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Original Articles

Controlling bond cleavage and probing intramolecular dynamics via photodissociation of rovibrationally excited molecules

Pages 711-749 | Published online: 26 Nov 2010

Keep up to date with the latest research on this topic with citation updates for this article.

Read on this site (4)

I. Bar & S. Rosenwaks. (2012) Vibrationally mediated photodissociation of ethyne isotopologues and homologues revisited. Molecular Physics 110:21-22, pages 2673-2686.
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Ran Marom, Uzi Zecharia, Salman Rosenwaks & Ilana Bar. (2008) Propensity towards H photofragments in the photodissociation of CD3NH2 pre-excited to the first N–H stretch overtone. Molecular Physics 106:2-4, pages 213-222.
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Brian J. Orr. (2006) Spectroscopy and energetics of the acetylene molecule: dynamical complexity alongside structural simplicity. International Reviews in Physical Chemistry 25:4, pages 655-718.
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Articles from other publishers (66)

Luuk J. G. W. van Wilderen, Daniela Kern-Michler, Carsten Neumann, Matiss Reinfelds, Jan von Cosel, Maximiliane Horz, Irene Burghardt, Alexander Heckel & Jens Bredenbeck. (2023) Choose your leaving group: selective photodeprotection in a mixture of p HP-caged compounds by VIPER excitation . Chemical Science 14:10, pages 2624-2630.
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Junggil Kim, Kyung Chul Woo & Sang Kyu Kim. (2021) Femtosecond Wavepacket Dynamics Reveals the Molecular Structures in the Excited (S 1 ) and Cationic (D 0 ) States . The Journal of Physical Chemistry A 125:30, pages 6629-6635.
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M. Leonard, A. M. Sayler, K. D. Carnes, Emily M. Kaufman, E. Wells, R. Cabrera-Trujillo, B. D. Esry & I. Ben-Itzhak. (2019) Bond rearrangement during Coulomb explosion of water molecules. Physical Review A 99:1.
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Kopin Liu. (2016) Vibrational Control of Bimolecular Reactions with Methane by Mode, Bond, and Stereo Selectivity. Annual Review of Physical Chemistry 67:1, pages 91-111.
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Michael Epshtein, Alexander Portnov & Ilana Bar. (2015) CD 3 Deformation Modes as Preferential Promoters of Methylamine- d 3 to the First Electronic State . The Journal of Physical Chemistry A 120:19, pages 3049-3054.
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Salman Rosenwaks & Ilana Bar. 2016. Advances in Chemical Physics Volume 159. Advances in Chemical Physics Volume 159 23 50 .
Rui Mao, Qun Zhang, Min Chen, Chao He, Dan-na Zhou, Xi-lin Bai, Limin Zhang & Yang Chen. (2013) Note: Vibrationally mediated photodissociation of carbon dioxide cation. The Journal of Chemical Physics 139:16.
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Alexander Portnov, Michael Epshtein, Salman Rosenwaks & Ilana Bar. (2013) Vibrational overtone spectroscopy and intramolecular dynamics of C–H stretches in pyrrole. The Journal of Chemical Physics 138:19.
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Alexander Portnov, Michael Epshtein, Salman Rosenwaks & Ilana Bar. (2012) Vibrational dynamics of pyrrole via frequency-domain spectroscopy. The Journal of Chemical Physics 136:2.
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Moshe Shapiro & Paul Brumer. 2011. Quantum Control of Molecular Processes. Quantum Control of Molecular Processes 513 535 .
Michael Epshtein, Alexander Portnov, Salman Rosenwaks & Ilana Bar. (2011) Communication: Mode-specific photodissociation of vibrationally excited pyrrole. The Journal of Chemical Physics 134:20.
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Ran Marom, Chen Levi, Tal Weiss, Salman Rosenwaks, Yehuda Zeiri, Ronnie Kosloff & Ilana Bar. (2010) Quantum Tunneling of Hydrogen Atom in Dissociation of Photoexcited Methylamine. The Journal of Physical Chemistry A 114:36, pages 9623-9627.
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Sergy Yu. Grebenshchikov & Salman Rosenwaks. (2010) Ab Initio Quantum Mechanical Study of the O( 1 D) Formation in the Photolysis of Ozone between 300 and 330 nm . The Journal of Physical Chemistry A 114:36, pages 9809-9819.
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Keevin Didriche & Michel Herman. (2010) A four-atom molecule at the forefront of spectroscopy, intramolecular dynamics and astrochemistry: Acetylene. Chemical Physics Letters 496:1-3, pages 1-7.
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Prashant Chandra Singh, Lei Shen, Myung Hwa Kim & Arthur G. Suits. (2010) Photodissociation and photoelectron imaging of molecular ions: probing multisurface and multichannel dynamics. Chemical Science 1:5, pages 552.
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Kathryn L. Plath, Kaito Takahashi, Rex T. Skodje & Veronica Vaida. (2009) Fundamental and Overtone Vibrational Spectra of Gas-Phase Pyruvic Acid. The Journal of Physical Chemistry A 113:26, pages 7294-7303.
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Salman Rosenwaks. 2009. Vibrationally Mediated Photodissociation. Vibrationally Mediated Photodissociation 142 188 .
Salman Rosenwaks. 2009. Vibrationally Mediated Photodissociation. Vibrationally Mediated Photodissociation 94 141 .
Salman Rosenwaks. 2009. Vibrationally Mediated Photodissociation. Vibrationally Mediated Photodissociation 68 93 .
Salman Rosenwaks. 2009. Vibrationally Mediated Photodissociation. Vibrationally Mediated Photodissociation 1 8 .
Ran Marom, Tal Weiss, Salman Rosenwaks & Ilana Bar. (2009) Site-dependent photodissociation of vibrationally excited CD3NH2. The Journal of Chemical Physics 130:16.
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Paranjothy Manikandan, Aravindan Semparithi & Srihari Keshavamurthy. (2009) Decoding the Dynamical Information Embedded in Highly Excited Vibrational Eigenstates: State Space and Phase Space Viewpoints. The Journal of Physical Chemistry A 113:9, pages 1717-1730.
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Amir Golan, Nitzan Mayorkas, Salman Rosenwaks & Ilana Bar. (2009) A new method for determining absorption cross sections out of initially excited vibrational states. The Journal of Chemical Physics 130:5.
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Meghan E. Dunn, George C. Shields, Kaito Takahashi, Rex T. Skodje & Veronica Vaida. (2008) Experimental and Theoretical Study of the OH Vibrational Spectra and Overtone Chemistry of Gas-Phase Vinylacetic Acid. The Journal of Physical Chemistry A 112:41, pages 10226-10235.
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Kaito Takahashi, Kathryn L. Plath, Rex T. Skodje & Veronica Vaida. (2008) Dynamics of Vibrational Overtone Excited Pyruvic Acid in the Gas Phase: Line Broadening through Hydrogen-Atom Chattering. The Journal of Physical Chemistry A 112:32, pages 7321-7331.
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Hiroshi Teramoto & Tamiki Komatsuzaki. (2008) Probing remnants of invariants to mediate energy exchange in highly chaotic many-dimensional systems. Physical Review E 78:1.
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Doo-Sik Ahn, Jeongmook Lee, Jeong-Mo Choi, Kyoung-Seok Lee, Sun Jong Baek, Kunhye Lee, Kyoung-Koo Baeck & Sang Kyu Kim. (2008) State-selective predissociation dynamics of methylamines: The vibronic and H∕D effects on the conical intersection dynamics. The Journal of Chemical Physics 128:22.
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Ran Marom, Uzi Zecharia, Salman Rosenwaks & Ilana Bar. (2008) Vibrational overtone spectra of N–H stretches and intramolecular dynamics on the ground and electronically excited states of methylamine. The Journal of Chemical Physics 128:15.
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Amir Zwielly, Alexander Portnov, Chen Levi, Salman Rosenwaks & Ilana Bar. (2008) Rovibrational spectroscopy and intramolecular dynamics of 1,2- trans -d2-ethene in the first CH stretch overtone region . The Journal of Chemical Physics 128:11.
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R. B. Metz. 2008. Advances in Chemical Physics. Advances in Chemical Physics 331 373 .
Jens Riedel, Shannon Yan, Hiroshi Kawamata & Kopin Liu. (2008) A simple yet effective multipass reflector for vibrational excitation in molecular beams. Review of Scientific Instruments 79:3.
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Murat Citir & Ricardo B. Metz. (2008) Mode selective photodissociation dynamics in V+(OCO). The Journal of Chemical Physics 128:2.
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Amir Golan, Salman Rosenwaks & Ilana Bar. (2007) Molecular Dynamics of Methylamine Following CH and NH Vibrational Excitation and Promotion to the à State. Israel Journal of Chemistry 47:1, pages 11-16.
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Alexander Portnov, Evgeny Bespechansky & Ilana Bar. (2007) Vibrational Overtone Spectroscopy and Intramolecular Dynamics of Ethene. The Journal of Physical Chemistry A 111:42, pages 10646-10653.
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Amir Golan, Alexander Portnov, Salman Rosenwaks & Ilana Bar. (2007) Mode-dependent enhancement and intramolecular dynamics via vibrationally mediated photodissociation. Physica Scripta 76:3, pages C79-C83.
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Ran Marom, Uzi Zecharia, Salman Rosenwaks & Ilana Bar. (2007) Nonstatistical energy flow in the first N–H stretch overtone region of methylamine. Chemical Physics Letters 440:4-6, pages 194-198.
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Amir Golan, Salman Rosenwaks & Ilana Bar. (2006) Mode-dependent enhancement of photodissociation and photoionization in a seven atom molecule. The Journal of Chemical Physics 125:15.
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Evgeny Bespechansky, Alexander Portnov, Amir Zwielly, Salman Rosenwaks & Ilana Bar. (2006) Vibrationally mediated photodissociation of ethene isotopic variants preexcited to the fourth C–H stretch overtone. The Journal of Chemical Physics 125:13.
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Alexander Portnov, Yuval Ganot, Evgeny Bespachiansky, Salman Rosenwaks & Ilana Bar. (2006) Intramolecular dynamics from frequency domain spectroscopy. Vibrational Spectroscopy 42:1, pages 147-155.
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Alexander Portnov, Lior Blockstein & Ilana Bar. (2006) Vibrational structure and methyl C–H dynamics in propyne. The Journal of Chemical Physics 124:16, pages 164301.
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A M Sayler, M Leonard, K D Carnes, R Cabrera-Trujillo, B D Esry & I Ben-Itzhak. (2006) Preference for breaking the O–H bond over the O–D bond following HDO ionization by fast ions. Journal of Physics B: Atomic, Molecular and Optical Physics 39:7, pages 1701-1710.
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Murat Citir, Gokhan Altinay & Ricardo B. Metz. (2006) Electronic and Vibrational Spectroscopy and Vibrationally Mediated Photodissociation of V + (OCO) . The Journal of Physical Chemistry A 110:15, pages 5051-5057.
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Hiroshi Akagi, Hiroshi Fukazawa, Keiichi Yokoyama & Atsushi Yokoyama. (2005) Selective OD bond dissociation of HOD: Photodissociation of vibrationally excited HOD in the 5νOD state. The Journal of Chemical Physics 123:18.
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Kai-Jun Yuan, Zhigang Sun, Shu-Lin Cong & Nanquan Lou. (2005) Selective excitation of the OClO molecule with femtosecond laser pulse. Physical Review A 72:5.
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Alexander Portnov, Evgeny Bespechansky, Salman Rosenwaks & Ilana Bar. (2005) Overtone spectroscopy of C–H ethyl stretches of 1-butyne. The Journal of Chemical Physics 123:8.
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Yuval Ganot, Salman Rosenwaks & Ilana Bar. (2005) Evidence for new bands in the 3ν1 and 4ν1 regions of propyne. The Journal of Chemical Physics 122:24.
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Alex Portnov, Evgeny Bespechansky, Yuval Ganot, Salman Rosenwaks & Ilana Bar. (2005) Determining the vibrational pattern via overtone cold spectra: C–H methyl stretches of propyne. The Journal of Chemical Physics 122:22.
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Alexander Portnov, Yuval Ganot, Salman Rosenwaks & Ilana Bar. (2005) Probing molecular dynamics using action, Doppler and photoacoustic spectroscopy. Journal of Molecular Structure 744-747, pages 107-115.
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Mark A. Payne, Angela P. Milce, Michael J. Frost & Brian J. Orr. (2005) Rovibrational Energy Transfer in the 4ν CH Manifold of Acetylene Viewed by IR−UV Double Resonance Spectroscopy. 2. Perturbed States with J = 17 and 18 . The Journal of Physical Chemistry B 109:17, pages 8332-8343.
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Chushuan Chang, Chu-Yung Luo & Kopin Liu. (2005) Imaging the Mode-Selected Predissociation of OCS + [( v 1 v 2 v 3 )B̃ 2 Σ + ] . The Journal of Physical Chemistry A 109:6, pages 1022-1025.
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Raphael D. Levine. 2009. Molecular Reaction Dynamics. Molecular Reaction Dynamics.
M. Herman, C. Depiesse, G. Di Lonardo, A. Fayt, L. Fusina, D. Hurtmans, S. Kassi, M. Mollabashi & J. Vander Auwera. (2004) The vibration–rotation spectrum of 12C2HD: new overtone bands and global vibrational analysis. Journal of Molecular Spectroscopy 228:2, pages 499-510.
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Alexander Portnov, Salman Rosenwaks & Ilana Bar. (2004) Vibrational spectroscopy and intramolecular dynamics of 1-butyne. The Journal of Chemical Physics 121:12, pages 5860-5867.
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Ran Marom, Amir Golan, Salman Rosenwaks & Ilana Bar. (2004) Intramolecular Dynamics in the Photofragmentation of Initially Vibrationally Excited CH 2 Cl 2 . The Journal of Physical Chemistry A 108:39, pages 8089-8095.
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Alexander Portnov, Salman Rosenwaks & Ilana Bar. (2004) Vibrationally mediated photodissociation of 1-butyne initially excited to the 3ν1 state. Chemical Physics Letters 392:1-3, pages 140-145.
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Yuval Ganot, Salman Rosenwaks & Ilana Bar. (2004) H and D release in ∼243.1 nm photolysis of vibrationally excited 3ν1, 4ν1, and 4νCD overtones of propyne-d3. The Journal of Chemical Physics 120:18, pages 8600-8607.
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D. J. Donaldson, A. F. Tuck & Veronica Vaida. (2003) Atmospheric Photochemistry via Vibrational Overtone Absorption. Chemical Reviews 103:12, pages 4717-4730.
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Jingang Zhou, Jim J. Lin & Kopin Liu. (2003) Mode-correlated product pairs in the F+CHD3→DF+CHD2 reaction. The Journal of Chemical Physics 119:16, pages 8289-8296.
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Ran Marom, Amir Golan, Salman Rosenwaks & Ilana Bar. (2003) Photodissociation dynamics of vibrationally excited CH2Cl2 molecules. Chemical Physics Letters 378:3-4, pages 305-312.
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Moshe Shapiro & Paul Brumer. (2003) Coherent control of molecular dynamics. Reports on Progress in Physics 66:6, pages 859-942.
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Hiroshi Akagi, Keiichi Yokoyama & Atsushi Yokoyama. (2003) Photodissociation of highly vibrationally excited NH3 in the 5νN–H region: Initial vibrational state dependence of N–H bond dissociation cross section. The Journal of Chemical Physics 118:8, pages 3600-3611.
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Xinzhi Sheng, Yuval Ganot, Salman Rosenwaks & Ilana Bar. (2002) Disclosing rovibrational couplings and overlaps from irregularities in action spectra: Photodissociation of the 4νCH rovibrational manifold of C2H2. The Journal of Chemical Physics 117:14, pages 6511-6518.
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Gabriela Dorfman, Aviva Melchior, Salman Rosenwaks & Ilana Bar. (2002) Vibrationally Mediated Photodissociation of Jet-Cooled CH 3 CF 2 Cl:  A Probe of Energy Flow and Bond Breaking Dynamics . The Journal of Physical Chemistry A 106:36, pages 8285-8290.
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Yuval Ganot, Xinzhi Sheng, Ilana Bar & Salman Rosenwaks. (2002) Differing reactivities in the predissociation of acetylene isotopomers pre-excited with three CH stretching quanta. Chemical Physics Letters 361:1-2, pages 175-181.
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Paul J. Dagdigian. (2002) Quantum theory of vector correlations in vibrationally mediated photodissociation. The Journal of Chemical Physics 116:18, pages 7948-7956.
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Lianbin Li, Gabriela Dorfman, Aviva Melchior, Salman Rosenwaks & Ilana Bar. (2002) Photodissociation and intramolecular dynamics of vibrationally excited CHF2Cl. The Journal of Chemical Physics 116:5, pages 1869-1876.
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