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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 34, 2004 - Issue 9
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Original Articles

CAN Catalyzed One‐Pot Synthesis of α‐Amino Phosphonates from Carbonyl Compounds

K. Ravinder Natural Products Laboratory, Organic Chemistry Division‐I, Indian Institute of Chemical Technology, Hyderabad, 500 007, India
,
A. Vijender Reddy Natural Products Laboratory, Organic Chemistry Division‐I, Indian Institute of Chemical Technology, Hyderabad, 500 007, India
,
P. Krishnaiah Natural Products Laboratory, Organic Chemistry Division‐I, Indian Institute of Chemical Technology, Hyderabad, 500 007, India
,
G. Venkataramana Natural Products Laboratory, Organic Chemistry Division‐I, Indian Institute of Chemical Technology, Hyderabad, 500 007, India
,
V. L. Niranjan Reddy Natural Products Laboratory, Organic Chemistry Division‐I, Indian Institute of Chemical Technology, Hyderabad, 500 007, India
&
Y. Venkateswarlu Natural Products Laboratory, Organic Chemistry Division‐I, Indian Institute of Chemical Technology, Hyderabad, 500 007, IndiaCorrespondence[email protected]
Pages 1677-1683 | Received 27 Nov 2003, Published online: 16 Aug 2006

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Ge Gao, Meng-Nan Chen, Li-Ping Mo & Zhan-Hui Zhang. (2019) Catalyst free one-pot synthesis of α-aminophosphonates in aqueous ethyl lactate. Phosphorus, Sulfur, and Silicon and the Related Elements 194:4-6, pages 528-532.
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Neelam P. Prajapati, Rajesh H. Vekariya & Hitesh D. Patel. (2015) Ceric Ammonium Nitrate (CAN)–Catalyzed Multicomponent Reactions: An Efficient Catalyst for Green Organic Synthesis. Synthetic Communications 45:21, pages 2399-2425.
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Ch. Syama Sundar, N. Bakthavatchala Reddy, S. Siva Prasad, K. Uma Maheswara Rao, S.H. Jaya Prakash & C. Suresh Reddy. (2014) The Synthesis and Bioactivity of Dimethyl (2,3- Dihydrobenzo[b][1,4]Dioxin-6-Yl)(Aryl Amino)Methylphosphonates. Phosphorus, Sulfur, and Silicon and the Related Elements 189:4, pages 551-557.
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S. Santhi Sudha, Ch. Syama Sundar, N. Bakthavatchala Reddy, K. Uma Maheswara Rao, S.H. Jaya Prakash & C. Suresh Reddy. (2013) Synthesis and Bioassay of Ethyl-2- (2-((Diethoxyphosphoryl) (Aryl) Methylamino)Thiazol-4-Yl)-2-(Methoxyimino)Acetates. Phosphorus, Sulfur, and Silicon and the Related Elements 188:10, pages 1402-1411.
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Ch. Syama Sundar, D. Srinivasulu, S.K. Nayak & C. Suresh Reddy. (2012) Tween-20: An Efficient Catalyst for One-Pot Synthesis of α-Aminophosphonates in Aqueous Media. Phosphorus, Sulfur, and Silicon and the Related Elements 187:4, pages 523-534.
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Xiao‐yong Lv, Jian‐min Zhang, Chun‐hui Xing, Wei‐qiong Du & Shi‐zheng Zhu. (2007) One‐Pot Preparation of Fluorinated α‐Aminoalkyl Phosphonates under Microwave Irradiation and Solvent‐Free Conditions. Synthetic Communications 37:5, pages 743-757.
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Articles from other publishers (19)

Kumaresh Datta, Bijeta Mitra & Pranab Ghosh. (2023) Humic Acid: A Green‐Catalyst‐Mediated Solvent‐Free Synthesis of Functionalized Diethyl(Phenyl(phenylamino)methyl)phosphonate. ChemistrySelect 8:29.
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Vipin K. Pandey, Chandra Shekhar Tiwari & Arnab Rit. (2022) Silver‐Catalyzed One‐Pot Three‐Component Synthesis of α‐Aminonitriles and Biologically Relevant α‐Amino‐phosphonates. Chemistry – An Asian Journal 17:20.
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Kamalakar K. Wavhal & Deepak M Nagrik. (2022) Synthesis of α-Aminophosphonates Derivatives by Using Novel Nano-Catalyst through Kabachnik-Fields Reaction. International Journal of Advanced Research in Science, Communication and Technology, pages 63-72.
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Haniyeh Zandieh, Javad Mokhtari & Kambiz Larijani. (2022) Synthesis of α-amino phosphonates catalyzed by copper-based metal organic frameworks. Journal of Organometallic Chemistry 957, pages 122156.
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Suman Das, Parveen Rawal, Jayeeta Bhattacharjee, Ajitrao Devadkar, Kuntal Pal, Puneet Gupta & Tarun K. Panda. (2021) Indium promoted C(sp 3 )–P bond formation by the Domino A 3 -coupling method – a combined experimental and computational study . Inorganic Chemistry Frontiers 8:5, pages 1142-1153.
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György Keglevich. (2021) Microwaves as “Co-Catalysts” or as Substitute for Catalysts in Organophosphorus Chemistry. Molecules 26:4, pages 1196.
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Erika Bálint, Regina Eszter Tóth & György Keglevich. (2016) Synthesis of alkyl α-aminomethyl-phenylphosphinates and N,N -bis(alkoxyphenylphosphinylmethyl)amines by the microwave-assisted Kabachnik-Fields reaction . Heteroatom Chemistry 27:5, pages 323-335.
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Mubarak H. Shaikh, Dnyaneshwar D. Subhedar, Firoz A. Kalam Khan, Jaiprakash N. Sangshetti & Bapurao B. Shingate. (2015) [Et3NH][HSO4]-catalyzed one-pot, solvent-free synthesis and biological evaluation of α-amino phosphonates. Research on Chemical Intermediates 42:5, pages 5115-5131.
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Erika Bálint, Anna Tripolszky, Erzsébet Jablonkai, Konstantin Karaghiosoff, Mátyás Czugler, Zoltán Mucsi, László Kollár, Péter Pongrácz & György Keglevich. (2016) Synthesis and use of α-aminophosphine oxides and N,N-bis(phosphinoylmethyl)amines – A study on the related ring platinum complexes. Journal of Organometallic Chemistry 801, pages 111-121.
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Anguo Ying, Shuo Liu, Jianguo Yang & Huanan Hu. (2014) Synthesis of α-Amino Phosphonates under a Neat Condition Catalyzed by Multiple-Acidic Ionic Liquids. Industrial & Engineering Chemistry Research 53:42, pages 16143-16147.
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Erika Bálint, Eszter Fazekas, László Drahos & György Keglevich. (2013) The Synthesis of N,N -Bis(dialkoxyphosphinoylmethyl)- and N,N -Bis(diphenylphosphinoylmethyl)glycine Esters by the Microwave-Assisted Double Kabachnik-Fields Reaction . Heteroatom Chemistry 24:6, pages 510-515.
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György Keglevich & Erika Bálint. (2012) The Kabachnik–Fields Reaction: Mechanism and Synthetic Use. Molecules 17:11, pages 12821-12835.
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Mario Ordóñez, Francisco J. Sayago & Carlos Cativiela. (2012) Synthesis of quaternary α-aminophosphonic acids. Tetrahedron 68:32, pages 6369-6412.
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Nóra Zsuzsa Kiss, Anna Kaszás, László Drahos, Zoltán Mucsi & György Keglevich. (2012) A neighbouring group effect leading to enhanced nucleophilic substitution of amines at the hindered α-carbon atom of an α-hydroxyphosphonate. Tetrahedron Letters 53:2, pages 207-209.
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Vellaisamy Sridharan & J. Carlos Menéndez. (2010) Cerium(IV) Ammonium Nitrate as a Catalyst in Organic Synthesis. Chemical Reviews 110:6, pages 3805-3849.
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Nicolas Louaisil, Nicolas Rabasso & Antoine Fadel. (2009) Highly stereoselective synthesis of new α-amino-β-hydroxy six-membered heterocyclic phosphonic acids, serine analogues. Tetrahedron 65:41, pages 8587-8595.
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Mona Hosseini-Sarvari. (2008) TiO2 as a new and reusable catalyst for one-pot three-component syntheses of α-aminophosphonates in solvent-free conditions. Tetrahedron 64:23, pages 5459-5466.
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Nicolas Rabasso, Nicolas Louaisil & Antoine Fadel. (2006) Synthesis of α-amino tetrahydropyranyl-, tetrahydrothiopyranyl-, 4- and 3-piperidinyl-phosphonic acids via phosphite addition to iminium ions. Tetrahedron 62:31, pages 7445-7454.
Crossref
K. Ravinder, A. Vijender Reddy, P. Krishnaiah, G. Venkataramana, V. L. Niranjan Reddy & Y. Venkateswarlu. (2004) CAN Catalyzed One‐Pot Synthesis of α‐Amino Phosphonates from Carbonyl Compounds.. ChemInform 35:39.
Crossref

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