Separation of americium from europium using 3,3′-dimethoxy-phenyl-bis-1,2,4-triazinyl-2,6-pyridine

References

• Mathur, J.N.; Murali, M.S.; Nash, K.L. (2001) Actinide Partitioning—A Review. Solvent Extraction and Ion Exchange, 19: 357–390.
   Web of Science ®Google Scholar
• Poinssot, C.; Rostaing, C.; Grandjean, S.; Boullis, B. (2012) Recycling the actinides, the Cornerstone of any sustainable nuclear fuel cycles. Procedia Chemical, 7: 349–357.
   Google Scholar
• Nuclear Non-Proliferation Act of 1978, U.S. Code, Section 3201, Title 22, 1978.
   Google Scholar
• Recktenwald, G.D.; Deinert, M.R. (2012) Cost probability analysis of reprocessing spent nuclear fuel in the US. Energy Economics, 34: 1873–1881.
   Web of Science ®Google Scholar
• Regalbuto, M.C. (2011) Alternative Separation and Extraction: UREX+ Processes for Actinide and Targeted Fission Product Recovery; Nash, K.L.; Lumetta, G.J. edsWoodhead Publishing Ltd: Cambridge, UK176–200
   Google Scholar
• Taylor, R.J.; Gregson, C.R.; Carrott, M.J.; Mason, C.; Sarsfield, M.J. (2013) Progress towards the full recovery of neptunium in an advanced PUREX process. Solvent Extraction and Ion Exchange, 31: 442–462.
   Web of Science ®Google Scholar
• Wagner, C.; Müllich, U.; Geist, A.; Panak, P.J. (2016) Selective extraction of Am(III) from PUREX raffinate: the AmSel system. Solvent Extraction and Ion Exchange, 34: 103–113.
   Web of Science ®Google Scholar
• OECD-NEA Potential Benefits and Impacts of Advanced Nuclear Fuel Cycles with Actinide Partitioning and Transmutation, NEA No. 6894, OECD, Nuclear Energy Agency (NEA), 2011.
   Google Scholar
• Magill, J.; Berthou, V.; Haas, D.; Galy, J.; Schenkel, R.; Wiese, H.-W.; Heusener, G.; Tommasi, J.; Youinou, G. (2003) Impact limits of partitioning and transmutation scenarios on the radiotoxicity of actinides in radioactive waste. Nuclear Energy, 42: 263–277.
   Google Scholar
• Choppin, G.; Nash, K. (1995) Actinide separation science. Radiochimica Acta, 70/71: 225–236.
   Web of Science ®Google Scholar
• Geist, A.; Müllich, U.; Magnusson, D.; Kaden, P.; Modolo, G.; Wilden, A.; Zevaco, T. (2012) Actinide(III)/lanthanide(III) separation via selective aqueous complexation of actinides(III) using a hydrophilic 2,6-Bis(1,2,4-Triazin-3-yl)-pyridine in nitric acid. Solvent Extraction and Ion Exchange, 30: 433–444.
   Web of Science ®Google Scholar
• Ekberg, C.; Fremvik, A.; Retegan, T.; Skarnemark, G.; Foreman, M.R.S.; Hudson, M.J.; Englund, S.; Nilsson, M. (2008) An overview and historical look back at the solvent extraction using nitrogen donor ligands to extract and separate An(III) from Ln(III). Radiochimica Acta, 96: 225−233.
   Web of Science ®Google Scholar
• Steppert, M.; Cisařova, T.; Fanghänel, T.; Geist, A.; Lindqvist-Reis, P.; Panak, P.; Štĕpnička, P.; Trumm, S.; Walther, C. (2012) Complexation of europium(III) by bis(dialkyltriazinyl)bipyridines in 1-octanol. Inorganic Chemical, 51: 591−600.
   PubMed Web of Science ®Google Scholar
• Lewis, F.W.; Harwood, L.M.; Hudson, M.J.; Distler, P.; John, J.; Stamberg, K.; Nunez, A.; Galan, H.; Espartero, A.G. (2012) Synthesis and evaluation of lipophilic BTBP ligands for An/Ln separation in nuclear waste treatment: The effect of alkyl substitution on extraction properties and implications for ligand design. European Journal Organic Chemical, 2012: 1509–1519.
   Web of Science ®Google Scholar
• Cotton, S. (2004) Scandium, yttrium, and the lanthanides. In Comprehensive Coordination Chemistry II, McCleverty, Jon A., Meyer, Thomas J. Eds. Elsevier: Oxford, 3: 93–188.
   Google Scholar
• Dam, H.H.; Reinhoundt, D.N.; Verboom, W. (2007) Multicoordinate ligands for actinide/lanthanide separations. Chemical Social Reviews, 36: 367–377.
   PubMed Web of Science ®Google Scholar
• Trumm, S.; Geist, A.; Panak, P.J.; Fanghänel, T. (2011) An improved Hydrolytically-Stable Bis-Triazinyl-Pyridine (BTP) for selective actinide extraction. Solvent Extraction and Ion Exchange, 29: 213–229.
   Web of Science ®Google Scholar
• Panak, P.J.; Geist, A. (2013) Complexation and extraction of trivalent actinides and lanthanides by triazinylpyridine N-Donor ligands. Chemical Reviews, 113: 1199–1236.
   PubMed Web of Science ®Google Scholar
• Kolarik, Z.; Müllich, U.; Gassner, F. (1999) Extraction of Am(III) and Eu(III) nitrates by 2,6-di(5,6-dripropyl-1,2,4-triazin-3-yl)pyridine. Solvent Extraction and Ion Exchange, 17: 1155–1183.
   Web of Science ®Google Scholar
• Kolarik, Z.; Müllich, U.; Gassner, F. (1999) Selective extraction of Am(III) over Eu(III) by 2,6-ditriazolyl- and 2,6-ditriazinylpyridines. Solvent Extraction and Ion Exchange, 17: 23−32.
   Web of Science ®Google Scholar
• Kolarik, Z.;. (2008) Complexation and separation of Lanthanides(III) and Actinides(III) by Heterocyclic N-Donors in solutions. Chemical Reviews, 108: 4208−4252.
   PubMed Web of Science ®Google Scholar
• Hill, C.; Guillaneux, D.; Berthon, L.; Madic, C. (2002) Sanex-BTP process development studies. Journal Nuclear Sciences Technology Supplement, 3: 309−313.
   Google Scholar
• Hudson, M.J.; Boucher, C.E.; Brealers, D.; Desreux, J.F.; Drew, M.G.; Foreman, R.S.; Harwood, L.M.; Hill, C.; Madic, C.; Marken, F.; Youngs, T.G.A. (2006) New bis(triazinyl) pyridines for selective extraction of americium(III). New Journal Chemical, 30, 1171.
   Web of Science ®Google Scholar
• Tevepaugh, K.N.; Carrick, J.D.; Tai, S.; Coonce, J.G.; Delmau, L.H.; Ensor, D.D. (2016) Separation of americium from europium using Camphor-BisTriazinyl pyridine: A fundamental study. Solvent Extraction and Ion Exchange, 34: 13–25.
   Web of Science ®Google Scholar
• Tai, S.; Marchi, S.V.; Carrick, J.D. (2015) Efficient preparation of Pyridinyl-1,2,4-Triazines via telescoped condensation with diversely functionalized 1,2-Dicarbonyls. Journal Heterocycl Chemistry, [Online early access]10.1002/jhet.2374Published Online: June 2015http://onlinelibrary.wiley.com/doi/10.1002/jhet.2374/full.
   Google Scholar
• Tai, S.; Williams, N.J.; Carrick, J.D. (2016) Synthesis of Bis-1,2,4-triazines via telescoped condensation of [1,10]-Phenanthroline-2,9-dicarbonitrile with aromatic 1,2-dicarbonyls. Journal Heterocycl Chemistry, 53: 307–312.
   Web of Science ®Google Scholar
• Chin, A.-L.; Carrick, J.D. (2016) Modular approaches to diversified soft lewis basic complexants through Suzuki-Miyaura cross-coupling of bromoheteroarenes with organotrifluoroborates. The Journal of Organic Chemistry, 81: 1106–1115.
   PubMed Web of Science ®Google Scholar
• Tai, S.; Marchi, S.V.; Dover, E.J.; Carrick, J.D. (2015) Pd-Catalyzed diamination of 1,2,4-Triazinyl complexant scaffolds. The Journal of Organic Chemistry, 80: 6275–6282.
   PubMed Web of Science ®Google Scholar
• Trumm, S.; Panak, P.J.; Geist, A.; Fanghänel, T. (2010) A TRFLS study on the complexation of Cm(III) and Eu(III) with 2,6-bis(5,6-dipropyl-1,2,4-triazin-3-yl)pyridine in water/methanol mixture. European Journal Inorganic Chemistry, 19: 3022–3028.
   Web of Science ®Google Scholar