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Original Articles

Direct Selective Extraction of Actinides(III) from PUREX Raffinate Using a Mixture of CyMe4-BTBP and TODGA as 1-cycle SANEX Solvent PART II: Flow-sheet Design for a Counter-Current Centrifugal Contactor Demonstration Process

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Pages 1-11 | Published online: 10 Dec 2012

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Thea Lyseid Authen, Jean-Marc Adnet, Stéphane Bourg, Michael Carrott, Christian Ekberg, Hitos Galán, Andreas Geist, Philippe Guilbaud, Manuel Miguirditchian, Giuseppe Modolo, Chris Rhodes, Andreas Wilden & Robin Taylor. (2022) An overview of solvent extraction processes developed in Europe for advanced nuclear fuel recycling, Part 2 — homogeneous recycling. Separation Science and Technology 57:11, pages 1724-1744.
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Andreas Geist, Jean-Marc Adnet, Stéphane Bourg, Christian Ekberg, Hitos Galán, Philippe Guilbaud, Manuel Miguirditchian, Giuseppe Modolo, Chris Rhodes & Robin Taylor. (2021) An overview of solvent extraction processes developed in Europe for advanced nuclear fuel recycling, part 1 — heterogeneous recycling. Separation Science and Technology 56:11, pages 1866-1881.
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Eros Mossini, Elena Macerata, Andreas Wilden, Peter Kaufholz, Giuseppe Modolo, Nicolò Iotti, Alessandro Casnati, Andreas Geist & Mario Mariani. (2018) Optimization and Single-Stage Centrifugal Contactor Experiments with the Novel Hydrophilic Complexant PyTri-Diol for the i-SANEX Process. Solvent Extraction and Ion Exchange 36:4, pages 373-386.
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Steve Lange, Andreas Wilden, Giuseppe Modolo, Fabian Sadowski, Markus Gerdes & Dirk Bosbach. (2017) Direct Selective Extraction of Trivalent Americium from PUREX Raffinate Using a Combination of CyMe4BTPhen and TEDGA—A Feasibility Study. Solvent Extraction and Ion Exchange 35:3, pages 161-173.
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Andreas Wilden, Giuseppe Modolo, Peter Kaufholz, Fabian Sadowski, Steve Lange, Michal Sypula, Daniel Magnusson, Udo Müllich, Andreas Geist & Dirk Bosbach. (2015) Laboratory-Scale Counter-Current Centrifugal Contactor Demonstration of an Innovative-SANEX Process Using a Water Soluble BTP. Solvent Extraction and Ion Exchange 33:2, pages 91-108.
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Daniel Magnusson, Andreas Geist, Rikard Malmbeck & Udo Müllich. (2013) Study of the Mass Transfer Behavior in a Centrifugal Contactor and Verification of the Solvent Extraction Model for the SX Process Program. Solvent Extraction and Ion Exchange 31:6, pages 578-589.
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Andreas Wilden, Giuseppe Modolo, Christian Schreinemachers, Fabian Sadowski, Steve Lange, Michal Sypula, Daniel Magnusson, Andreas Geist, Frank W. Lewis, Laurence M. Harwood & Michael J. Hudson. (2013) Direct Selective Extraction of Actinides (III) from PUREX Raffinate using a Mixture of CyMe4BTBP and TODGA as 1-cycle SANEX Solvent Part III: Demonstration of a Laboratory-Scale Counter-Current Centrifugal Contactor Process. Solvent Extraction and Ion Exchange 31:5, pages 519-537.
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Haolong Wang, Pengyuan Gao, Tengfei Cui, Dongqi Wang, Jinping Liu, Hui He, Zongyuan Chen, Qiang Jin & Zhijun Guo. (2024) New asymmetric tetradentate phenanthroline chelators with pyrazole and amide groups for complexation and solvent extraction of Ln( iii )/Am( iii ) . Dalton Transactions.
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Lei Xu, Wenya Ding, Anyun Zhang & Ziyang Liu. (2022) Effect of ligand initial conformation and counteranion on complexation behaviors of R-BTBP toward Pd(II) contained in highly active liquid waste. Chinese Chemical Letters 33:7, pages 3565-3569.
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Andreas Wilden, Dimitri Schneider, Zaina Paparigas, Maximilian Henkes, Fabian Kreft, Andreas Geist, Eros Mossini, Elena Macerata, Mario Mariani, Maria Chiara Gullo, Alessandro Casnati & Giuseppe Modolo. (2022) Selective actinide(III) separation using 2,6-bis[1-(propan-1-ol)-1,2,3-triazol-4-yl]pyridine (PyTri-Diol) in the innovative-SANEX process: laboratory scale counter current centrifugal contactor demonstration. Radiochimica Acta 110:6-9, pages 515-525.
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Alastair Baker, Alex Fells, Michael J. Carrott, Chris J. Maher & Bruce C. Hanson. (2022) Process intensification of element extraction using centrifugal contactors in the nuclear fuel cycle. Chemical Society Reviews 51:10, pages 3964-3999.
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Thomas M. Trunks, Jasraj Singh Babra, James Westwood & Christopher D. Smith. (2022) A Homocoupling Approach to the Key Dione of CyMe4-BTPhen – Vital Ligands for Nuclear Clean-Up by the SANEX Process. SynOpen 06:01, pages 16-18.
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Holger Schmidt, Andreas Wilden, Giuseppe Modolo, Dirk Bosbach, Beatrix Santiago-Schübel, Michelle Hupert, Bruce J. Mincher, Stephen P. Mezyk, Jaroslav Švehla, Bohumir Grüner & Christian Ekberg. (2021) Gamma and pulsed electron radiolysis studies of CyMe4BTBP and CyMe4BTPhen: Identification of radiolysis products and effects on the hydrometallurgical separation of trivalent actinides and lanthanides. Radiation Physics and Chemistry 189, pages 109696.
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Ruixue Meng, Lei Xu, Xiao Yang, Mingze Sun, Chao Xu, Nataliya E. Borisova, Xingwang Zhang, Lecheng Lei & Chengliang Xiao. (2021) Influence of a N-Heterocyclic Core on the Binding Capability of N,O-Hybrid Diamide Ligands toward Trivalent Lanthanides and Actinides. Inorganic Chemistry 60:12, pages 8754-8764.
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Péter Zsabka, Karen Van Hecke, Lesley Adriaensen, Andreas Wilden, Giuseppe Modolo, Marc Verwerft, Koen Binnemans & Thomas Cardinaels. (2021) Selective extraction of trivalent actinides using CyMe 4 BTPhen in the ionic liquid Aliquat-336 nitrate . RSC Advances 11:11, pages 6014-6021.
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Umesh Fegade. 2021. Green Sustainable Process for Chemical and Environmental Engineering and Science. Green Sustainable Process for Chemical and Environmental Engineering and Science 1 19 .
Fangfang Wu, Hongbin Lv, Xihong He, Zhongping Cheng, Hongwei Jia, Shubao Xie, Yuekun Liu, Guoan Ye & Hui He. (2019) Selective Am(III) stripping with water-soluble PyTri-Diol in nitric acid from HDEHP organic phase. Journal of Radioanalytical and Nuclear Chemistry 323:1, pages 283-289.
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Anyun Zhang, Huimin Wu, Hao Fu, Zhanghao Xu & Yanqin Ji. (2019) Highly Selective Adsorption of New Bis-Opened-Triazine Materials Hybridized with a Cross-Linked Polymer Support for Palladium and Some Typical Coexisting Metals. Journal of Chemical & Engineering Data 64:4, pages 1529-1537.
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Ying Liu, Xiuying Yang, Songdong Ding, Zhipeng Wang, Lirong Zhang, Lianjun Song, Zhili Chen & Xueyu Wang. (2018) Highly Efficient Trivalent Americium/Europium Separation by Phenanthroline-Derived Bis(pyrazole) Ligands. Inorganic Chemistry 57:10, pages 5782-5790.
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Santa Jansone-Popova, Alexander S. Ivanov, Vyacheslav S. Bryantsev, Frederick V. SloopJr.Jr., Radu Custelcean, Ilja Popovs, Madeline M. Dekarske & Bruce A. Moyer. (2017) Bis-lactam-1,10-phenanthroline (BLPhen), a New Type of Preorganized Mixed N,O-Donor Ligand That Separates Am(III) over Eu(III) with Exceptionally High Efficiency. Inorganic Chemistry 56:10, pages 5911-5917.
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Arunasis Bhattacharyya, Manoj Mohapatra, Prasanta K. Mohapatra, Trilochan Gadly, Sunil K. Ghosh, Debashree Manna, Tapan K. Ghanty, Neetika Rawat & Bhupendra S. Tomar. (2016) An Insight into the Complexation of Trivalent Americium Vis‐à‐Vis Lanthanides with Bis(1,2,4‐triazinyl)bipyridine Derivatives. European Journal of Inorganic Chemistry 2017:4, pages 820-828.
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Anyun Zhang, Wenjing Xue & Xinchen Dong. (2016) Minor Actinides Partitioning: Uptake of Palladium with Triazine-Containing Adsorbent under the Framework of SPMP Process. Journal of Chemical & Engineering Data 61:9, pages 3303-3310.
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Anyun Zhang, Lei Xu & Gaoming Lei. (2016) Separation and complexation of palladium( ii ) with a new soft N-donor ligand 6,6′-bis(5,6-dinonyl-1,2,4-triazin-3-yl)-2,2′-bipyridine (C9-BTBP) in nitric acid medium . New Journal of Chemistry 40:7, pages 6374-6383.
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Frank W. Lewis, Laurence M. Harwood, Michael J. Hudson, Udo Müllich & Andreas Geist. (2015) Efficient masking of corrosion and fission products such as Ni( ii ) and Pd( ii ) in the presence of the minor actinide Am( iii ) using hydrophilic anionic or cationic bis-triazines . Chemical Communications 51:44, pages 9189-9192.
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Giuseppe Modolo, Andreas Geist & Manuel Miguirditchian. 2015. Reprocessing and Recycling of Spent Nuclear Fuel. Reprocessing and Recycling of Spent Nuclear Fuel 245 287 .
Clint A. Sharrad & Daniel M. Whittaker. 2015. Reprocessing and Recycling of Spent Nuclear Fuel. Reprocessing and Recycling of Spent Nuclear Fuel 153 189 .
G. Modolo, A. Wilden, P. Kaufholz, D. Bosbach & A. Geist. (2014) Development and demonstration of innovative partitioning processes (i-SANEX and 1-cycle SANEX) for actinide partitioning. Progress in Nuclear Energy 72, pages 107-114.
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Frank W. Lewis, Laurence M. Harwood, Michael J. Hudson, Michael G. B. Drew, Véronique Hubscher-Bruder, Vladimira Videva, Françoise Arnaud-Neu, Karel Stamberg & Shyam Vyas. (2013) BTBPs versus BTPhens: Some Reasons for Their Differences in Properties Concerning the Partitioning of Minor Actinides and the Advantages of BTPhens. Inorganic Chemistry 52:9, pages 4993-5005.
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Petra J. Panak & Andreas Geist. (2013) Complexation and Extraction of Trivalent Actinides and Lanthanides by Triazinylpyridine N -Donor Ligands . Chemical Reviews 113:2, pages 1199-1236.
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Michael J. Hudson, Frank W. Lewis & Laurence M. Harwood. 2013. 177 202 .
Andreas Wilden, Giuseppe Modolo, Michal Sypula, Andreas Geist & Daniel Magnusson. (2012) The Recovery of An(Iii) in an Innovative-Sanex Process using a Todga-based Solvent and Selective Stripping with a Hydrophilic BTP. Procedia Chemistry 7, pages 418-424.
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Daniel Magnusson, Andreas Geist, Rikard Malmbeck, Giuseppe Modolo & Andreas Wilden. (2012) Flow-Sheet Design for an Innovative SANEX Process Using TODGA and SO3-Ph-BTP. Procedia Chemistry 7, pages 245-250.
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