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Designed Monomers and Polymers Volume 18, 2015 - Issue 7
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Articles

Highly efficient FeCl3 doped Mg(OEt)2/TiCl4-based Ziegler–Natta catalysts for ethylene polymerization

Reza BazvandPolymerization Engineering Department, Iran Polymer and Petrochemical Institute (IPPI), P.O. Box 14965/115, Tehran, IranView further author information
,
Naeimeh Bahri-LalehPolymerization Engineering Department, Iran Polymer and Petrochemical Institute (IPPI), P.O. Box 14965/115, Tehran, IranCorrespondence[email protected]
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,
Mehdi NekoomaneshPolymerization Engineering Department, Iran Polymer and Petrochemical Institute (IPPI), P.O. Box 14965/115, Tehran, IranCorrespondence[email protected]
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&
Hossein AbediniProcess, Modeling and Control Department, Iran Polymer & Petrochemical Institute, P.O. Box 14965/115, Tehran, IranView further author information
Pages 599-610 | Received 31 Jan 2015, Accepted 12 Apr 2015, Published online: 11 Jun 2015

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Seyed Amin Mirmohammadi, Amin Hedayati Moghaddam & Naeimeh Bahri-Laleh. (2023) Simulation and optimization of supported Ziegler–Natta catalyst preparation based on AI approach coupled with genetic algorithm. International Journal of Polymer Analysis and Characterization 28:3, pages 269-278.
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Mohammad Hossein Jandaghian, Yasaman Maddah, Ehsan Nikzinat, Maryam Masoori, Abdolhannan Sepahi & Reza Rashedi. (2021) Investigation of the effects of heat treatment parameters during synthesis of titanium-magnesium-based Ziegler-Natta catalysts. Journal of Macromolecular Science, Part A 58:5, pages 287-297.
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Farshid Nouri-Ahangarani, Naeimeh Bahri-Laleh, Mehdi Nekoomanesh-Haghighi & Milad Karbalaie. (2016) Synthesis of highly isotactic poly 1-hexene using Fe-doped Mg(OEt)2/TiCl4/ED Ziegler–Natta catalytic system. Designed Monomers and Polymers 19:5, pages 394-405.
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Articles from other publishers (30)

Mohammad Hossein Jandaghian, Abdolhannan Sepahi, Shahin Hosseini, Ali Salimzadeh, Reza Zaeri & Ehsan Nikzinat. (2022) Clarifying the effects of comonomer distribution between short and long chains on physical and mechanical properties of ethylenic copolymers. Polymer Engineering & Science 63:2, pages 646-659.
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Arash Shams, Mohammadreza Mehdizadeh, HamidReza Teimoury, Mehrsa Emami, Seyed Amin Mirmohammadi, Samahe Sadjadi, Eduard Bardají, Albert Poater & Naeimeh Bahri-Laleh. (2022) Effect of the pore architecture of Ziegler-Natta catalyst on its behavior in propylene/1-hexene copolymerization. Journal of Industrial and Engineering Chemistry 116, pages 359-370.
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Mohammad Hossein Jandaghian, Yasaman Maddah, Shahin Hosseini, Fahimeh Eshaghzadeh, Abdolhannan Sepahi, Ehsan Nikzinat, Maryam Masoori, Hossein Bazgir & Reza Rashedi. (2022) Demystifying the two-sided role of inorganic halides in the structure and performance of Ziegler–Natta catalysts. Molecular Systems Design & Engineering 7:12, pages 1722-1735.
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Morteza Abazari, Roghayeh Jamjah, Naeimeh Bahri-Laleh & Ahad Hanifpour. (2021) Synthesis and evaluation of a new three-metallic high-performance Ziegler–Natta catalyst for ethylene polymerization: experimental and computational studies. Polymer Bulletin 79:9, pages 7265-7280.
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Mohammad Hossein Jandaghian, Yasaman Maddah, Abdolhannan Sepahi, Shahin Hosseini, Ehsan Nikzinat, Maryam Masoori, Kamal Afzali, Reza Rashedi & Saeed Houshmandmoayed. (2022) Chlorination of Mg(OEt) 2 with Halocarbons: A Promising Approach for Eliminating Chlorine-Containing Activators from Ziegler–Nattas’ Recipes . Industrial & Engineering Chemistry Research 61:32, pages 11708-11717.
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Maryam Masoori, Mehdi Nekoomanesh, Sergio Posada-Pérez, Reza Rashedi & Naeimeh Bahri-Laleh. (2022) Exploring cocatalyst type effect on the Ziegler–Natta catalyzed ethylene polymerizations: experimental and DFT studies. Journal of Polymer Research 29:5.
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Farideh Paymozd, Ali Reza Modarresi-Alam & Hamideh Saravani. (2022) Synthesis and characterization of chiral nano-poly [(±)-2-sec-butyl aniline] and its application in the first chiral polymer solar cell. Optical Materials 125, pages 112098.
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Sanjay Chauhan, Sanket Shah, Harshad R. Patil & Virendrakumar Gupta. (2021) Investigating effect of mixed alcohols and in-situ initiator on magnesium alkoxide for Ziegler–Natta catalyst and polypropylene improvement. Journal of Polymer Research 28:7.
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Sahar Karimi, Naeimeh Bahri-Laleh, Gerard Pareras, Samahe Sadjadi, Mehdi Nekoomanesh-Haghighi & Albert Poater. (2021) Pd on nitrogen rich polymer–halloysite nanocomposite as an environmentally benign and sustainable catalyst for hydrogenation of polyalfaolefin based lubricants. Journal of Industrial and Engineering Chemistry 97, pages 441-451.
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Mahtab Tabrizi, Samahe Sadjadi, Gerard Pareras, Mehdi Nekoomanesh-Haghighi, Naeimeh Bahri-Laleh & Albert Poater. (2021) Efficient hydro-finishing of polyalfaolefin based lubricants under mild reaction condition using Pd on ligands decorated halloysite. Journal of Colloid and Interface Science 581, pages 939-953.
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Samahe Sadjadi, Fatemeh Koohestani & Naeimeh Bahri-Laleh. (2020) Pd immobilization on the multi-amine functionalized halloysite as an efficient catalyst for hydrogenation reaction: An experimental and computational study. Applied Clay Science 192, pages 105645.
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Aazam Jalali, Mehdi Nekoomanehs‐Haghighi, Sevda Dehghani & Naeimeh Bahri‐Laleh. (2019) Effect of metal type on the metallocene‐catalyzed oligomerization of 1‐hexene and 1‐octene to produce polyα‐olefin‐based synthetic lubricants. Applied Organometallic Chemistry 34:2.
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Mehrdad Fallah, Naeimeh Bahri‐Laleh, Khadijeh Didehban & Albert Poater. (2019) Interaction of common cocatalysts in Ziegler–Natta‐catalyzed olefin polymerization. Applied Organometallic Chemistry 34:2.
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Ahad Hanifpour & Naeimeh Bahri-Laleh. (2019) Effects of the molecular weight and CC functionality of poly 1-hexene on the properties of poly 1-hexene-based high impact polystyrene. Journal of Applied Polymer Science 136:10, pages 47169.
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Ahad Hanifpour, Naeimeh Bahri-Laleh & Seyed Amin Mirmohammadi. (2019) Silica-grafted poly1-hexene: A new approach to prepare polyethylene/silica nanocomposites. Polymer Composites 40:3, pages 1053-1060.
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Sanaz Rahmatiyan, Naeimeh Bahri-Laleh, Ahad Hanifpour & Mehdi Nekoomanesh-Haghighi. (2019) Different behaviors of metallocene and Ziegler-Natta catalysts in ethylene/1,5-hexadiene copolymerization. Polymer International 68:1, pages 94-101.
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Naeimeh Bahri-Laleh, Samaheh Sadjadi & Albert Poater. (2018) Pd immobilized on dendrimer decorated halloysite clay: Computational and experimental study on the effect of dendrimer generation, Pd valance and incorporation of terminal functionality on the catalytic activity. Journal of Colloid and Interface Science 531, pages 421-432.
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Sedigheh Shirbakht, Seyed Amin Mirmohammadi, Khadijeh Didehban, Samaheh Sadjadi & Naeimeh Bahri-Laleh. (2018) Effects of monomer length on α-olefins polymerization using a conventional Ziegler-Natta catalyst. Advances in Polymer Technology 37:7, pages 2588-2596.
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Naeimeh Bahri-Laleh & Samahe Sadjadi. (2018) CuI@Sulfur-functionalized halloysite nanoclay: a novel recyclable catalyst for the ultrasonic-assisted synthesis of propargylamines: a combination of experimental and DFT simulation. Research on Chemical Intermediates 44:10, pages 6351-6368.
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Naeimeh Bahri-Laleh, Ahad Hanifpour, Seyed Amin Mirmohammadi, Albert Poater, Mehdi Nekoomanesh-Haghighi, Giovanni Talarico & Luigi Cavallo. (2018) Computational modeling of heterogeneous Ziegler-Natta catalysts for olefins polymerization. Progress in Polymer Science 84, pages 89-114.
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Naeimeh Bahri-Laleh, Majid Karimi, Zahra Kalantari, Mehrdad Fallah, Ahad Hanifpour & Mehdi Nekoomanesh-Haghighi. (2017) H2 effect in Chevron–Phillips ethylene trimerization catalytic system: an experimental and theoretical investigation. Polymer Bulletin 75:8, pages 3555-3565.
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Samaheh Sadjadi & Naeimeh Bahri-Laleh. (2017) CuI@amine-functionalized halloysite as an efficient heterogeneous catalyst for promoting A3 coupling reaction under ultrasonic irradiation: a combination of experimental and DFT simulation. Journal of Porous Materials 25:3, pages 821-833.
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Davood Nazari, Naeimeh Bahri‐Laleh, Mehdi Nekoomanesh‐Haghighi, Seyed Mehrdad Jalilian, Razieh Rezaie & Seyed Amin Mirmohammadi. (2018) New high impact polystyrene: Use of poly(1‐hexene) and poly(1‐hexene‐co‐hexadiene) as impact modifiers. Polymers for Advanced Technologies 29:6, pages 1603-1612.
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Naeimeh Bahri‐Laleh, Samaheh Sadjadi, Majid M. Heravi & Masoumeh Malmir. (2018) CuI‐functionalized halloysite nanoclay as an efficient heterogeneous catalyst for promoting click reactions: Combination of experimental and computational chemistry. Applied Organometallic Chemistry 32:6.
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Ebtehal Naji-Rad, Martí Gimferrer, Naeimeh Bahri-Laleh, Mehdi Nekoomanesh-Haghighi, Roghieh Jamjah & Albert Poater. (2018) Exploring Basic Components Effect on the Catalytic Efficiency of Chevron-Phillips Catalyst in Ethylene Trimerization. Catalysts 8:6, pages 224.
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Ahad Hanifpour, Naeimeh Bahri-Laleh, Mehdi Nekoomanesh-Haghighi & Majid Karimi. (2017) Synthesis and characterization of poly1-hexene/silica nanocomposites. Polymer Testing 61, pages 27-34.
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Ting Fu, Rui-hua Cheng, Xue-lian He, Zhen Liu, Zhou Tian & Bo-ping Liu. (2017) Modification of the (SiO2/MgO/MgCl2)·TiCl x Ziegler-Natta polyethylene catalysts using the third metal elements. Chinese Journal of Polymer Science 35:6, pages 739-751.
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Ahad Hanifpour, Naeimeh Bahri-Laleh, Mehdi Nekoomanesh-Haghighi & Seyed Amin Mirmohammadi. (2016) Poly1-hexene: New impact modifier in HIPS technology. Journal of Applied Polymer Science 133:35.
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Ahad Hanifpour, Naeimeh Bahri-Laleh, Mehdi Nekoomanesh-Haghighi & Majid Karimi. (2016) Study on unsaturated structure and tacticity of poly1-hexene and new copolymer of 1-hexene/5-hexene-1-ol prepared by metallocene catalyst. Journal of Organometallic Chemistry 819, pages 103-108.
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Naeimeh Bahri-Laleh. (2016) Interaction of different poisons with MgCl2/TiCl4 based Ziegler-Natta catalysts. Applied Surface Science 379, pages 395-401.
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