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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 13, 1983 - Issue 3
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Original Articles

The Use of the Alkali Metal Dianion of Methallyl Alcohol in the Synthesis of α-Methylene-δ-Valerolactones

Robert M. Carlson Department of Chemistry, University of Minnesota, Duluth, Minnesota, 55812
&
Linda L. White Department of Chemistry, University of Minnesota, Duluth, Minnesota, 55812
Pages 237-241 | Published online: 05 Dec 2006

Citations (21)

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Read on this site (3)

Tian Liu & RobertM. Carlson. (1993) The Preparation and Utilization of 2-Ethylallyl Alcohol Dianions in α-Alkylidene Lactone Synthesis. Synthetic Communications 23:10, pages 1437-1442.
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MariaM. Murta, MariangelaB. M. de Azevedo & AndrewE. Greene. (1993) An Improved Procedure for α-Methylenation of Lactones. Synthetic Communications 23:4, pages 495-503.
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F.K. Meyer, J.G. Drewett & R.M. Carlson. (1986) The Crotyl Alcohol Dianion: Addition Reactions. Synthetic Communications 16:3, pages 261-265.
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Articles from other publishers (18)

Richard C. LarockRichard C. Larock & Li Zhang. 2018. Comprehensive Organic Transformations. Comprehensive Organic Transformations 1 19 .
Richard C. LarockRichard C. Larock & Gilson Zeni. 2018. Comprehensive Organic Transformations. Comprehensive Organic Transformations 1 73 .
Richard C. LarockRichard C. Larock & Tuanli Yao. 2018. Comprehensive Organic Transformations. Comprehensive Organic Transformations 1 85 .
Min Shi, Feijun Wang, Mei-Xin Zhao & Yin WeiFei-jun Wang, Yin Wei & Min Shi. 2011. The Chemistry of the Morita-Baylis-Hillman Reaction. The Chemistry of the Morita-Baylis-Hillman Reaction 325 484 .
Łukasz Albrecht, Jakub Wojciechowski, Anna Albrecht, Wojciech M. Wolf, Anna Janecka, Kazimierz Studzian, Urszula Krajewska, Marek Różalski, Tomasz Janecki & Henryk Krawczyk. (2010) Synthesis and cytotoxic evaluation of β-alkyl or β-aryl-δ-methyl-α-methylene-δ-lactones. Comparison with the corresponding γ-lactones. European Journal of Medicinal Chemistry 45:2, pages 710-718.
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Łukasz Albrecht, Bo Richter, Henryk Krawczyk & Karl Anker Jørgensen. (2008) Enantioselective Organocatalytic Approach to α-Methylene-δ-lactones and δ-Lactams. The Journal of Organic Chemistry 73:21, pages 8337-8343.
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Xiaoyang Xia & Frédéric R. Leroux. 2001. Encyclopedia of Reagents for Organic Synthesis. Encyclopedia of Reagents for Organic Synthesis.
Yung-Son Hon, Yu-Wei Liu & Cheng-Han Hsieh. (2004) Dibromomethane as one-carbon source in organic synthesis: a versatile methodology to prepare the cyclic and acyclic α-methylene or α-keto acid derivatives from the corresponding terminal alkenes. Tetrahedron 60:22, pages 4837-4860.
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Henryk Krawczyk & Marcin Śliwiński. (2003) Self-catalytic Michael reaction of enolizable carbonyl compounds. A facile route to α-methylene-δ-valerolactones. Tetrahedron 59:46, pages 9199-9211.
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Robert M. Carlson. 2001. Encyclopedia of Reagents for Organic Synthesis. Encyclopedia of Reagents for Organic Synthesis.
Abderrazak Bachki, Larry R Falvello, Francisco Foubelo & Miguel Yus. (1997) Enantiomerically pure γ-oxidofunctionalised organolithium compounds from chiral oxetanes. Tetrahedron: Asymmetry 8:15, pages 2633-2643.
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. 1995. Comprehensive Organic Functional Group Transformations. Comprehensive Organic Functional Group Transformations 1147 1316 .
Timothy N. Birkinshaw. 1995. Comprehensive Organic Functional Group Transformations. Comprehensive Organic Functional Group Transformations 171 247 .
Manfred Schlosser. 1994. Organometallics in Synthesis. Organometallics in Synthesis 1 166 .
Charles M. Thompson & Diana L.C. Green. (1991) Recent advances in dianion chemistry. Tetrahedron 47:25, pages 4223-4285.
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Thérèse Cuvigny, Marc Julia & Christian Rolando. (1988) Alkylation du linalol sur les carbones C8 (et C6). Journal of Organometallic Chemistry 344:1, pages 9-28.
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Seiichi Takano, Masamichi Morimoto, Shigeki Satoh & Kunio Ogasawara. (1984) SYNTHESES OF PERILLENE AND ROSEFURAN FROM COMMON STARTING MATERIALS. Chemistry Letters 13:7, pages 1261-1262.
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R. M. CARLSON & L. L. WHITE. (2016) ChemInform Abstract: THE USE OF THE ALKALI METAL DIANION OF METHALLYL ALCOHOL IN THE SYNTHESIS OF α‐METHYLENE‐Δ‐VALEROLACTONES. Chemischer Informationsdienst 14:37.
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