulfonic acid functionalized imidazolium salts. Applied Catalysis A: General 400:1-2, pages 70-81.
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A. Zare, A. Hasaninejad, A. Salimi Beni, A.R. Moosavi-Zare, M. Merajoddin, E. Kamali, M. Akbari-Seddigh & Z. Parsaee. (2011) Ionic liquid 1-butyl-3-methylimidazolium bromide ([Bmim]Br) as a green and neutral reaction media for the catalyst-free synthesis of 1-amidoalkyl-2-naphthols. Scientia Iranica.
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Abolghasem Davoodnia, Mehdi Bakavoli, Raheleh Moloudi, Niloofar Tavakoli-Hoseini & Maryam Khashi. (2010) Highly efficient, one-pot, solvent-free synthesis of 2,4,6-triarylpyridines using a Brønsted-acidic ionic liquid as reusable catalyst. Monatshefte für Chemie - Chemical Monthly 141:8, pages 867-870.
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Abdolkarim Zare, Ahmad Reza Moosavi‐Zare, Alireza Hasaninejad, Abolfath Parhami, Ali Khalafi‐Nezhad & Mohammad Hassan Beyzavi. (2009) ChemInform Abstract: Green, Catalyst‐Free Protocol for the Efficient Synthesis of N‐Sulfonyl Aldimines and Ketimines in Ionic Liquid [Bmim]Br.. ChemInform 41:3.
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Abdolkarim Zare, Alireza Hasaninejad, Abolfath Parhami, Ahmad Moosavi-ZareRezaReza, Fatemeh Khedri, Zahra Parsaee, Maasoomeh Abdolalipoor-Saretoli, Maasoomeh Khedri, Mehrnoosh Roshankar & Hanafieh Deisi. (2010) Ionic liquid 1-butyl-3-methylimidazolium bromide ([bmim]Br): A green and neutral reaction media for the efficient, catalyst-free synthesis of quinoxaline derivatives. Journal of the Serbian Chemical Society 75:10, pages 1315-1324.
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