804
Views
50
CrossRef citations to date
0
Altmetric
Original Articles

New Insight into the Americium/Curium Separation by Solvent Extraction using Diglycolamides

, , , &

REFERENCES

  • Poinssot, C.; Rostaing, C.; Baron, P.; Warin, D.; Boullis, B. Main results of the French program on partitioning of minor actinides: A significant improvement towards nuclear waste reduction. Procedia Chem. 2012, 7, 358–366.
  • Ansari, S. A.; Pathak, P.; Mohapatra, P. K.; Manchanda, V. K. Aqueous partitioning of minor actinides by different processes. Sep. Purif. Rev. 2011, 40, 43–76.
  • Poinssot, C.; Rostaing, C.; Grandjean, S.; Boullis, B. Recycling the actinides, the Cornerstone of any sustainable nuclear fuel cycles. Procedia Chem. 2012, 7, 349–357.
  • Rostaing, C.; Poinssot, C.; Warin, D.; Baron, P.; Lorrain, B. Development and validation of the EXAm separation process for single Am recycling. Procedia Chem. 2012, 7, 367–373.
  • Sasaki, Y.; Suzuki, H.; Sugo, Y.; Kimura, T.; Choppin, G. R. New water-soluble organic ligands for actinide cations complexation. Chem. Lett. 2006, 35, 256–257.
  • Galán, H.; Murillo, M. T.; Sedano, R.; Núñez, A.; de Mendoza, J.; González‐Espartero, A.; Prados, P. Hydrolysis and radiation stability of m‐Xylylene Bis‐diglycolamide: Synthesis and quantitative study of degradation products by HPLC–APCI+. Eur. J. Org. Chem. 2011, 2011, 3959–3969.
  • Galán, H.; Núñez, A.; Espartero, A. G.; Sedano, R.; Durana, A.; de Mendoza, J. Radiolytic stability of TODGA: Characterization of degraded samples under different experimental conditions. Procedia Chem. 2012, 7, 195–201.
  • Hérès, X.; Baron, P. Increase in the separation factor between americium and curium and/or between lanthanides in a liquid-liquid extraction process. WO2011012579, 2009.
  • Charbonnel, M.-C.; Berthon, C.; Berthon, L.; Boubals, N.; Burdet, F.; Duchesne, M.-T.; Guilbaud, P.; Mabille, N.; Petit, S.; Zorz, N. Complexation of Ln(III) and Am(III) with the hydrosoluble TEDGA: Speciation and Thermodynamics studies. Procedia Chem. 2012, 7, 20–26.
  • Pacary, V.; Burdet, F.; Duchesne, M.-T. Experimental and modeling of extraction of lanthanides in system HNO3-TEDGA-{DMDOHEMA-HDEHP}. Procedia Chem. 2012, 7, 328–333.
  • Sasaki, Y.; Sugo, Y.; Suzuki, S.; Tachimori, S. The novel extractants, diglycolamides, for the extraction of lanthanides and actinides in HNO3–n-dodecane system. Solvent Extr. Ion Exch. 2001, 19, 91–103.
  • Sasaki, Y.; Sugo, Y.; Kitatsuji, Y.; Kirishima, A.; Kimura, T.; Choppin, G. R. Complexation and back extraction of various metals by water-soluble diglycolamide. Anal. Sci. 2007, 23, 727–731.
  • Mowafy, E. A.; Aly, H. F. Synthesis of some N,N,N′,N′‐Tetraalkyl‐3‐Oxa‐Pentane‐1,5‐diamide and their applications in solvent extraction. Solvent Extr. Ion Exch. 2007, 25, 205–224.
  • Tian, G.; Zhang, P.; Wang, J.; Rao, L. Extraction of actinide(III, IV, V, VI) ions and TcO4 − by N,N,N′,N′‐tetraisobutyl‐3‐oxa‐glutaramide. Solvent Extr. Ion Exch. 2005, 23, 631–643.
  • Sasaki, Y.; Tachimori, S. Extraction of actinide(III), (IV), (V), (VI), and lanthanides(III) by structurally tailored diamides. Solvent Extr. Ion Exch. 2002, 20, 21–34.
  • Narita, H.; Yaita, T.; Tamura, K.; Tachimori, S. Study on the extraction of trivalent lanthanide ions with N,N′-dimethyl-N,N′-diphenyl-malonamide and diglycolamide. J. Radioanal. Nucl. Chem. 1999, 239, 381–384.
  • Zhu, Z.-X.; Sasaki, Y.; Suzuki, H.; Suzuki, S.; Kimura, T. Cumulative study on solvent extraction of elements by N,N,N′,N′-tetraoctyl-3-oxapentanediamide (TODGA) from nitric acid into n-dodecane. Anal. Chim. Acta 2004, 527, 163–168.
  • Ansari, S. A.; Pathak, P. N.; Manchanda, V. K.; Husain, M.; Prasad, A. K.; Parmar, V. S. N,N,N′,N′‐Tetraoctyl Diglycolamide (TODGA): A promising extractant for actinide‐partitioning from High‐Level Waste (HLW). Solvent Extr. Ion Exch. 2005, 23, 463–479.
  • Sasaki, Y.; Tsubata, Y.; Kitatsuji, Y.; Sugo, Y.; Shirasu, N.; Morita, Y.; Kimura, T. Extraction Behavior of metal ions by TODGA, DOODA, MIDOA, and NTAamide extractants from HNO3 to N-dodecane. Solvent Extr. Ion Exch. 2013, 31, 401–415.

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.