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Original Articles

New Insight into the Americium/Curium Separation by Solvent Extraction using Diglycolamides

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Read on this site (13)

Marie Simonnet, Yuji Sasaki & Tsuyoshi Yaita. (2023) Combining a Lipophilic Phenanthroline Carboxamide and a Hydrophilic Diglycolamide to Increase the Separation Factors of Adjacent Light Lanthanides. Solvent Extraction and Ion Exchange 41:7, pages 857-867.
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Gauthier J.-P. Deblonde, Alexandre Chagnes & Gérard Cote. (2023) Recent Advances in the Chemistry of Hydrometallurgical Methods. Separation & Purification Reviews 52:3, pages 221-241.
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Petr Matveev, Prasanta K. Mohapatra, Stepan N. Kalmykov & Vladimir Petrov. (2021) Solvent extraction systems for mutual separation of Am(III) and Cm(III) from nitric acid solutions. A review of recent state-of-the-art. Solvent Extraction and Ion Exchange 39:7, pages 679-713.
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Andreas Geist, Jean-Marc Adnet, Stéphane Bourg, Christian Ekberg, Hitos Galán, Philippe Guilbaud, Manuel Miguirditchian, Giuseppe Modolo, Chris Rhodes & Robin Taylor. (2021) An overview of solvent extraction processes developed in Europe for advanced nuclear fuel recycling, part 1 — heterogeneous recycling. Separation Science and Technology 56:11, pages 1866-1881.
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Manuel Miguirditchian, Vincent Vanel, Cécile Marie, Vincent Pacary, Marie-Christine Charbonnel, Laurence Berthon, Xavier Hérès, Marc Montuir, Christian Sorel, Marie-Jordane Bollesteros, Sylvain Costenoble, Christine Rostaing, Michel Masson & Christophe Poinssot. (2020) Americium Recovery from Highly Active PUREX Raffinate by Solvent Extraction: The EXAm Process. A Review of 10 Years of R&D. Solvent Extraction and Ion Exchange 38:4, pages 365-387.
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Larissa Klaß, Andreas Wilden, Fabian Kreft, Christoph Wagner, Andreas Geist, Petra J. Panak, Irena Herdzik-Koniecko, Jerzy Narbutt & Giuseppe Modolo. (2019) Evaluation of the Hydrophilic Complexant N,N,N’,N’-tetraethyldiglycolamide (TEDGA) and its Methyl-substituted Analogues in the Selective Am(III) Separation. Solvent Extraction and Ion Exchange 37:5, pages 297-312.
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Cécile Marie, Peter Kaufholz, Vincent Vanel, Marie-Thérèse Duchesne, Emilie Russello, Federica Faroldi, Laura Baldini, Alessandro Casnati, Andreas Wilden, Giuseppe Modolo & Manuel Miguirditchian. (2019) Development of a Selective Americium Separation Process Using H4TPAEN as Water-Soluble Stripping Agent. Solvent Extraction and Ion Exchange 37:5, pages 313-327.
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Łukasz Steczek, Jerzy Narbutt, Marie-Christine Charbonnel & Philippe Moisy. (2019) Solvent Extraction Investigations on Pu(IV) and Th(IV) Complexes with Hydrophilic SO3-Ph-BTP and SO3-Ph-BTBP Ligands. Solvent Extraction and Ion Exchange 37:3-4, pages 259-268.
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Frank W. Lewis, Laurence M. Harwood, Michael J. Hudson, Ashfaq Afsar, Dominic M. Laventine, Kamila Šťastná, Jan John & Petr Distler. (2018) Separation of the Minor Actinides Americium(III) and Curium(III) by Hydrophobic and Hydrophilic BTPhen ligands: Exploiting Differences in their Rates of Extraction and Effective Separations at Equilibrium. Solvent Extraction and Ion Exchange 36:2, pages 115-135.
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Hideya Suzuki, Yasuhiro Tsubata, Tatsuya Kurosawa, Hiroshi Sagawa & Tatsuro Matsumura. (2017) Continuous extraction and separation of Am(III) and Cm(III) using a highly practical diamide amine extractant. Journal of Nuclear Science and Technology 54:11, pages 1163-1167.
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Steve Lange, Andreas Wilden, Giuseppe Modolo, Fabian Sadowski, Markus Gerdes & Dirk Bosbach. (2017) Direct Selective Extraction of Trivalent Americium from PUREX Raffinate Using a Combination of CyMe4BTPhen and TEDGA—A Feasibility Study. Solvent Extraction and Ion Exchange 35:3, pages 161-173.
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Christoph Wagner, Udo Müllich, Andreas Geist & Petra J. Panak. (2016) Selective Extraction of Am(III) from PUREX Raffinate: The AmSel System. Solvent Extraction and Ion Exchange 34:2, pages 103-113.
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Articles from other publishers (37)

Vladislav E. Sharov, Galina V. Kostikova, Mikhail S. Grigoriev & Alexandr A. Fedoseev. (2023) Solvent extraction of Eu(III), Am(III) and Cm(III) by N,N,N’,N’-tetrabutyldiglycolamide: Can the diluent participate in the extraction?. Polyhedron 244, pages 116590.
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Brian M. Rotermund, Joseph M. Sperling, Gregory P. Horne, Nicholas B. Beck, Hannah B. Wineinger, Zhuanling Bai, Cristian Celis-Barros, Daniela Gomez Martinez & Thomas E. Albrecht-Schönzart. (2023) Co-Crystallization of Plutonium(III) and Plutonium(IV) Diglycolamides with Pu(III) and Pu(IV) Hexanitrato Anions: A Route to Redox Variants of [Pu III,IV (DGA) 3 ][Pu III,IV (NO 3 ) 6 ] x . Inorganic Chemistry 62:32, pages 12905-12912.
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P. Zsabka, A. Wilden, K. Van Hecke, G. Modolo, M. Verwerft & T. Cardinaels. (2023) Beyond U/Pu separation: Separation of americium from the highly active PUREX raffinate. Journal of Nuclear Materials 581, pages 154445.
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Hideya Suzuki & Yasutoshi Ban. (2023) Efficient separation of americium by a mixed solvent of two extractants, a diamideamine and a nitrilotriacetamide. Analytical Sciences 39:8, pages 1341-1348.
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V. E. Sharov & G. V. Kostikova. (2023) Influence of the Nature of the Diluent on the Extraction of Eu(III), Am(III), and Cm(III) with N,N,Nꞌ,Nꞌ-Tetrabutyldiglycolamide from Nitric Acid Solutions. Radiochemistry 65:1, pages 45-51.
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Ling Li, Chengjin Xu, Xiujing Peng, Miaomiao Zhang, Shah Zeb, Xu Jiang, Yan Liu, Yu Cui & Guoxin Sun. (2021) Extraction and separation of Pd(II) by N, N'-diethyl-N, N'-dicyclohexylmalonamide in a nitric acid system. Separation and Purification Technology 277, pages 119479.
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V.L. Vidanov, A.Yu. Shadrin, L.I. Tkachenko, E.V. Kenf, P.V. Parabin & S.S. Shirokov. (2021) Separation of americium and curium for transmutation in the fast neutron reactor. Nuclear Engineering and Design 385, pages 111434.
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Gauthier J.-P. Deblonde, Joseph A. Mattocks, Huan Wang, Eric M. Gale, Annie B. Kersting, Mavrik Zavarin & Joseph A. CotruvoJr.Jr.. (2021) Characterization of Americium and Curium Complexes with the Protein Lanmodulin: A Potential Macromolecular Mechanism for Actinide Mobility in the Environment. Journal of the American Chemical Society 143:38, pages 15769-15783.
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Arunasis Bhattacharyya, S. A. Ansari, N. S. Karthikeyan, C. Ravichandran, B. Venkatachalapathy, T. S. Rao, H. Seshadri & P. K. Mohapatra. (2021) Bis-(1,2,4-triazin-3-yl) ligand structure driven selectivity reversal between Am 3+ and Cm 3+ : solvent extraction and DFT studies . Dalton Transactions 50:22, pages 7783-7790.
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Pin-Wen Huang, Cong-Zhi Wang, Qun-Yan Wu, Jian-Hui Lan, Zhi-Fang Chai & Wei-Qun Shi. (2021) Enhancing the Am 3+ /Cm 3+ separation ability by weakening the binding affinity of N donor atoms: a comparative theoretical study of N, O combined extractants . Dalton Transactions 50:10, pages 3559-3567.
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Miaomiao Zhang, Xiujing Peng, Jianhui Su, Zhen Yang, Shah Zeb, Ling Li, Chengjin Xu, Yiming Zhao, Guoxin Sun & Yu Cui. (2021) Highly efficient extraction separation of La3+ and Ce3+ with N, N, N′, N′-tetraisobutyl-3-oxadiglycolamide from mixed REEs. Separation and Purification Technology 258, pages 118012.
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Tomohiro Toigawa, Dean R. Peterman, David S. Meeker, Travis S. Grimes, Peter R. Zalupski, Stephen P. Mezyk, Andrew R. Cook, Shinichi Yamashita, Yuta Kumagai, Tatsuro Matsumura & Gregory P. Horne. (2021) Radiation-induced effects on the extraction properties of hexa- n -octylnitrilo-triacetamide (HONTA) complexes of americium and europium . Physical Chemistry Chemical Physics 23:2, pages 1343-1351.
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Xiujing Peng, Xiaolei Liu, Yu Cui, Yulan Li, Jifei Ma & Guoxin Sun. (2020) Adsorption of uranyl ion with polymer spheres modified by diamide. Journal of Radioanalytical and Nuclear Chemistry 327:1, pages 395-402.
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Zhili Chen, Xiuying Yang, Lianjun Song, Xueyu Wang, Qian Xiao, Haowei Xu, Qiuxia Feng & Songdong Ding. (2020) Extraction and complexation of trivalent rare earth elements with tetraalkyl diglycolamides. Inorganica Chimica Acta 513, pages 119928.
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Andreas Wilden, Fabian Kreft, Dimitri Schneider, Zaina Paparigas, Giuseppe Modolo, Gregg J. Lumetta, Artem V. Gelis, Jack D. Law & Andreas Geist. (2020) Countercurrent Actinide Lanthanide Separation Process (ALSEP) Demonstration Test with a Simulated PUREX Raffinate in Centrifugal Contactors on the Laboratory Scale. Applied Sciences 10:20, pages 7217.
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Ning Wang, Yi Li, Lei Xie, Fan Zhang, Kai-Qiang Ma, Xi-Peng Chen, Sheng Hu, Chu-Ting Yang & Xiao-Lin Wang. (2020) Cerium separation with NaBiO 3 nanoflower material via an oxidation adsorption strategy . Journal of Materials Chemistry A 8:16, pages 7907-7913.
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Jerzy Narbutt. 2020. Liquid-Phase Extraction. Liquid-Phase Extraction 725 744 .
Gregory P. Horne, Andreas Wilden, Stephen P. Mezyk, Liam Twight, Michelle Hupert, Andrea Stärk, Willem Verboom, Bruce J. Mincher & Giuseppe Modolo. (2019) Gamma radiolysis of hydrophilic diglycolamide ligands in concentrated aqueous nitrate solution. Dalton Transactions 48:45, pages 17005-17013.
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Xiujing Peng, Jixun Han, Guangzheng Yuan, Jialin Zhao, Yu Cui & Guoxin Sun. (2019) Separation of Pr(III) and Fe(III) by unsymmetrical diglycolamides from nitric acid media. Separation and Purification Technology 217, pages 294-298.
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Andreas Wilden, Piotr M. Kowalski, Larissa Klaß, Benjamin Kraus, Fabian Kreft, Giuseppe Modolo, Yan Li, Jörg Rothe, Kathy Dardenne, Andreas Geist, Andrea Leoncini, Jurriaan Huskens & Willem Verboom. (2019) Unprecedented Inversion of Selectivity and Extraordinary Difference in the Complexation of Trivalent f  Elements by Diastereomers of a Methylated Diglycolamide . Chemistry – A European Journal 25:21, pages 5507-5513.
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Ying Dai, Bin Cao, Shimin Zhong, Guanbao Xie, Youqun Wang, Yuhui Liu, Zhibin Zhang, Yunhai Liu & Xiaohong Cao. (2019) Homogeneous liquid–liquid extraction of europium from aqueous solution with ionic liquids. Journal of Radioanalytical and Nuclear Chemistry 319:3, pages 1219-1225.
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Pierre Farger, Blaise Haidon, Pascal Roussel, Bénédicte Arab-Chapelet & Murielle Rivenet. (2019) Crystal Growth in the Thorium-TEDGA-Oxalate-Nitrate System: Description and Comparison of the Main Structural Features. Inorganic Chemistry 58:2, pages 1267-1277.
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Annalisa Ossola, Elena Macerata, Eros Mossini, Marco Giola, Maria Chiara Gullo, Arturo Arduini, Alessandro Casnati & Mario Mariani. (2018) 2,6-Bis(1-alkyl-1H-1,2,3-triazol-4-yl)-pyridines: selective lipophilic chelating ligands for minor actinides. Journal of Radioanalytical and Nuclear Chemistry 318:3, pages 2013-2022.
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Nishesh Kumar Gupta. (2018) Ionic liquids for TRansUranic Extraction (TRUEX)—Recent developments in nuclear waste management: A review. Journal of Molecular Liquids 269, pages 72-91.
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Chu-Ting Yang, Jun Han, Jun Liu, Yi Li, Fan Zhang, Hai-Zhu Yu, Sheng Hu & Xiaolin Wang. (2018) Pd-Catalyzed Vinylation of Aryl Halides with Inexpensive Organosilicon Reagents Under Mild Conditions. Chemistry - A European Journal 24:41, pages 10324-10328.
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Seraj A. Ansari, Prasanta K. Mohapatra, Sk. Musharaf Ali, Neetika Rawat, Bhupinder S. Tomar, Andrea Leoncini, Jurriaan Huskens & Willem Verboom. (2018) Complexation thermodynamics of tetraalkyl diglycolamides with trivalent f-elements in ionic liquids: spectroscopic, microcalorimetric and computational studies. New Journal of Chemistry 42:1, pages 708-716.
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Nathalie Boubals, Christoph Wagner, Thomas Dumas, Léa Chanèac, Gabriel Manie, Peter Kaufholz, Cécile Marie, Petra J. Panak, Giuseppe Modolo, Andreas Geist & Philippe Guilbaud. (2017) Complexation of Actinide(III) and Lanthanide(III) with H 4 TPAEN for a Separation of Americium from Curium and Lanthanides . Inorganic Chemistry 56:14, pages 7861-7869.
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Dattaprasad R. Prabhu, Dhaval R. Raut, Mallekav S. Murali & Prasanta K. Mohapatra. (2017) Extraction of plutonium(IV) by diglycolamide extractants in room temperature ionic liquids. Radiochimica Acta 105:4, pages 285-293.
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Arijit Sengupta, Arunasis Bhattacharyya, Willem Verboom, Sk. Musharaf Ali & Prasanta K. Mohapatra. (2017) Insight into the Complexation of Actinides and Lanthanides with Diglycolamide Derivatives: Experimental and Density Functional Theoretical Studies. The Journal of Physical Chemistry B 121:12, pages 2640-2649.
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Hideya Suzuki, Yasuhiro Tsubata & Tatsuro Matsumura. (2017) High-Performance Alkyl Diamide Amine and Water-soluble Diamide Ligand for Separating of Am(III) from Cm(III). Analytical Sciences 33:2, pages 239-242.
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Fei Kou, Suliang Yang, Lihua Zhang, Simon J. Teat & Guoxin Tian. (2016) Complexation of Ho(III) with tetraalkyl-diglycolamide in aqueous solutions and a solid state compared in organic solutions of solvent extraction. Inorganic Chemistry Communications 71, pages 41-44.
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Tomoya Suzuki, Keisuke Morita, Yuji Sasaki & Tatsuro Matsumura. (2016) Recovery of Rhodium(III) from Nitric Acid Solutions Using Adsorbent Functionalized with N , N , N -Trimethylglycine . Bulletin of the Chemical Society of Japan 89:5, pages 608-616.
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Fei Kou, Suliang Yang, Hongjuan Qian, Lihua Zhang, Christine M. Beavers, Simon J. Teat & Guoxin Tian. (2016) A fluorescence study on the complexation of Sm( iii ), Eu( iii ) and Tb( iii ) with tetraalkyldiglycolamides (TRDGA) in aqueous solution, in solid state, and in solvent extraction . Dalton Transactions 45:46, pages 18484-18493.
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Andreas Geist, Robin Taylor, Christian Ekberg, Philippe Guilbaud, Giuseppe Modolo & Stéphane Bourg. (2016) The SACSESS Hydrometallurgy Domain — An Overview. Procedia Chemistry 21, pages 218-222.
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S. Chapron, C. Marie, V. Pacary, M.-T. Duchesne, G. Arrachart, S. Pellet-Rostaing & M. Miguirditchian. (2016) Separation of Americium by Liquid-Liquid Extraction Using Diglycolamides Water-Soluble Complexing Agents. Procedia Chemistry 21, pages 133-139.
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Stéphanie Gracia, Guilhem Arrachart, Cécile Marie, Simon Chapron, Manuel Miguirditchian & Stéphane Pellet-Rostaing. (2015) Separation of Am (III) by solvent extraction using water-soluble H4tpaen derivatives. Tetrahedron 71:33, pages 5321-5336.
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Ashfaq Afsar, Laurence M. Harwood, Michael J. Hudson, James Westwood & Andreas Geist. (2015) Effective separation of the actinides Am( iii ) and Cm( iii ) by electronic modulation of bis-(1,2,4-triazin-3-yl)phenanthrolines . Chemical Communications 51:27, pages 5860-5863.
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