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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 27, 1997 - Issue 6
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Original Articles

A Facile Reduction Procedure for Nitroarenes with Cp2TiCl2/Sm System

You Huang Department of Chemistry, Hangzhou University, Hangzhou, 310028, P. R. China
,
Puhong Liao Department of Chemistry, Hangzhou University, Hangzhou, 310028, P. R. China
,
Yongmin Zhang Department of Chemistry, Hangzhou University, Hangzhou, 310028, P. R. China
&
Yulu Wang Department of Chemistry, Henan Normal University, Xinxiang, 453002, P. R. China
Pages 1059-1063 | Received 20 Aug 1996, Published online: 22 Aug 2006

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Xiaoling Yang, Ying Bai, Jiayun Li, Yu Liu, Jiajian Peng, Tianbo Li, Rui Lang & Botao Qiao. (2019) Titanium-catalyzed hydrosilylation of olefins: A comparison study on Cp2TiCl2/Sm and Cp2TiCl2/LiAlH4 catalyst system. Phosphorus, Sulfur, and Silicon and the Related Elements 194:1-2, pages 64-68.
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Byung Woo Yoo, Sung Jae Lee, Byoung Seung Yoo, Kyung Il Choi & Joong Hyup Kim. (2002) A FACILE REDUCTION OF AROMATIC NITRO COMPOUNDS TO AROMATIC AMINES WITH BIS(CYCLOPENTADIENYL)TITANIUM(IV) DICHLORIDE–INDIUM SYSTEM. Synthetic Communications 32:16, pages 2489-2493.
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Huayue Wu, Rener Chen & Yongmin Zhang. (2002) A FACILE REDUCTION OF AZIDES TO THE CORRESPONDING AMINES WITH Sm/NiCl2·6H2O SYSTEM. Synthetic Communications 32:2, pages 189-193.
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Weihui Zhong, Yongmin Zhang & Xiaoyuan Chen. (2001) A NOVEL SYNTHESIS OF 2H-1,4-BENZOSELENAZINES FROM (o-NITROPHENYL)DISELENIDES AND ω-BROMOKETONES PROMOTED BY Sm/TiCl4 SYSTEM. Organic Preparations and Procedures International 33:2, pages 181-184.
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Weihui Zhong, Xiaoyuan Chen & Yongmin Zhang. (2000) Low-valent Titanium Induced Simultaneous Reduction of Nitro Group and S-S Bond in Nitrodisulfides: A Novel Method For the Synthesis of Benzothiazoline, Benzothiazoles and 2,3-Dihydro- 1,5-benzothiazepines. Synthetic Communications 30:24, pages 4451-4460.
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Uwe Rosenthal. (2019) Advantages of Group 4 Metallocene Bis(trimethylsilyl)acetylene Complexes as Metallocene Sources Towards Other Synthetically used Systems. ChemistryOpen 8:8, pages 1036-1047.
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Uwe Rosenthal. (2019) Recent Synthetic and Catalytic Applications of Group 4 Metallocene Bis(trimethylsilyl)acetylene Complexes. European Journal of Inorganic Chemistry 2019:7, pages 895-919.
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Uwe Rosenthal. (2018) Reactions of Group 4 Metallocene Bis(trimethylsilyl)acetylene Complexes with Nitriles and Isonitriles. Angewandte Chemie International Edition 57:45, pages 14718-14735.
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U. Rosenthal. (2018) Reaktionen von Gruppe‐4‐Metallocen‐Komplexen des Bis(trimethylsilyl)acetylens mit Nitrilen und Isonitrilen. Angewandte Chemie 130:45, pages 14932-14950.
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Kazuma Matsunaga, Kazuhiko Takatori, Hiroshi Kogen & Naoki Saito. (2018) Synthesis of 6,6-dimethyltricyclo[5.4.0.02,8]undecane-2,9-diol for (ent-)longipinane-type sesquiterpenoids using two types of radical cyclization reactions. Tetrahedron Letters 59:43, pages 3872-3875.
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Richard C. LarockRichard C. Larock & Alexandre A. Pletnev. 2018. Comprehensive Organic Transformations. Comprehensive Organic Transformations 1 11 .
Yukihiro Motoyama, Masahiro Taguchi, Nelfa Desmira, Seong‐Ho Yoon, Isao Mochida & Hideo Nagashima. (2013) Chemoselective Hydrogenation of Functionalized Nitroarenes and Imines by Using Carbon Nanofiber‐Supported Iridium Nanoparticles. Chemistry – An Asian Journal 9:1, pages 71-74.
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George G. Wu, Frank X. Chen, Danny LaFrance, Zhijian Liu, Scott G. Greene, Yee-Shing Wong & Ji Xie. (2011) A Novel Iodide-Catalyzed Reduction of Nitroarenes and Aryl Ketones with H 3 PO 2 or H 3 PO 3 : Its Application to the Synthesis of a Potential Anticancer Agent . Organic Letters 13:19, pages 5220-5223.
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Yukihiro Motoyama, Kazuyuki Kamo & Hideo Nagashima. (2009) Catalysis in Polysiloxane Gels: Platinum-Catalyzed Hydrosilylation of Polymethylhydrosiloxane Leading to Reusable Catalysts for Reduction of Nitroarenes. Organic Letters 11:6, pages 1345-1348.
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. (2005) Mild and Efficient Deoxygenation of Epoxides with Bis(cyclopentadienyl)titanium(IV) Dichloride-Indium System. Bulletin of the Korean Chemical Society 26:10, pages 1495-1496.
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J.L. Chiara. 2005. Comprehensive Organic Functional Group Transformations II. Comprehensive Organic Functional Group Transformations II 709 852 .
Xing‐Liaiig Zheng & Yong‐Min Zhang. (2010) Samarium‐promoted Chemoselective Reduction of Aromatic Nitro Compounds in Ionic Liquid. Chinese Journal of Chemistry 20:9, pages 925-928.
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Michael B. Smith. 2002. Compendium of Organic Synthetic Methods. Compendium of Organic Synthetic Methods 118 138 .
Zhi‐Fang Li & Yong‐Min Zhang. (2010) Low‐valent Titanium Induced Reductive Coupling of O ‐Nitrophenylazide with Benzoyl Substituted Ketene Dithioacetals: a Novel Synthesis of 4‐Aryl‐2‐methylthio‐3Z7‐l,5‐benzodiazepines . Chinese Journal of Chemistry 19:10, pages 996-998.
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Yong‐Min Zhang, Wei‐Hui Zhong & Xiao‐Yian Chen. (2010) Low‐Valent Titanium Induced Simultaneous Reduction of Nitro Group and SS Bond in Nitrodisulfides: A Facile Synthesis of 2 H ‐1,4‐Benzothiazines . Chinese Journal of Chemistry 19:2, pages 189-192.
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Yong‐Min Zhang & Yun‐Kui Liu. (2010) Application of Sm 0 /Auxiliary and Sm 0 /MCl n System in Organic Synthesis . Chinese Journal of Chemistry 19:2, pages 123-130.
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Weihui Zhong, Yongmin Zhang & Xiaoyuan Chen. (2001) Simultaneous reduction of the nitro group and the azide group in o -nitrophenylazide induced by the TiCl 4 /Sm system: a novel synthesis of 2,3-dihydro-1 H -1,5-benzodiazepines. Tetrahedron Letters 42:1, pages 73-75.
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Huayue Wu, Rener Chen & Yongmin Zhang. (2019) A novel method for the chemoselective reduction of azides to amines with a Sm/CoCl 2 · 6H 2 O system . Journal of Chemical Research 2000:5, pages 248-249.
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Ming‐Xin Yu, Yong‐Min Zhang & Wei‐Liang Bao. (2010) Application of samarium reagents in organic synthesis. Chinese Journal of Chemistry 17:1, pages 4-15.
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Guy C. Lloyd-Jones. (1998) Chapter 3. Organometallic chemistry . Part (ii) Stoichiometric methods. Annual Reports Section "B" (Organic Chemistry) 94, pages 105.
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Y. HUANG, P. LIAO, Y. ZHANG & Y. WANG. (2010) ChemInform Abstract: A Facile Reduction Procedure for Nitroarenes with Cp2TiCl2/Sm System.. ChemInform 28:27.
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