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Original Articles

The Orientational Order in So-Called de Vries Materials

, &
Pages 148/[1282]-157/[1291] | Published online: 05 Oct 2009

Keep up to date with the latest research on this topic with citation updates for this article.

Read on this site (7)

Ziauddin Ahmed, Carsten Müller, Jaya J. Johnston, Kevin Nguyen, Christopher P. J. Schubert, Karina Abitaev, Sebastian Marino, Frank Giesselmann & Robert P. Lemieux. (2019) Design of liquid crystals with ‘de Vries-like’ properties: the effect of an ethynyl spacer in the core structure. Liquid Crystals 46:6, pages 896-904.
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Mark T. Sims, Laurence C. Abbott, Robert M. Richardson, John W. Goodby & John N. Moore. (2019) Considerations in the determination of orientational order parameters from X-ray scattering experiments. Liquid Crystals 46:1, pages 11-24.
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Per Rudquist, Mikhail A. Osipov & Frank Giesselmann. (2018) On the orientational distribution functions in de Vries-type smectic liquid crystals. Liquid Crystals 45:13-15, pages 2097-2108.
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Deña M. Agra-Kooijman, Gautam Singh, Michael R. Fisch, M. R. Vengatesan, Jang-Kun Song & Satyendra Kumar. (2017) The oblique chiral nematic phase in calamitic bimesogens. Liquid Crystals 44:1, pages 191-203.
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O. E. Panarina, Yu. P. Panarin & J. K. Vij. (2015) Dielectric Study of Liquid Crystals with Large Electroclinic Effect. Molecular Crystals and Liquid Crystals 610:1, pages 193-200.
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Guan-Yeow Yeap, Tze-Nee Chan, Wan-Sinn Yam, Karolina Madrak, Damian Pociecha & Ewa Gorecka. (2012) Non-symmetric chiral isoflavone dimers: synthesis, characterisation and mesomorphic behaviour. Liquid Crystals 39:9, pages 1041-1047.
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SvenT. Lagerwall. (2011) Linear and Non-Linear Polar Effects in Liquid Crystals. Molecular Crystals and Liquid Crystals 543:1, pages 3/[769]-47/[813].
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Articles from other publishers (40)

Luana D. Lopes & Aloir A. Merlo. (2022) Born to be a Liquid Crystal: The role of fluorinated chain in the design and synthesis of new mesogens. Journal of Molecular Liquids 349, pages 118157.
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P. Subhasri, K. Rajakumar, S. Balamuralikrishnan & V.N. Vijayakumar. (2020) Detailed analysis of induced smectic phases and paramorphic effect of double hydrogen bonded ferroelectric liquid crystals. Journal of Molecular Liquids 318, pages 114076.
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Kristian Poll & Mark T. Sims. (2020) An insight into de Vries behaviour of smectic liquid crystals from atomistic molecular dynamics simulations. Journal of Materials Chemistry C 8:37, pages 13040-13052.
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Korinna Bader, Carsten Müller, Yann Molard, Angelika Baro, Philipp Ehni, Jakob Knelles & Sabine Laschat. (2020) Fluorenone imidazolium salts as novel de Vries materials. RSC Advances 10:40, pages 23999-24016.
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V. Swaminathan, V. P. Panov, A. Panov, D. Rodriguez-Lojo, P. J. Stevenson, E. Gorecka & Jagdish K. Vij. (2020) Design and electro-optic investigations of de Vries chiral smectic liquid crystals for exhibiting broad temperature ranges of SmA* and SmC* phases and fast electro-optic switching. Journal of Materials Chemistry C 8:14, pages 4859-4868.
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Anne Lehmann, Mohamed Alaasar, Marco Poppe, Silvio Poppe, Marko Prehm, Mamatha Nagaraj, Sithara P. Sreenilayam, Yuri P. Panarin, Jagdish K. Vij & Carsten Tschierske. (2020) Stereochemical Rules Govern the Soft Self‐Assembly of Achiral Compounds: Understanding the Heliconical Liquid‐Crystalline Phases of Bent‐Core Mesogens. Chemistry – A European Journal 26:21, pages 4714-4733.
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Marco Poppe, Mohamed Alaasar, Anne Lehmann, Silvio Poppe, Maria-Gabriela Tamba, Marharyta Kurachkina, Alexey Eremin, Mamatha Nagaraj, Jagdish K. Vij, Xiaoqian Cai, Feng Liu & Carsten Tschierske. (2020) Controlling the formation of heliconical smectic phases by molecular design of achiral bent-core molecules. Journal of Materials Chemistry C 8:10, pages 3316-3336.
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Neelam Yadav, V. Swaminathan, V. P. Panov, R. Dhar & J. K. Vij. (2019) Elucidation of the de Vries behavior in terms of the orientational order parameter, apparent tilt angle, and field-induced tilt angle for smectic liquid crystals by polarized infrared spectroscopy. Physical Review E 100:5.
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Mohamed Alaasar, Marko Prehm, Sebastian Belau, Nerea Sebastián, Marharyta Kurachkina, Alexey Eremin, Changlong Chen, Feng Liu & Carsten Tschierske. (2019) Polar Order, Mirror Symmetry Breaking, and Photoswitching of Chirality and Polarity in Functional Bent‐Core Mesogens. Chemistry – A European Journal 25:25, pages 6362-6377.
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V. Swaminathan, V. P. Panov, A. Kocot & J. K. Vij. (2019) Molecular orientational distribution function of a chiral de Vries smectic liquid crystal from birefringence measurements. The Journal of Chemical Physics 150:8.
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Carsten Müller, Christopher P. J. Schubert, Robert P. Lemieux & Frank Giesselmann. (2018) The Influence of Carbosilane Nanosegregation on the Dynamics in ‘de Vries-type’ Liquid Crystals. ChemPhysChem 19:20, pages 2703-2708.
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Nadia Kapernaum, Eugen Wuckert, Wolfgang Frey, Sebastian Marino, Manuel Wahl, Frank Giesselmann & Sabine Laschat. (2018) Hunting for smectic C in calamitic azobenzene ionic liquid crystals with different cationic head groups. Journal of Physical Organic Chemistry 31:3, pages e3779.
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S. P. Sreenilayam, D. Rodriguez-Lojo, D. M. Agra-Kooijman, J. K. Vij, V. P. Panov, A. Panov, M. R. Fisch, Satyendra Kumar & P. J. Stevenson. (2018) de Vries liquid crystals based on a chiral 5-phenylpyrimidine benzoate core with a tri- and tetra-carbosilane backbone. Physical Review Materials 2:2.
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S. P. Sreenilayam, D. Rodriguez-Lojo, V. P. Panov, V. Swaminathan, J. K. Vij, Yu. P. Panarin, E. Gorecka, A. Panov & P. J. Stevenson. (2017) Design and investigation of de Vries liquid crystals based on 5-phenyl-pyrimidine and ( R,R )-2,3-epoxyhexoxy backbone . Physical Review E 96:4.
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Mohamed Alaasar, Marko Prehm, Silvio Poppe & Carsten Tschierske. (2017) Development of Polar Order by Liquid‐Crystal Self‐Assembly of Weakly Bent Molecules. Chemistry – A European Journal 23:23, pages 5541-5556.
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Christopher P. J. Schubert, Carsten Müller, Andreas Bogner, Frank Giesselmann & Robert P. Lemieux. (2017) Design of liquid crystals with ‘de Vries-like’ properties: structural variants of carbosilane-terminated 5-phenylpyrimidine mesogens. Soft Matter 13:18, pages 3307-3313.
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Z. Zhang, S. Kaur, B. Kundu, B. K. Sadashiva & H. F. Gleeson. (2017) Observing the emergence of phase biaxiality in a polar smectic A system via polarised Raman spectroscopy. Journal of Materials Chemistry C 5:5, pages 1195-1205.
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Nadia Kapernaum, Carsten Müller, Svenja Moors, M. Christian Schlick, Eugen Wuckert, Sabine Laschat & Frank Giesselmann. (2016) First Examples of de Vries-like Smectic A to Smectic C Phase Transitions in Ionic Liquid Crystals. ChemPhysChem 17:24, pages 4116-4123.
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Gautam Singh, Jinxin Fu, Dena M. Agra-Kooijman, Jang-Kun Song, M. R. Vengatesan, Mohan Srinivasarao, Michael R. Fisch & Satyendra Kumar. (2016) X-ray and Raman scattering study of orientational order in nematic and heliconical nematic liquid crystals. Physical Review E 94:6.
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Frank Jenz, Mikhail A. Osipov, Stefan Jagiella & Frank Giesselmann. (2016) Orientational distribution functions and order parameters in “de Vries”-type smectics: A simulation study. The Journal of Chemical Physics 145:13.
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Eduard Westphal, Hugo Gallardo, Giovanni Finoto Caramori, Nerea Sebastián, Maria-Gabriela Tamba, Alexey Eremin, Susumu Kawauchi, Marko Prehm & Carsten Tschierske. (2016) Polar Order and Symmetry Breaking at the Boundary between Bent-Core and Rodlike Molecular Forms: When 4-Cyanoresorcinol Meets the Carbosilane End Group. Chemistry - A European Journal 22:24, pages 8181-8197.
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Christopher P. J. Schubert, Carsten Müller, Frank Giesselmann & Robert P. Lemieux. (2016) Chiral 5-phenylpyrimidine liquid crystals with ‘de Vries-like’ properties: dependence of electroclinic effect and ferroelectric properties on carbosilane nanosegregation. Journal of Materials Chemistry C 4:36, pages 8483-8489.
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Hale Ocak, Marco Poppe, Belkız Bilgin-Eran, Gürkan Karanlık, Marko Prehm & Carsten Tschierske. (2016) Effects of molecular chirality on self-assembly and switching in liquid crystals at the cross-over between rod-like and bent shapes. Soft Matter 12:35, pages 7405-7422.
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Mohamed Alaasar, Marko Prehm, Maria‐Gabriela Tamba, Nerea Sebastián, Alexey Eremin & Carsten Tschierske. (2015) Development of Polar Order in the Liquid Crystal Phases of a 4‐Cyanoresorcinol‐Based Bent‐Core Mesogen with Fluorinated Azobenzene Wings. ChemPhysChem 17:2, pages 278-287.
Crossref
Dilek Güzeller, Hale Ocak, Belkız Bilgin-Eran, Marko Prehm & Carsten Tschierske. (2015) Development of tilt, biaxiality and polar order in bent-core liquid crystals derived from 4′-hydroxybiphenyl-3-carboxylic acid. Journal of Materials Chemistry C 3:17, pages 4269-4282.
Crossref
Christopher P. J. Schubert, Carsten Müller, Michael D. Wand, Frank Giesselmann & Robert P. Lemieux. (2015) Electroclinic effect in a chiral carbosilane-terminated 5-phenylpyrimidine liquid crystal with ‘de Vries-like’ properties. Chemical Communications 51:63, pages 12601-12604.
Crossref
Eugen Wuckert, Marc D. Harjung, Nadia Kapernaum, Carsten Mueller, Wolfgang Frey, Angelika Baro, Frank Giesselmann & Sabine Laschat. (2015) Photoresponsive ionic liquid crystals based on azobenzene guanidinium salts. Physical Chemistry Chemical Physics 17:13, pages 8382-8392.
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Dena M. Agra-Kooijman, HyungGuen Yoon, Sonal Dey & Satyendra Kumar. (2014) Origin of weak layer contraction in de Vries smectic liquid crystals. Physical Review E 89:3.
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Carsten Tschierske. 2014. Handbook of Liquid Crystals. Handbook of Liquid Crystals 1 44 .
Kirk M. Mulligan, Andreas Bogner, Qingxiang Song, Christopher P. J. Schubert, Frank Giesselmann & Robert P. Lemieux. (2014) Design of liquid crystals with ‘de Vries-like’ properties: the effect of carbosilane nanosegregation in 5-phenyl-1,3,4-thiadiazole mesogens. J. Mater. Chem. C 2:39, pages 8270-8276.
Crossref
Christopher P. J. Schubert, Andreas Bogner, Jan H. Porada, Khurshid Ayub, Tamer Andrea, Frank Giesselmann & Robert P. Lemieux. (2014) Design of liquid crystals with ‘de Vries-like’ properties: carbosilane-terminated 5-phenylpyrimidine mesogens suitable for chevron-free FLC formulations. J. Mater. Chem. C 2:23, pages 4581-4589.
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Dorothee Nonnenmacher, Stefan Jagiella, Qingxiang Song, Robert P. Lemieux & Frank Giesselmann. (2013) Orientational Fluctuations Near the Smectic A to Smectic C Phase Transition in Two “de Vries”-Type Liquid Crystals. ChemPhysChem 14:13, pages 2990-2995.
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Zachary V. Kost-Smith, Paul D. Beale, Noel A. Clark & Matthew A. Glaser. (2013) Microscopic origins of first-order Sm- –Sm- phase behavior in de Vries smectic liquid crystals . Physical Review E 87:5.
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Qingxiang Song, Dorothee Nonnenmacher, Frank Giesselmann & Robert P. Lemieux. (2013) Tuning ‘de Vries-like’ properties in siloxane- and carbosilane-terminated smectic liquid crystals. J. Mater. Chem. C 1:2, pages 343-350.
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Tonatiuh García, Leticia Larios‐López, Rosa Julia Rodríguez‐González, José Román Torres‐Lubián & Dámaso Navarro‐Rodríguez. (2012) Azo Monomers Exhibiting Low Layer Shrinkage at the SmA–SmC Transition and trans – cis Light‐Induced Isomerization . ChemPhysChem 13:17, pages 3937-3944.
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Kacper Drużbicki, Antoni Kocot, Edward Mikuli, Mirosława Danuta Ossowska-Chruściel & Janusz Chruściel. (2012) Temperature-Dependent Infrared Spectroscopy Studies of a Novel Antiferroelectric Liquid-Crystalline Thiobenzoate. The Journal of Physical Chemistry B 116:36, pages 11332-11343.
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A. Sanchez-Castillo, M. A. Osipov, S. Jagiella, Z. H. Nguyen, M. Kašpar, V. Hamplovă, J. Maclennan & F. Giesselmann. (2012) Orientational order parameters of a de Vries–type ferroelectric liquid crystal obtained by polarized Raman spectroscopy and x-ray diffraction. Physical Review E 85:6.
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Rafał Korlacki, Vitaly P. Panov, Atsuo Fukuda, Jagdish K. Vij, Christopher M. Spillmann & Jawad Naciri. (2010) Orientational order of a ferroelectric liquid crystal with small layer contraction. Physical Review E 82:3.
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Werner Kaminsky, Steven Steininger, Javier Herreros-Cedres & Anthony Michael Glazer. (2010) Evidence of a circularly polarized light mode along the optic axis in c -cut NH 4 H 2 PO 4 , induced by circular differential reflection and anomalous birefringence . Journal of Physics: Condensed Matter 22:9, pages 095902.
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Ramaiahgari Amaranatha Reddy, Ute Baumeister, Jessie Lorenzo Chao, Horst Kresse & Carsten Tschierske. (2010) Silylated bent-core molecules: the influence of the direction of the carboxyl connecting groups on the mesophase behaviour. Soft Matter 6:16, pages 3883.
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