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Solvent Extraction and Ion Exchange Volume 32, 2014 - Issue 2
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Original Articles

Modified Diglycolamides for the An(III) + Ln(III) Co-separation: Evaluation by Solvent Extraction and Time-Resolved Laser Fluorescence Spectroscopy

Andreas Wilden Forschungszentrum Jülich GmbH (FZJ), Institut für Energie- und Klimaforschung, Nukleare Entsorgung und Reaktorsicherheit (IEK-6), Jülich, GermanyCorrespondence[email protected]
,
Giuseppe Modolo Forschungszentrum Jülich GmbH (FZJ), Institut für Energie- und Klimaforschung, Nukleare Entsorgung und Reaktorsicherheit (IEK-6), Jülich, Germany
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Steve Lange Forschungszentrum Jülich GmbH (FZJ), Institut für Energie- und Klimaforschung, Nukleare Entsorgung und Reaktorsicherheit (IEK-6), Jülich, Germany
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Fabian Sadowski Forschungszentrum Jülich GmbH (FZJ), Institut für Energie- und Klimaforschung, Nukleare Entsorgung und Reaktorsicherheit (IEK-6), Jülich, Germany
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Björn B. Beele Ruprecht-Karls-Universität Heidelberg, Physikalisch Chemisches Institut (PCI), Heidelberg, Germany; Karlsruher Institut für Technologie (KIT), Institut für Nukleare Entsorgung (INE), Karlsruhe, Germany
,
Andrej Skerencak-Frech Karlsruher Institut für Technologie (KIT), Institut für Nukleare Entsorgung (INE), Karlsruhe, Germany
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Petra J. Panak Ruprecht-Karls-Universität Heidelberg, Physikalisch Chemisches Institut (PCI), Heidelberg, Germany; Karlsruher Institut für Technologie (KIT), Institut für Nukleare Entsorgung (INE), Karlsruhe, Germany
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Mudassir Iqbal University of Twente, Laboratory of Molecular Nanofabrication, MESA+ Institute for Nanotechnology, Enschede, The Netherlands; Department of Chemistry, University of Sargodha, Sargodha, Pakistan
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Willem Verboom University of Twente, Laboratory of Molecular Nanofabrication, MESA+ Institute for Nanotechnology, Enschede, The Netherlands
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Andreas Geist Karlsruher Institut für Technologie (KIT), Institut für Nukleare Entsorgung (INE), Karlsruhe, Germany
&
Dirk Bosbach Forschungszentrum Jülich GmbH (FZJ), Institut für Energie- und Klimaforschung, Nukleare Entsorgung und Reaktorsicherheit (IEK-6), Jülich, Germany
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Pages 119-137 | Published online: 24 Jan 2014

Citations (54)

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Christopher A. Zarzana, Jack McAlpine, Andreas Wilden, Michelle Hupert, Andrea Stärk, Mudassir Iqbal, Willem Verboom, Bruce J. Mincher, Gary S. Groenewold & Giuseppe Modolo. (2023) Gamma Radiolysis of Phenyl-Substituted TODGAs: Part I. Solvent Extraction and Ion Exchange 41:5, pages 564-581.
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Eduardo Rodríguez de San Miguel, René González-Albarrán & Yahsé Rojas-Challa. (2023) Conditional Equilibrium Constants Reviewed. Critical Reviews in Analytical Chemistry 53:4, pages 775-797.
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Bart Verlinden, Andreas Wilden, Karen Van Hecke, Richard J. M. Egberink, Jurriaan Huskens, Willem Verboom, Michelle Hupert, Patrik Weßling, Andreas Geist, Petra J. Panak, Rainier Hermans, Marc Verwerft, Giuseppe Modolo, Koen Binnemans & Thomas Cardinaels. (2023) Solvent Optimization Studies for a New EURO-GANEX Process with 2,2’-Oxybis(N,N-di-n-decylpropanamide) (mTDDGA) and Its Radiolysis Products. Solvent Extraction and Ion Exchange 41:1, pages 59-87.
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Larissa Klaß, Andreas Wilden, Fabian Kreft, Christoph Wagner, Andreas Geist, Petra J. Panak, Irena Herdzik-Koniecko, Jerzy Narbutt & Giuseppe Modolo. (2019) Evaluation of the Hydrophilic Complexant N,N,N’,N’-tetraethyldiglycolamide (TEDGA) and its Methyl-substituted Analogues in the Selective Am(III) Separation. Solvent Extraction and Ion Exchange 37:5, pages 297-312.
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Peter Zsabka, Karen Van Hecke, Lesley Adriaensen, Andreas Wilden, Giuseppe Modolo, Marc Verwerft, Koen Binnemans & Thomas Cardinaels. (2018) Solvent Extraction of Am(III), Cm(III), and Ln(III) Ions from Simulated Highly Active Raffinate Solutions by TODGA Diluted in Aliquat-336 Nitrate Ionic Liquid. Solvent Extraction and Ion Exchange 36:6, pages 519-541.
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Daniel Whittaker, Andreas Geist, Giuseppe Modolo, Robin Taylor, Mark Sarsfield & Andreas Wilden. (2018) Applications of Diglycolamide Based Solvent Extraction Processes in Spent Nuclear Fuel Reprocessing, Part 1: TODGA. Solvent Extraction and Ion Exchange 36:3, pages 223-256.
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Elena Macerata, Annalisa Ossola, Walter Panzeri, Marco Giola, Federica Faroldi, Dario Alberto Tinonin, Andrea Mele, Alessandro Casnati & Mario Mariani. (2018) Actinide–lanthanide co-extraction by rigidified diglycolamides. Solvent Extraction and Ion Exchange 36:1, pages 41-53.
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M. E. Case, R. V. Fox, D. L. Baek, B. J. Mincher & C. M. Wai. (2017) Extraction behavior of selected rare earth metals from acidic chloride media using tetrabutyl diglycolamide. Solvent Extraction and Ion Exchange 35:7, pages 496-506.
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Steve Lange, Andreas Wilden, Giuseppe Modolo, Fabian Sadowski, Markus Gerdes & Dirk Bosbach. (2017) Direct Selective Extraction of Trivalent Americium from PUREX Raffinate Using a Combination of CyMe4BTPhen and TEDGA—A Feasibility Study. Solvent Extraction and Ion Exchange 35:3, pages 161-173.
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Peter Kaufholz, Giuseppe Modolo, Andreas Wilden, Fabian Sadowski, Dirk Bosbach, Christoph Wagner, Andreas Geist, Petra J. Panak, Frank W. Lewis & Laurence M. Harwood. (2016) Solvent Extraction and Fluorescence Spectroscopic Investigation of the Selective Am(III) Complexation with TS-BTPhen. Solvent Extraction and Ion Exchange 34:2, pages 126-140.
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Christoph Wagner, Udo Müllich, Andreas Geist & Petra J. Panak. (2016) Selective Extraction of Am(III) from PUREX Raffinate: The AmSel System. Solvent Extraction and Ion Exchange 34:2, pages 103-113.
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Jammu Ravi, K. A. Venkatesan, M. P. Antony, T. G. Srinivasan & P. R. Vasudeva Rao. (2016) Solvent extraction behavior of trivalent metal ions in diglycolamides having same carbon to oxygen ratio. Separation Science and Technology 51:1, pages 32-40.
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Christopher A. Zarzana, Gary S. Groenewold, Bruce J. Mincher, Stephen P. Mezyk, Andreas Wilden, Holger Schmidt, Giuseppe Modolo, James F. Wishart & Andrew R. Cook. (2015) A Comparison of the γ-Radiolysis of TODGA and T(EH)DGA Using UHPLC-ESI-MS Analysis. Solvent Extraction and Ion Exchange 33:5, pages 431-447.
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Bart Verlinden, Karen Van Hecke, Andreas Wilden, Giuseppe Modolo, Koen Binnemans, Thomas Cardinaels & Piotr M. Kowalski. (2023) First-principles study of the radiolytic degradation of diglycolamides. Radiochimica Acta 0:0.
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Hao-Liang Chen, Bin Zhou, Ming Qi, Yao Zou, Hua-Wu Pei, Peng Ren & Ping-Wen Huang. (2023) Selective separation of Pu(IV) and U(VI) with bisdiglycolamde ligands: solvent extraction and DFT calculations. Journal of Radioanalytical and Nuclear Chemistry 332:8, pages 3361-3369.
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