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Separation Science and Technology Volume 53, 2018 - Issue 12: Proceedings of the 19th Symposium on Separate Science and Technology for Energy Applications
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Separation of americium from europium using 3,3′-dimethoxy-phenyl-bis-1,2,4-triazinyl-2,6-pyridine

Talon G. HillOak Ridge National Laboratory, Oak Ridge, Tennessee, USAView further author information
,
Ai Lin ChinDepartment of Chemistry, Tennessee Technological University, Cookeville, Tennessee, USAView further author information
,
Serene TaiDepartment of Chemistry, Tennessee Technological University, Cookeville, Tennessee, USAView further author information
,
Jesse D. CarrickDepartment of Chemistry, Tennessee Technological University, Cookeville, Tennessee, USAView further author information
,
Dale D. EnsorDepartment of Chemistry, Tennessee Technological University, Cookeville, Tennessee, USAView further author information
&
Lætitia H. DelmauOak Ridge National Laboratory, Oak Ridge, Tennessee, USACorrespondence[email protected]
View further author information
Pages 1848-1855 | Received 02 Dec 2016, Accepted 06 Mar 2017, Published online: 11 May 2017

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Kumari Anshul, J. Selvakumar, S. Srinivasan, G. Suneel, N.R. Jawahar, J.K. Gayen & K.V. Ravi. (2023) Chromatography separation of minor actinides from Ln3+ rich high-level radioactive liquid waste (HLW) using bis-triazinyl-pyridine (BTP) resin. Separation Science and Technology 58:15-16, pages 2631-2640.
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Yuji Sasaki, Masashi Kaneko, Yasutoshi Ban, Masahiko Matsumiya, Masahiko Nakase & Kenji Takeshita. (2022) Multi-stage extraction and separation of Ln and An using TODGA and DTBA or DTPA accompanying pH adjustment with lactic acid and ethylenediamine. Separation Science and Technology 57:16, pages 2543-2553.
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Articles from other publishers (21)

Ning Pu, Emma Archer, Xihong He, Jing Chen, Linfeng Rao, Jenifer C. Shafer, Ping Yang & Chao Xu. (2024) Tuning Selectivity to f-Elements through Bonding and Solvation Effects of a Sulfur Donor Ligand. Inorganic Chemistry 63:15, pages 6845-6853.
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Eric A. Agyei & Jesse D. Carrick. (2024) Synthetic approach to the construction of unsymmetric pyridyl-1,2,4-triazine complexants. Tetrahedron 155, pages 133872.
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Lesta S. Fletcher, Mariah L. Tedder, Samiat O. Olayiwola, Nickolas A. Joyner, Marcos M. Mason, Allen G. Oliver, Dale D. Ensor, David A. Dixon & Jesse D. Carrick. (2024) Next-Generation 3,3′-AlkoxyBTPs as Complexants for Minor Actinide Separation from Lanthanides: A Comprehensive Separations, Spectroscopic, and DFT Study. Inorganic Chemistry 63:11, pages 4819-4827.
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Eric A. Agyei & Jesse D. Carrick. (2023) Metal‐Free, Oxidative Condensation of Heteroaryl‐ and Aryl Carbaldehydes towards Functionalized Carbonitriles. ChemistrySelect 8:23.
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Abigail Jennifer G, Yang Gao, Georg Schreckenbach & Elumalai Varathan. (2023) Periodic Trends in the Stabilization of Actinyls in Their Higher Oxidation States Using Pyrrophen Ligands. Inorganic Chemistry 62:18, pages 6920-6933.
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Fortune O. Dzeagu & Jesse D. Carrick. (2022) Synthetic Access to Unsymmetric, Tridentate, Pyridyl-1,3,4-oxadiazole Complexants via Intramolecular Oxidative Annulation of Arylhydrazides with Heteroaryl Carbaldehydes. The Journal of Organic Chemistry 88:1, pages 419-432.
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Haitao Zhang, Xiaolin Hou, Jixin Qiao & Jianfeng Lin. (2022) Determination of 241Am in Environmental Samples: A Review. Molecules 27:14, pages 4536.
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Mariah L. Tedder, Fortune O. Dzeagu, Marcos M. Mason, David A. Dixon & Jesse D. Carrick. (2022) Microwave-assisted C–H oxidation of methylpyridylheteroarenes via a Kornblum-Type reaction. Tetrahedron 116, pages 132805.
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Cheriyan Ebenezer & Rajadurai Vijay Solomon. (2022) Uptake of Am(III) Ions and Eu(III) Ions Using Cyclic Substituted N, O‐hybrid 1,10‐Phenanthroline Derived Phosphine Oxide Ligands ‐ A DFT Exploration. ChemistrySelect 7:17.
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Cheriyan Ebenezer & Rajadurai Vijay Solomon. (2021) Does the length of the alkyl chain affect the complexation and selectivity of phenanthroline-derived phosphonate ligands? – Answers from DFT calculations. Polyhedron 210, pages 115533.
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Midhun George Thomas, Cheriyan Ebenezer & Rajadurai Vijay Solomon. (2021) Tuning the structure of disulfonated phenanthroline based ligands for effective separation of Am(III)/Eu(III) ions : A DFT investigation. Journal of Molecular Liquids 340, pages 117151.
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Arunasis Bhattacharyya, Avinash S. Kanekar, N.S. Karthikeyan, C. Ravichandran, B. Venkatachalapathy, T. Subba Rao, H. Seshadri & Prasanta K. Mohapatra. (2021) Aqueous soluble ‘N′ donor heterocyclic ligands for the mutual separation of Am3+ and Eu3+: Solvent extraction, flat sheet supported liquid membrane and hollow fiber microextraction studies. Journal of Environmental Chemical Engineering 9:5, pages 106041.
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Marcos M. Mason, Caris Smith, Monica Vasiliu, Jesse D. Carrick & David A. Dixon. (2021) Prediction of An(III)/Ln(III) Separation by 1,2,4-Triazinylpyridine Derivatives. The Journal of Physical Chemistry A 125:30, pages 6529-6542.
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Cheriyan Ebenezer & Rajadurai Vijay Solomon. (2021) Tailoring the selectivity of phenanthroline derivatives for the partitioning of trivalent Am/Eu ions – a relativistic DFT study. Inorganic Chemistry Frontiers 8:12, pages 3012-3024.
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Alexey I. Nemytov, Irina A. Utepova, Mikhail A. Kiskin, Nikolay N. Efimov, Matvey V. Fedin, Igor L. Eremenko, Alexandra A. Musikhina, Pavel A. Slepukhin & Oleg N. Chupakhin. (2021) Synthesis, structure and magnetic properties of binuclear 3d-metal complexes of new 3-(2-pyridyl)-6-phenyl-1,2,4-triazine derivative. Polyhedron 193, pages 114901.
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Cheriyan Ebenezer & Rajadurai Vijay Solomon. (2020) Insights into the Extraction of Actinides from Lanthanides Using 3,3’‐Dimethoxy‐phenyl‐bis‐1,2,4‐triazinyl‐2,6‐pyridine Ligand – A DFT Study. ChemistrySelect 5:44, pages 13895-13901.
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Zachary Z. Gulledge & Jesse D. Carrick. (2020) Deprotection of N ‐ tert ‐Butoxycarbonyl (Boc) Protected Functionalized Heteroarenes via Addition–Elimination with 3‐Methoxypropylamine . European Journal of Organic Chemistry 2020:12, pages 1817-1822.
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Gabrielle D. Waters & Jesse D. Carrick. (2020) Convergent access to bis-1,2,4-triazinyl-2,2′-bipyridines (BTBPs) and 2,2′-bipyridines via a Pd-catalyzed Ullman-type reaction . RSC Advances 10:18, pages 10807-10815.
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Zachary Z. Gulledge, Mariah L. Tedder, Kyle R. Lyons & Jesse D. Carrick. (2019) Synthesis of Tridentate [1,2,4] Triazinyl-Pyridin-2-yl Indole Lewis Basic Complexants via Pd-Catalyzed Suzuki–Miyaura Cross-Coupling. ACS Omega 4:20, pages 18855-18866.
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Sauradip Chaudhuri & Jesse D. Carrick. (2018) Synthetic Access to Functionalized Dipolarophiles of Lewis Basic Complexant Scaffolds through Sonogashira Cross-Coupling. The Journal of Organic Chemistry 83:17, pages 10261-10271.
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Kayron N. Tevepaugh, Janet Coonce, Serene Tai, Lætitia H. Delmau, Jesse D. Carrick & Dale D. Ensor. (2017) Chromatographic separation of americium from europium using bis-2,6-(5,6,7,8-tetrahydro-5,9,9-trimethyl-5,8-methano-1,2,4-benzotriazin-3-yl) pyridine. Journal of Radioanalytical and Nuclear Chemistry 314:1, pages 371-376.
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