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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 13, 1983 - Issue 3
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Original Articles

The Use of the Alkali Metal Dianion of Methallyl Alcohol in the Synthesis of α-Methylene-δ-Valerolactones

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Pages 237-241 | Published online: 05 Dec 2006

References

  • Carlson , R. M. 1978 . Tetrahedron Lett. , 2 : 111
  • Meyer , F. K. 1979 . “The Crotyl Alcohol Dianion in Organic Synthesis,” , M. S. Thesis U of Minnesota .
  • Carlson , R. M. , Hewetson , D. W. , Deeg , M. A. , Mix , G. R. and Liu , T-L. 1981 . Syn. Commun. , 11 ( 12 ) : 1017 In contrast to allylic alkoxides, and lead to subsequent “normal” ∞ anion formation, see; Giess, K-H., Seebach, D., and Seuring, B., Chem. Ber. 110, 1833 (1977); Seebach, D., Giess, K-H., and Pohmakotr, M., Angew. Chem. Int. Ed., 15, 437 (1976)
  • Dimmel , D. R. , Fu , W. Y. and Gharpure , S. B. 1976 . J. Org. Chem. , 41 : 3092 The presence of will not prohibit the formation of normal ∞ dianions if other stabilizing features are present, see
  • Crandall , J. K. and Clark , A. C. 1976 . J. Org. Chem. , : 4236 These results contrast with the reported vulnerability of allylic compounds to undergo addition reactions in the presence of organolithium compounds, see

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