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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 40, 2010 - Issue 6
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Original Articles

Mild and Efficient Method for α-Thiocyanation of Ketones and β-Dicarbonyl Compounds Using Bromodimethylsulfonium Bromide–Ammonium Thiocyanate

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Pages 799-807 | Received 25 Nov 2008, Published online: 22 Feb 2010

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Read on this site (7)

K. Uma, H. S. Lalithamba, V. Chandramohan & K. Lingaraju. (2019) A Facile Synthesis of Hydroxamic Acids of N-Protected Amino Acids Employing BDMS, a Study of Their Molecular Docking and Their Antibacterial Activities. Organic Preparations and Procedures International 51:2, pages 161-174.
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Rajesh H. Vekariya & Hitesh D. Patel. (2017) α-thiocyanation of carbonyl compounds: A review. Synthetic Communications 47:2, pages 87-104.
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Kobra Nikoofar & Samareh Gorji. (2016) Oxidant-free thiocyanation of phenols and carbonyl compounds under solvent-free conditions by AlCl3/NH4SCN. Journal of Sulfur Chemistry 37:1, pages 80-88.
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MoustafaA. Gouda. (2013) 1-Phenyl-2-thiocyanatoethanone as Synthons in Heterocyclic Synthesis. Synthetic Communications 43:19, pages 2547-2574.
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Mohammad Ali Karimi Zarchi & Nahid Ebrahimi. (2012) An Efficient and Simple Method for Diazotization-Thiocyanation of Aryl Amine using Cross-Linked Poly (4-Vinylpyridine) Supported Thiocyanate Ion. Phosphorus, Sulfur, and Silicon and the Related Elements 187:10, pages 1226-1235.
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Liqiang Wu & Xiaojuan Yang. (2012) Efficient α-Thiocyanation of Ketones Using Pyridinium Hydrobromide Perbromide. Phosphorus, Sulfur, and Silicon and the Related Elements 187:6, pages 748-753.
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Liqiang Wu, Xiaojuan Yang & Fulin Yan. (2011) I2O5 as a mild, inexpensive, and environmentally benign oxidant for the α -thiocyanation of ketones. Journal of Sulfur Chemistry 32:2, pages 105-110.
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Articles from other publishers (12)

Yakun Wang, Jie Liu, Yingying Wang, Xiaoyu Du, Haojie Song, Lizhen Fang, Liqiang Wu & Tao Zhang. (2024) Visible-Light-Promoted Aerobic α-Thiocyanation of Carbonyl Compounds with Ammonium Thiocyanate. The Journal of Organic Chemistry 89:5, pages 3453-3470.
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Andrey S. Kirillov, Egor A. Semenov, Oleg V. Bityukov, Maria A. Kuznetsova, Valentina N. Demidova, Alexander N. Rogozhin, Alexei P. Glinushkin, Vera A. Vil’ & Alexander O. Terent'ev. (2023) An environmentally benign way to synthesize 2-thiocyano-1,3-dicarbonyl compounds with high antifungal activity: a key role of solvent. Organic & Biomolecular Chemistry 21:17, pages 3615-3622.
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Ye Yuan, Yibo Liu, HongLing Wang & Xiang Zhang. (2022) Fe(III)‐Mediated para ‐Selective Nucleophilic Thiocyanation and Oxidation Reactions, Access to Thiocyanated Amidophenols and Amidoquinones . ChemistrySelect 7:39.
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Nidhi Jangir, Shikha Agarwal & Dinesh K. Jangid. (2022) The Role of (BDMS) Bromodimethylsulfonium bromide as a Catalyst and Brominating Reagent: A Concise Overview. ChemistrySelect 7:27.
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Sobhan Rezayati & Ali Ramazani. (2020) A review on electrophilic thiocyanation of aromatic and heteroaromatic compounds. Tetrahedron 76:36, pages 131382.
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Indranirekha Saikia, Arun Jyoti Borah & Prodeep Phukan. (2016) Use of Bromine and Bromo-Organic Compounds in Organic Synthesis. Chemical Reviews 116:12, pages 6837-7042.
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Alexander O. Terent’ev, Mikhail Yu. Sharipov, Alexey P. Glinuskin, Igor B. Krylov, Darya V. Gaidarenko & Gennady I. Nikishin. (2016) Difference in α-thiocyanation of malonates, β-oxo esters and β-diketones with sodium thiocyanate and cerium(IV) ammonium nitrate. Mendeleev Communications 26:3, pages 226-227.
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Dariush Khalili. (2016) Graphene oxide: a promising carbocatalyst for the regioselective thiocyanation of aromatic amines, phenols, anisols and enolizable ketones by hydrogen peroxide/KSCN in water. New Journal of Chemistry 40:3, pages 2547-2553.
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DEZHEN WU, XIAOJUAN YANG & LIQIANG WU. (2012) SelectfluorTM: A novel and efficient reagent for the rapid α-thiocyanation of ketones. Journal of Chemical Sciences 124:4, pages 901-905.
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H.M. Meshram, Pramod B. Thakur, B. Madhu Babu & Vikas M. Bangade. (2012) A convenient, rapid, and general synthesis of α-oxo thiocyanates using clay supported ammonium thiocyanate. Tetrahedron Letters 53:14, pages 1780-1785.
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Shanshan Liu, Zhihao Guo, Yaqin Wang, Tianbao Wang & Liqiang Wu. (2011) Trichloroisocyanuric Acid as a Novel and Versatile Reagent for the Rapid α-Thiocyanation of Ketones. Bulletin of the Korean Chemical Society 32:10, pages 3760-3762.
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Dinesh S. Bhalerao & Krishnacharya G. Akamanchi. (2010) ChemInform Abstract: Mild and Efficient Method for α‐Thiocyanation of Ketones and β‐Dicarbonyl Compounds Using Bromodimethylsulfonium Bromide—Ammonium Thiocyanate.. ChemInform 41:31.
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