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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 26, 1996 - Issue 3
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Original Articles

A Facile Route to Synthesize α,α′-bis(Substituted-benzylidene) Cycloalkanones Promoted by SmI3

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Pages 503-507 | Received 12 Jun 1995, Published online: 21 Aug 2006

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Read on this site (3)

Gholam Hossein Mahdavinia, Shahnaz Rostamizadeh, Ali Mohammad Amani & Maryam Mirzazadeh. (2012) NH4H2PO4/SiO2: a recyclable, efficient heterogeneous catalyst for crossed aldol condensation reaction. Green Chemistry Letters and Reviews 5:3, pages 255-281.
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Hassan Hazarkhani, Pradeep Kumar, Kadam Sachin Kondiram & IkhlasM. Shafi Gadwal. (2010) Highly Selective Claisen–Schmidt Condensation Catalyzed by Silica Chloride Under Solvent-Free Reaction Conditions. Synthetic Communications 40:19, pages 2887-2896.
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Xingliang Zheng & Yongmin Zhang. (2003) SmI3 Catalyzed Condensation of Aliphatic Cycloketones and Aldehydes in Ionic Liquid. Synthetic Communications 33:1, pages 161-165.
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Articles from other publishers (20)

Kulsum Bano, Archana Jain, Ratan Sarkar & Tarun K. Panda. (2020) Economically Viable and Efficient Catalysts for Esterification and Cross Aldol Condensation Reactions under Mild Conditions. ChemistrySelect 5:15, pages 4470-4477.
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Yufei Wu, Jie Hou, Yuliang Liu, Mingfu Zhang, Chen-Ho Tung & Yifeng Wang. (2016) Chemoselective Claisen–Schmidt bis-substitutional condensation catalyzed by an alkoxy-bridged dinuclear Ti(IV) cluster. Tetrahedron 72:12, pages 1511-1516.
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Assem Barakat, Hazem Ghabbour, Abdullah Al-Majid, Saied Soliman, M. Ali, Yahia Mabkhot, Mohammed Shaik & Hoong-Kun Fun. (2015) Synthesis, Spectroscopic Investigations (X-ray, NMR and TD-DFT), Antimicrobial Activity and Molecular Docking of 2,6-Bis(hydroxy(phenyl)methyl)cyclohexanone. Molecules 20:7, pages 13240-13263.
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Ali Amoozadeh, Eskandar Kolvari, Nadiya Koukabi & Somayeh Otokesh. (2015) Nanomagnetic‐supported Sulfonic Acid: Simple and Rapid Method for the Synthesis of α , α′ ‐Bis‐(substituted‐benzylidene) Cycloalkanones . Journal of the Chinese Chemical Society 62:6, pages 501-505.
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Nader Ghaffari Khaligh & Taraneh Mihankhah. (2013) Aldol condensations of a variety of different aldehydes and ketones under ultrasonic irradiation using poly(N-vinylimidazole) as a new heterogeneous base catalyst under solvent-free conditions in a liquid-solid system. Chinese Journal of Catalysis 34:12, pages 2167-2173.
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Kirat Rawal, Manish Kumar Mishra, Manish Dixit & Meka Srinivasarao. (2012) Microwave assisted solvent free synthesis of α,ά-bis (arylidene) cycloalkanones by sulfated zirconia catalyzed cross aldol condensation of aromatic aldehydes and cycloalkanones. Journal of Industrial and Engineering Chemistry 18:4, pages 1474-1481.
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A. F. M. Motiur Rahman, Roushown Ali, Yurngdong Jahng & Adnan A. Kadi. (2012) A Facile Solvent Free Claisen-Schmidt Reaction: Synthesis of α,α′-bis-(Substituted-benzylidene)cycloalkanones and α,α′-bis-(Substituted-alkylidene)cycloalkanones. Molecules 17:1, pages 571-583.
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Abderrahim Solhy, Walid Amer, Mohamed Karkouri, Rachid Tahir, Abdeslam El Bouari, Aziz Fihri, Mostapha Bousmina & Mohamed Zahouily. (2011) Bi-functional modified-phosphate catalyzed the synthesis of α-α′-(EE)-bis(benzylidene)-cycloalkanones: Microwave versus conventional-heating. Journal of Molecular Catalysis A: Chemical 336:1-2, pages 8-15.
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. (2009) Acetate-Promoted Aldol-Type Reaction: Scope and Reactivity of Acetates and Aldehydes. Bulletin of the Korean Chemical Society 30:4, pages 797-802.
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Li-Tao An, Jian-Ping Zou & Li-Li Zhang. (2008) Polymer-supported sulphonic acid catalyzed cross-aldol condensation: An expeditious synthesis of α,α′-bis(substituted benzylidene) cycloalkanones. Catalysis Communications 9:3, pages 349-354.
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Mohame D. A. Ameen & Essam, Kh. Ahmed. (2009) Iodine catalyzed synthesis of α,α'‐bis(substituted benzylidene)‐1‐carbethoxy‐4‐piperidone. Journal of Heterocyclic Chemistry 45:2, pages 579-581.
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A.F.M. Motiur Rahman, Byeong-Seon Jeong, Dong Hyeon Kim, Jung Ki Park, Eung Seok Lee & Yurngdong Jahng. (2007) A facile synthesis of α,α′-bis(substituted-benzylidene)-cycloalkanones and substituted-benzylidene heteroaromatics: utility of NaOAc as a catalyst for aldol-type reaction. Tetrahedron 63:11, pages 2426-2431.
Crossref
Lijun Zhang, Shaowu Wang, Enhong Sheng & Shuangliu Zhou. (2005) A solvent-free synthesis of α,α′-bis(substituted benzylidene) cycloalkanones catalyzed by lanthanide amides [(Me3Si)2N]3Ln(µ-Cl)Li(THF)3 under microwave irradiation. Green Chemistry 7:9, pages 683.
Crossref
Xueyuan Hu, Xuesen Fan, Xinying Zhang & Jianji Wang. (2019) InCl 3 ·4H 2 O/TMSCl-Catalysed Aldol Reaction of Aromatic Aldehydes with Cycloalkanones in Ionic Liquid Medium . Journal of Chemical Research 2004:10, pages 684-686.
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Xingliang Zheng & Yongmin Zhang. (2019) SmI 3 mediated reginospecific Michael addition of ω-bromo-acetophenone to α,β-unsaturated alkynones . Journal of Chemical Research 2004:6, pages 412-413.
Crossref
Yulin Zhu & Yuanjiang Pan. (2004) A New Lewis Acid System Palladium/TMSCl for Catalytic Aldol Condensation of Aldehydes with Ketones. Chemistry Letters 33:6, pages 668-669.
Crossref
Yongjun Liu & Yongmin Zhang. (2003) Formation of 1,4-diketones via bis-acylation of the conjugated carbon–carbon double bonds in acrylates, acrylamides, methyl vinyl ketone and styrenes with aroyl chlorides promoted by samarium metal in DMF. Tetrahedron 59:42, pages 8429-8437.
Crossref
Xue‐Sen Fan & Yong‐Min Zhang. (2010) A Simple Access to Chalcones via Modified Mukaiyama Aldol Condensation Promoted by SmI 3 /TMSCl . Chinese Journal of Chemistry 20:2, pages 198-201.
Crossref
Zhifang Li, Yongmin Zhang & Qiaoling Li. (2019) Samarium (III) iodide promoted preparation of α,α′-bis (substituted benzylidene)cyclohexanones from benzaldehydes and cyclohexanone. Journal of Chemical Research 2000:12, pages 580-581.
Crossref
W. BAO, Y. ZHANG & T. YING. (2010) ChemInform Abstract: A Facile Route to Synthesize α,α′‐Bis(substituted‐ benzylidene) Cycloalkanones Promoted by SmI3.. ChemInform 27:24.
Crossref

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