Advanced search
Publication Cover
Phase Transitions
A Multinational Journal
Volume 69, 1999 - Issue 1
Submit an article Journal homepage
383
Views
64
CrossRef citations to date
0
Altmetric
Original Articles

Oxygen vacancy ordering in CaTiO3–CaFeO2.5 perovskites: From isolated defects to infinite sheets

A. I. Becerro Bayerisches Geoinstitut, Universität Bayreuth, 95440 Bayreuth, Germany
,
C. McCammon Bayerisches Geoinstitut, Universität Bayreuth, 95440 Bayreuth, Germany
,
F. Langenhorst Bayerisches Geoinstitut, Universität Bayreuth, 95440 Bayreuth, Germany
,
F. Seifert Bayerisches Geoinstitut, Universität Bayreuth, 95440 Bayreuth, Germany
&
R. Angel Bayerisches Geoinstitut, Universität Bayreuth, 95440 Bayreuth, Germany
Pages 133-146 | Received 25 Feb 1999, Published online: 19 Aug 2006

Citations (64)

Keep up to date with the latest research on this topic with citation updates for this article.

Subscribe to citation updates

Read on this site (5)

Yuki Hidaka, Shinya Tsukada & Seiji Kojima. (2008) Aging of Dielectric Properties in Na0.5Bi0.5TiO3 Ceramics. Ferroelectrics 376:1, pages 134-139.
Read now
J.F. Scott & Matthew Dawber. (2002) Physics of ferroelectric thin-film memory devices. Ferroelectrics 265:1, pages 119-128.
Read now
Matthew Dawber & J.F. Scott. (2001) Fatigue and oxygen vacancy ordering in thin-film and bulk single crystal ferroelectrics. Integrated Ferroelectrics 32:1-4, pages 259-266.
Read now
J.F. Scott. (2001) Fatigue as a phase transition. Integrated Ferroelectrics 38:1-4, pages 125-133.
Read now
A.I. Becerro, M.A. Carpenter, T. Boffa Ballaran & F. Seifert. (2000) Hard mode infrared spectroscopy of CaTiO3—CaFeO2.5 perovskites. Phase Transitions 71:3, pages 161-172.
Read now

Articles from other publishers (59)

Yongda Li, Gang Li, Ningyu Zhang, Guishang Pei, Yuxiao Xue & Xuewei Lv. (2024) Metallurgical performance of Ca3TiFe2O8. Calphad 85, pages 102671.
Crossref
Jason Luong, Xin Wang, Alicia Tsung, Nicholas Humphrey, Huiming Guo, Benjamin X. Lam, Shaama Mallikarjun Sharada & William J. Bowman. (2023) Nanoscale Iron Redistribution during Thermochemical Decomposition of CaTi 1– x Fe x O 3−δ Alters the Electrical Transport Pathway: Implications for Oxygen-Transport Membranes, Electrocatalysis, and Photocatalysis . ACS Applied Nano Materials 6:3, pages 1620-1630.
Crossref
Yong Yu, Lin XieStephen J. Pennycook, Michel Bosman & Jiaqing He. (2022) Strain-induced van der Waals gaps in GeTe revealed by in situ nanobeam diffraction. Science Advances 8:45.
Crossref
Sergey N. Britvin, Natalia S. Vlasenko, Andrey Aslandukov, Alena Aslandukovа, Leonid Dubrovinsky, Liudmila A. Gorelova, Maria G. Krzhizhanovskaya, Oleg S. Vereshchagin, Vladimir N. Bocharov, Yulia S. Shelukhina, Maksim S. Lozhkin, Anatoly N. Zaitsev & Fabrizio Nestola. (2022) Natural cubic perovskite, Ca(Ti,Si,Cr)O3–δ, a versatile potential host for rock-forming and less-common elements up to Earth’s mantle pressure. American Mineralogist 107:10, pages 1936-1945.
Crossref
Maxime Delporte, Julie Cavailles, Michaël Martin Romo y Morales, Nicolas Bion, Luca Nodari, Xavier Courtois, Fabien Can & Helena Kaper. (2022) High-Surface-Area Synthesis of Iron-Doped CaTiO 3 at Low Temperatures: New Insights into Oxygen Activation, Iron States, and the Impact on Methane Oxidation . Inorganic Chemistry 61:39, pages 15432-15443.
Crossref
Yaolong Xing, Inhwan Kim, Kyeong Tae Kang, Bumsu Park, Zhen Wang, Jong Chan Kim, Hu Young Jeong, Woo Seok Choi, Jaekwang Lee & Sang Ho Oh. (2022) Atomic-scale operando observation of oxygen diffusion during topotactic phase transition of a perovskite oxide. Matter 5:9, pages 3009-3022.
Crossref
Rong Huang, Tiziana Boffa Ballaran, Catherine A. McCammon, Nobuyoshi Miyajima & Daniel J. Frost. (2021) The Effect of Fe‐Al Substitution on the Crystal Structure of MgSiO 3 Bridgmanite . Journal of Geophysical Research: Solid Earth 126:9.
Crossref
Dino Aegerter, Mario Borlaf, Emiliana Fabbri, Adam H. Clark, Maarten Nachtegaal, Thomas Graule & Thomas J. Schmidt. (2020) Tuning the Co Oxidation State in Ba0.5Sr0.5Co0.8Fe0.2O3-δ by Flame Spray Synthesis Towards High Oxygen Evolution Reaction Activity. Catalysts 10:9, pages 984.
Crossref
X. H. Tian, Y. J. Wang, Y. L. Tang, Y. L. Zhu & X. L. Ma. (2020) The effect of oxygen vacancy plate on the domain structure in BiFeO3 thin films by phase field simulations. Journal of Applied Physics 127:9.
Crossref
Victor V. Sharygin, Grigory A. Yakovlev, Richard Wirth, Yurii V. Seryotkin, Ellina V. Sokol, Elena N. Nigmatulina, Nikolai S. Karmanov & Leonid A. Pautov. (2019) Nataliakulikite, Ca4Ti2(Fe3+,Fe2+)(Si,Fe3+,Al)O11, a New Perovskite-Supergroup Mineral from Hatrurim Basin, Negev Desert, Israel. Minerals 9:11, pages 700.
Crossref
Helen Grüninger, Zhaodong Liu, Renée Siegel, Tiziana Boffa Ballaran, Tomoo Katsura, Jürgen Senker & Daniel J. Frost. (2019) Oxygen Vacancy Ordering in Aluminous Bridgmanite in the Earth's Lower Mantle. Geophysical Research Letters 46:15, pages 8731-8740.
Crossref
Ella Sokol, Svetlana Kokh, Victor Sharygin, Victoria Danilovsky, Yurii Seryotkin, Ruslan Liferovich, Anna Deviatiiarova, Elena Nigmatulina & Nikolay Karmanov. (2019) Mineralogical Diversity of Ca2SiO4-Bearing Combustion Metamorphic Rocks in the Hatrurim Basin: Implications for Storage and Partitioning of Elements in Oil Shale Clinkering. Minerals 9:8, pages 465.
Crossref
Francesco Cordero, Elena Buixaderas & Carmen Galassi. (2019) Damage from Coexistence of Ferroelectric and Antiferroelectric Domains and Clustering of O Vacancies in PZT: An Elastic and Raman Study. Materials 12:6, pages 957.
Crossref
C. Salles, J.M. Bassat, J. Fouletier, D. Marinha & M.-C. Steil. (2018) Oxygen pressure dependence of the ionic conductivity of iron-doped calcium titanate. Solid State Ionics 324, pages 103-108.
Crossref
Rafał Juroszek, Hannes Krüger, Irina Galuskina, Biljana Krüger, Lidia Jeżak, Bernd Ternes, Justyna Wojdyla, Tomasz Krzykawski, Leonid Pautov & Evgeny Galuskin. (2018) Sharyginite, Ca3TiFe2O8, A New Mineral from the Bellerberg Volcano, Germany. Minerals 8:7, pages 308.
Crossref
L. T. H. Thanh, N. B. Doan, N. Q. Dung, L. V. Cuong, L. H. Bac, N. A. Duc, P. Q. Bao & D. D. Dung. (2017) Origin of Room Temperature Ferromagnetism in Cr-Doped Lead-Free Ferroelectric Bi0.5Na0.5TiO3 Materials. Journal of Electronic Materials 46:6, pages 3367-3372.
Crossref
Maria Balaguer, Sonia Escolástico & Jose M. Serra. (2017) Oxygen permeation and stability of CaTi0.73Fe0.18Mg0.09O3−δ oxygen-transport membrane. Journal of Membrane Science 524, pages 56-63.
Crossref
Felix V. KaminskyFelix V. Kaminsky. 2017. The Earth's Lower Mantle. The Earth's Lower Mantle 47 160 .
J. SHI, Y. L. JIA, X. H. LI, X. H. DAI, J. X. GUO, J. Z. LOU, Q. X. ZHAO, J. WANG, X. Y. ZHANG & B. T. LIU. (2016) IMPACTS OF ANNEAL TEMPERATURE ON THE STRUCTURAL, MAGNETIC AND OPTICAL PROPERTIES OF THE Fe:LaSrFeO 4 COMPOSITE FILM . Surface Review and Letters 23:06, pages 1650060.
Crossref
Chi Chen & Francesco Ciucci. (2016) Designing Fe-Based Oxygen Catalysts by Density Functional Theory Calculations. Chemistry of Materials 28:19, pages 7058-7065.
Crossref
E. Gerasimov, N. Kulikovskaya, A. Chuvilin, L. Isupova & S. Tsybulya. (2016) Microstructural Changes in La1−xCaxCoO3−δ Solid Solutions Under the Influence of Catalytic Reaction of Methane Combustion. Topics in Catalysis 59:15-16, pages 1354-1360.
Crossref
Jonathan M. Polfus, Wen Xing, Marit Riktor, Martin F. Sunding, Paul Inge Dahl, Sidsel M. Hanetho, Tommy Mokkelbost, Yngve Larring, Marie‐Laure Fontaine & Rune Bredesen. (2015) Enhanced O 2 Flux of CaTi 0.85 Fe 0.15 O 3−δ Based Membranes by Mn Doping . Journal of the American Ceramic Society 99:3, pages 1071-1078.
Crossref
Jonathan M. Polfus, Wen Xing, Goran Pećanac, Anita Fossdal, Sidsel M. Hanetho, Yngve Larring, Jürgen Malzbender, Marie-Laure Fontaine & Rune Bredesen. (2016) Oxygen permeation and creep behavior of Ca1−Sr Ti0.6Fe0.15Mn0.25O3− (x=0, 0.5) membrane materials. Journal of Membrane Science 499, pages 172-178.
Crossref
Jonathan M. Polfus, Wen Xing, Martin F. Sunding, Sidsel M. Hanetho, Paul Inge Dahl, Yngve Larring, Marie-Laure Fontaine & Rune Bredesen. (2015) Doping strategies for increased oxygen permeability of CaTiO3 based membranes. Journal of Membrane Science 482, pages 137-143.
Crossref
. 2015. Coal and Peat Fires: A Global Perspective. Coal and Peat Fires: A Global Perspective 281 316 .
Shu Fei Liu, Yong Jun Wu, Juan Li & Xiang Ming Chen. (2014) Effects of oxygen vacancies on dielectric, electrical, and ferroelectric properties of Ba 4 Nd 2 Fe 2 Nb 8 O 30 ceramics . Applied Physics Letters 104:8, pages 082912.
Crossref
Falko Langenhorst, Dennis Harries & Kilian Pollok. 2013. Minerals at the Nanoscale. Minerals at the Nanoscale 261 295 .
Stefan Stöber, Günther Redhammer, Susan Schorr, Oleksandr Prokhnenko & Herbert Pöllmann. (2013) Structure refinements of members in the brownmillerite solid solution series Ca2Al (Fe0.5Mn0.5)2−O5+ with 1/2≤x≤4/3. Journal of Solid State Chemistry 197, pages 420-428.
Crossref
David J. Keeble. (2012) Variable Energy Positron Annihilation Spectroscopy of Perovskite Oxides. Defect and Diffusion Forum 331, pages 201-233.
Crossref
Yoichi Nakajima, Daniel J. Frost & David C. Rubie. (2012) Ferrous iron partitioning between magnesium silicate perovskite and ferropericlase and the composition of perovskite in the Earth's lower mantle. Journal of Geophysical Research: Solid Earth 117:B8.
Crossref
W. Hajjaji, C. Zanelli, M.P. Seabra, M. Dondi & J.A. Labrincha. (2011) Cr-doped perovskite and rutile pigments derived from industrial by-products. Chemical Engineering Journal 171:3, pages 1178-1184.
Crossref
J. F. Scott. (2010) Leading the Way to Lead‐Free. ChemPhysChem 11:2, pages 341-343.
Crossref
V.V. Sharygin, E.V. Sokol & Ye. Vapnik. (2008) Minerals of the pseudobinary perovskite-brownmillerite series from combustion metamorphic larnite rocks of the Hatrurim Formation ( Israel ) . Russian Geology and Geophysics 49:10, pages 709-726.
Crossref
Carine B. Vanpeteghem, Ross J. Angel, Jing Zhao, Nancy L. Ross, Günther J. Redhammer & Friedrich Seifert. (2008) The effect of oxygen vacancies and aluminium substitution on the high-pressure properties of brownmillerite-structured Ca2Fe2−x Al x O5. Physics and Chemistry of Minerals 35:9, pages 493-504.
Crossref
David P. Dobson, Ralf Dohmen & Michael Wiedenbeck. (2008) Self-diffusion of oxygen and silicon in MgSiO3 perovskite. Earth and Planetary Science Letters 270:1-2, pages 125-129.
Crossref
G. C. Mather, M. S. Islam & F. M. Figueiredo. (2007) Atomistic Study of a CaTiO 3 ‐Based Mixed Conductor: Defects, Nanoscale Clusters, and Oxide‐Ion Migration . Advanced Functional Materials 17:6, pages 905-912.
Crossref
Norimasa Nishiyama, Takehiko Yagi, Shigeaki Ono, Hirotada Gotou, Tatsuhiko Harada & Takumi Kikegawa. (2006) Effect of incorporation of iron and aluminum on the thermoelastic properties of magnesium silicate perovskite. Physics and Chemistry of Minerals 34:3, pages 131-143.
Crossref
C.B. Vanpeteghem, R.J. Angel, N.L. Ross, S.D. Jacobsen, D.P Dobson, K.D. Litasov & E. Ohtani. (2006) Al, Fe substitution in the MgSiO3 perovskite structure: A single-crystal X-ray diffraction study. Physics of the Earth and Planetary Interiors 155:1-2, pages 96-103.
Crossref
N Menou, Ch Muller, I S Baturin, D K Kuznetsov, V Ya Shur, J L Hodeau & T Schneller. (2005) In situ synchrotron x-ray diffraction study of electrical field induced fatigue in Pt/PbZr 0.45 Ti 0.55 O 3 /Pt ferroelectric capacitors . Journal of Physics: Condensed Matter 17:48, pages 7681-7688.
Crossref
J M Wesselinowa, S Trimper & K Zabrocki. (2005) Impact of layer defects in ferroelectric thin films. Journal of Physics: Condensed Matter 17:29, pages 4687-4699.
Crossref
Wei Li, Aiping Chen, Xiaomei Lu & Jinsong Zhu. (2005) Collective domain-wall pinning of oxygen vacancies in bismuth titanate ceramics. Journal of Applied Physics 98:2.
Crossref
Wei Li, Chengju Wang, Jinsong Zhu & Yening Wang. (2004) Correlation among oxygen vacancies and its effect on fatigue in neodymium-modified bismuth titanate ceramics. Journal of Physics: Condensed Matter 16:50, pages 9201-9208.
Crossref
Jesús Canales-Vázquez, Filipe M. Figueiredo, João C. Waerenborgh, Wuzong Zhou, Jorge R. Frade & John T.S. Irvine. (2004) Microdomain texture and microstructures of Fe4+-containing CaTi0.4Fe0.6O3−δ. Journal of Solid State Chemistry 177:9, pages 3105-3113.
Crossref
Takehiko Yagi, Kouichi Okabe, Norimasa Nishiyama, Atsushi Kubo & Takumi Kikegawa. (2004) Complicated effects of aluminum on the compressibility of silicate perovskite. Physics of the Earth and Planetary Interiors 143-144, pages 81-91.
Crossref
J. F. Scott, A. Q. Jiang, S. A. T. Redfern, Ming Zhang & M. Dawber. (2003) Infrared spectra and second-harmonic generation in barium strontium titanate and lead zirconate-titanate thin films: “Polaron” artifacts. Journal of Applied Physics 94:5, pages 3333-3344.
Crossref
R.L. Withers, M. James & D.J. Goossens. (2003) Atomic ordering in the doped rare earth cobaltates Ln0.33Sr0.67CoO3−δ (Ln=Y3+, Ho3+ and Dy3+). Journal of Solid State Chemistry 174:1, pages 198-208.
Crossref
Jürgen Nuffer, Doru C. Lupascu, Alexandre Glazounov, Hans-Joachim Kleebe & Jürgen Rödel. (2002) Microstructural modifications of ferroelectric lead zirconate titanate ceramics due to bipolar electric fatigue. Journal of the European Ceramic Society 22:13, pages 2133-2142.
Crossref
Doru C. Lupascu & Ute Rabe. (2002) Cyclic Cluster Growth in Ferroelectric Perovskites. Physical Review Letters 89:18.
Crossref
A.I. Becerro, S.A.T. Redfern, M.A. Carpenter, K.S. Knight & F. Seifert. (2002) Displacive Phase Transitions in and Strain Analysis of Fe-Doped CaTiO3 Perovskites at High Temperatures by Neutron Diffraction. Journal of Solid State Chemistry 167:2, pages 459-471.
Crossref
Doru C. Lupascu, Vladimir Ya. Shur & Alevtina G. Shur. (2002) Dynamics of a single-planar domain wall in ferroelectric–ferroelastic Gd2(MoO4)3. Applied Physics Letters 80:13, pages 2359-2361.
Crossref
Catherine A. McCammon, Ana Isabel Becerro, Stefan Lauterbach, Ulrich Bläß, Stefan Marion, Falko Langenhorst, Ross J. Angel, Peter van Aken & Friedrich Seifert. (2011) Oxygen Vacancies in Perovskite and Related Structures: Implications for the Lower Mantle. MRS Proceedings 718.
Crossref
Nancy L. Ross, R.J. Angel & F. Seifert. (2002) Compressibility of brownmillerite (Ca2Fe2O5): effect of vacancies on the elastic properties of perovskites. Physics of the Earth and Planetary Interiors 129:1-2, pages 145-151.
Crossref
V.V. Kharton, A.V. Kovalevsky, A.P. Viskup, J.R. Jurado, F.M. Figueiredo, E.N. Naumovich & J.R. Frade. (2001) Transport Properties and Thermal Expansion of Sr0.97Ti1−FexO3− (x=0.2–0.8). Journal of Solid State Chemistry 156:2, pages 437-444.
Crossref
J. F. Scott & Matthew Dawber. (2000) Oxygen-vacancy ordering as a fatigue mechanism in perovskite ferroelectrics. Applied Physics Letters 76:25, pages 3801-3803.
Crossref
A I Becerro, F Seifert, R J Angel, S Ríos & C McCammon. (2000) Displacive phase transitions and spontaneous strains in oxygen deficient CaFe x Ti 1- x O 3- x /2 perovskites (0le x le0.40) . Journal of Physics: Condensed Matter 12:15, pages 3661-3670.
Crossref
C A McCammon, A I Becerro, F Langenhorst, R J Angel, S Marion & F Seifert. (2000) Short-range ordering of oxygen vacancies in CaFe x Ti 1 - x O 3 - x /2 perovskites (0 < x < 0.4) . Journal of Physics: Condensed Matter 12:13, pages 2969-2984.
Crossref
Matthew Dawber & J. F. Scott. (2000) A model for fatigue in ferroelectric perovskite thin films. Applied Physics Letters 76:8, pages 1060-1062.
Crossref
James F. ScottJames F. Scott. 2000. Ferroelectric Memories. Ferroelectric Memories 133 143 .
S. Marion, A. I. Becerro & T. Norby. (1999) Ionic and electronic conductivity in CaTi1−xFexO3−δ (x=0.1–0.3). Ionics 5:5-6, pages 385-392.
Crossref

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Order Reprints Request Corporate Permissions

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

Request Academic Permissions

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.

Related research

People also read lists articles that other readers of this article have read.

Recommended articles lists articles that we recommend and is powered by our AI driven recommendation engine.

Cited by lists all citing articles based on Crossref citations.
Articles with the Crossref icon will open in a new tab.