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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 33, 2003 - Issue 17
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Original Articles

An Easy Method for the Generation of Amides from Ketones by a Beckmann Type Rearrangement Mediated by Microwave

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Pages 2971-2978 | Received 22 Jul 2002, Published online: 21 Aug 2006

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Read on this site (6)

Atefeh Ghasemi, Abolghasem Davoodnia, Mehdi Pordel & Niloofar Tavakoli-Hoseini. (2017) P2O5 supported on SiO2 as an efficient and reusable catalyst for rapid one-pot synthesis of carbamatoalkyl naphthols under solvent-free conditions. Cogent Chemistry 3:1.
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Mohammad Navid Soltani Rad, Ali Khalafi-Nezhad, Somayeh Behrouz, Zohreh Amini & Marzieh Behrouz. (2010) A Simple and Highly Efficient One-Pot Procedure for the Synthesis of Amides via Beckmann Rearrangements Using 1-Tosylimidazole (TsIm). Phosphorus, Sulfur, and Silicon and the Related Elements 185:8, pages 1658-1671.
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Hossein Eshghi & Asadollah Hassankhani. (2006) P2O5/SiO2‐Catalyzed One‐Pot Synthesis of Amides from Ketones via Schmidt Reaction under Microwave Irradiation in Dry Media. Synthetic Communications 36:15, pages 2211-2216.
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Michael P. Curtis, William H. Bunnelle, Thomas G. Pagano, Murali Gopalakrishnan & Ramin Faghih. (2006) Microwave‐Assisted Beckmann Rearrangement: Convenient Synthesis of 1,3‐Diaza‐bicyclo[3.2.2]nonane. Synthetic Communications 36:3, pages 321-326.
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Hossein Eshghi & Zinat Gordi. (2005) P2O5/SiO2 as an Efficient Reagent for the Preparation of -Aldoximes Under Solvent-Free Conditions. Phosphorus, Sulfur, and Silicon and the Related Elements 180:7, pages 1553-1557.
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Hossein Eshghi & Zinat Gordi. (2005) Microwave-Assisted Efficient One-Pot Synthesis of Nitriles From Aldehydes in the Presence of P2O5/SiO2 in Solvent-Free Media. Phosphorus, Sulfur, and Silicon and the Related Elements 180:2, pages 619-623.
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Articles from other publishers (33)

Xinyun Zhao, Tsunghsueh Wu, Xi Chen, Lamei Wu & Zhongqiang Zhou. (2023) A Comprehensive Inquiry-Based Comparative Experiment for an Undergraduate Organic Chemistry Laboratory Course: Elucidating the Formation Process of N -Phenylbenzamide . Journal of Chemical Education.
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Athmanand Anchi, Rajesh G. Kalkhambkar, Suraj M. Sutar, Ravi S. Naik, Moamen S. Refat, Abdel Majid A. Adam & Amnah Mohammed Alsuhaibani. (2023) Tropylium‐BF 4 as Organocatalyst for Microwave‐assisted Beckmann rearrangement in [TMG][BF 4 ]: One‐pot conversion of Ketones to Amides . ChemistrySelect 8:23.
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H. Keith Chenault. 2021. Handbook of Pyrrolidone and Caprolactam Based Materials. Handbook of Pyrrolidone and Caprolactam Based Materials 191 238 .
Kamalpreet Kaur & Suman Srivastava. (2020) Beckmann rearrangement catalysis: a review of recent advances. New Journal of Chemistry 44:43, pages 18530-18572.
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Li Yu, Liping Guo, Wanlu Hu, Zulei Zhang, Yuqing Bai, Jiani Ye, Hailong Wang & Lei Li. (2019) One-pot conversion of ketones to amides via Beckmann rearrangement catalyzed by metal chloride-ionic liquids under solvent-free condition. Catalysis Communications 123, pages 119-123.
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Kengo Hyodo, Genna Hasegawa, Naoki Oishi, Kazuma Kuroda & Kingo Uchida. (2018) Direct and Catalytic Amide Synthesis from Ketones via Transoximation and Beckmann Rearrangement under Mild Conditions. The Journal of Organic Chemistry 83:21, pages 13080-13087.
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Chander Singh Digwal, Upasana Yadav, P. V. Sri Ramya, Baijayantimala Swain & Ahmed Kamal. (2018) Vanadium‐Catalyzed N‐Benzoylation of 2‐Aminopyridines via Oxidative C(CO)−C(CO) Bond Cleavage of 1,2‐Diketones, N→N′ Aroyl Migration and Hydrolysis of 2‐(Diaroylamino)pyridines. Asian Journal of Organic Chemistry 7:5, pages 865-869.
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Richard C. LarockRichard C. Larock & Roman Rozhkov. 2018. Comprehensive Organic Transformations. Comprehensive Organic Transformations 1 28 .
Prateek U. Jain & Shriniwas D. Samant. (2018) A Facile One‐Pot Transformation of Aromatic Aldehydes/Ketones to Amides: Fe 2 O 3 @SiO 2 as an Environmentally Benign Core‐Shell Catalyst . ChemistrySelect 3:7, pages 1967-1975.
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Sheena Mahajan, Bhavana Sharma & Kamal K. Kapoor. (2015) A solvent-free one step conversion of ketones to amides via Beckmann rearrangement catalysed by FeCl3·6H2O in presence of hydroxylamine hydrochloride. Tetrahedron Letters 56:14, pages 1915-1918.
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S. Chandrasekhar. 2014. Comprehensive Organic Synthesis II. Comprehensive Organic Synthesis II 770 800 .
Uroš Grošelj, Alen Sevšek, Sebastijan Ričko, Amalija Golobič, Jurij Svete & Branko Stanovnik. (2012) Synthesis and Structural Characterization of Novel Camphor-derived Amines. Chirality 24:10, pages 778-788.
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Hossein Eshghi & Asadollah Hassankhani. (2012) Phosphorus pentoxide supported on silica gel and alumina (P2O5/SiO2, P2O5/Al2O3) as useful catalysts in organic synthesis. Journal of the Iranian Chemical Society 9:4, pages 467-482.
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María Guadalupe Hernández-Linares, Jesús Sandoval-Ramírez, Socorro Meza-Reyes, Sara Montiel-Smith & Gabriel Guerrero-Luna. (2011) Stereospecific synthesis of new steroidal isoxazoles in dry media. Steroids 76:14, pages 1521-1526.
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Girijesh K. Verma, Keshav Raghuvanshi, Rajiv K. Verma, Pratibha Dwivedi & M.S. Singh. (2011) An efficient one-pot solvent-free synthesis and photophysical properties of 9-aryl/alkyl-octahydroxanthene-1,8-diones. Tetrahedron 67:20, pages 3698-3704.
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Ram Kumar, Keshav Raghuvanshi, Rajiv K. Verma & Maya S. Singh. (2010) Application of cyclic-1,3-diketones in domino and multicomponent reactions: facile route to highly functionalized chromeno[2,3-d]pyrimidinones and diazabenzo[b]fluorenones under solvent-free conditions. Tetrahedron Letters 51:45, pages 5933-5936.
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Haibo Zhao, Hua Fu & Renzhong Qiao. (2010) Copper-Catalyzed Direct Amination of Ortho-Functionalized Haloarenes with Sodium Azide as the Amino Source. The Journal of Organic Chemistry 75:10, pages 3311-3316.
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M. Manuela A. Pereira & Pedro Paulo Santos. 2009. PATAI'S Chemistry of Functional Groups. PATAI'S Chemistry of Functional Groups.
Hossein Eshghi, Mohammad Rahimizadeh & Sattar Saberi. (2008) Selective monotetrahydropyranylation of symmetrical diols using P2O5/SiO2 under solvent-free conditions and their depyranylation. Chinese Chemical Letters 19:9, pages 1063-1067.
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. (2008) Silica Supported Sulphamic Acid as Mild Catalyst for Synthesis of Anilides (Beckmann Rearrangement), Using Microwave Irradiation. Journal of the Korean Chemical Society 52:4, pages 454-456.
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J.S. Yadav, B.V. Subba Reddy, U.V. Subba Reddy & K. Praneeth. (2008) Azido-Schmidt reaction for the formation of amides, imides and lactams from ketones in the presence of FeCl3. Tetrahedron Letters 49:32, pages 4742-4745.
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Abdul RAUF, Saloni GANGAL & Shweta SHARMA. (2008) Silica‐gel‐supported Phosphorus Pentoxide:a Simple and Efficient Solid‐supported Reagent for Esterification of Long‐ Chain Carboxylic Acids and Their Antimicrobial Screening. Chinese Journal of Chemistry 26:4, pages 699-708.
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. (2008) Regioselective Synthesis of Z-Aldoximes Catalyzed By H 3 PMo 12 O 40 under Solvent-Free Conditions . Journal of the Korean Chemical Society 52:1, pages 52-56.
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Matthew D. BowmanJennifer L. HolcombChad M. KormosNicholas E. LeadbeaterVictoria A. Williams. (2007) Approaches for Scale-Up of Microwave-Promoted Reactions. Organic Process Research & Development 12:1, pages 41-57.
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. (2007) One-Pot Efficient Beckmann Rearrangement of Ketones Catalyzed by Silica Sulfuric Acid. Journal of the Korean Chemical Society 51:4, pages 361-364.
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Fatemeh Tamaddon, Mehdi Khoobi & Elham Keshavarz. (2007) (P2O5/SiO2): a useful heterogeneous alternative for the Ritter reaction. Tetrahedron Letters 48:21, pages 3643-3646.
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Michael A. Walters, Andrew B. Hoem, Masakatsu Shibasaki & Noriyuki Yamagiwa. 2001. Encyclopedia of Reagents for Organic Synthesis. Encyclopedia of Reagents for Organic Synthesis.
Hossein Eshghi. (2006) Ferric Hydrogensulfate Catalysed Schmidt Reaction of Ketones to Amides under Solvent-Free Conditions. Journal of the Chinese Chemical Society 53:4, pages 987-990.
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Zhen-Shui Cui, Zhan-Hui Zhang & Shu-Fen Liu. (2019) An efficient conversion of β-diketones into β-keto enol ethers with P 2 O 5 /SiO 2 under solvent-free conditions . Journal of Chemical Research 2006:6, pages 390-392.
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Hossein Eshghi, Asadollah Hassankhani & Elaheh Mosaddegh. (2019) Silica Sulfuric Acid as a Reusable Catalyst for the Conversion of Ketones into Amides by a Schmidt Reaction under Solvent-Free Conditions. Journal of Chemical Research 2006:4, pages 218-219.
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Hossein Eshghi & Parvaneh Shafieyoon. (2005) P 2 O 5 /SiO 2 as an Efficient Reagent for Selective Deprotection of 1,1-Diacetates under Solvent-Free Conditions . Journal of the Chinese Chemical Society 52:1, pages 155-157.
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Hossein Eshghi & Parvaneh Shafieyoon. (2019) P 2 O 5 / SiO 2 as a mild and efficient reagent for acylation of alcohols, phenols and amines under solvent-free conditions . Journal of Chemical Research 2004:12, pages 802-805.
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Hossein Eshghi & Zinat Gordi. (2003) An Easy Method for the Generation of Amides from Ketones by a Beckmann Type Rearrangement Mediated by Microwave.. ChemInform 34:52.
Crossref

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