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Solvent Extraction and Ion Exchange Volume 20, 2002 - Issue 1
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Original Articles

EXTRACTION OF ACTINIDES(III), (IV), (V), (VI), AND LANTHANIDES(III) BY STRUCTURALLY TAILORED DIAMIDES

Yuji Sasaki Research Group for Separation Chemistry, Department of Materials Science, Japan Atomic Energy Research Institute, Tokai, Ibaraki, 319-1195, JapanCorrespondence[email protected]
&
Shoichi Tachimori Research Group for Separation Chemistry, Department of Materials Science, Japan Atomic Energy Research Institute, Tokai, Ibaraki, 319-1195, Japan
Pages 21-34 | Received 15 Jun 2001, Published online: 15 Feb 2007

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Ryoma Kinoshita, Masahiko Matsumiya & Yuji Sasaki. (2022) Recovery of Palladium by Extraction-electrodeposition Using N, N, N’, N’, N”, N”- Hexaoctyl-nitrilotriacetamide. Solvent Extraction and Ion Exchange 40:6, pages 606-619.
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Qian Liu, Jin Zhou, Liyang Zhu, Yan Zhang, Dingming Li, Suliang Yang & Guoxin Tian. (2020) Extraction of Actinides Including Neptunyl (V) by Asymmetrical N,N’-Dimethyl-N,N’-Dioctyl-Diglycolamide in Comparison with Symmetrical N,N,N’,N’-Tetraoctyl-Diglycolamide—Sterically Structural Insight into Actinide Separations†. Solvent Extraction and Ion Exchange 38:5, pages 485-495.
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Yan-Ning Niu, Peng Ren, Fang Zhang & Ze-Yi Yan. (2018) Solvent extraction of Eu3+ with 4-oxaheptanediamide into ionic liquid system. Separation Science and Technology 53:17, pages 2750-2755.
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Meena B Singh, Suneha R Patil, Aishwarya A Lohi & Vilas G. Gaikar. (2018) Insight into nitric acid extraction and aggregation of N, N, N’, N’-Tetraoctyl diglycolamide (TODGA) in organic solutions by molecular dynamics simulation. Separation Science and Technology 53:9, pages 1361-1371.
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Y.A. El-Nadi. (2017) Solvent Extraction and Its Applications on Ore Processing and Recovery of Metals: Classical Approach. Separation & Purification Reviews 46:3, pages 195-215.
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Yuji Sasaki, Ryo Yoshimitsu, Syouhei Nishihama, Yuma Shimbori & Hidenobu Shiroishi. (2017) Solvent extraction of metal ions using a new extractant, biuret(C8). Separation Science and Technology 52:7, pages 1186-1192.
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Yuji Sasaki, Yumi Sugo, Keisuke Morita & Kenneth L. Nash. (2015) The Effect of Alkyl Substituents on Actinide and Lanthanide Extraction by Diglycolamide Compounds. Solvent Extraction and Ion Exchange 33:7, pages 625-641.
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Dongping Su, Huang Huang, Song Huang, Ning Liu & Songdong Ding. (2015) Extraction of Trivalent Europium and Americium from Nitric Acid Solution with Bisdiglycolamides. Separation Science and Technology 50:9, pages 1384-1393.
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J. Borrini, A. Favre-Reguillon, M. Lemaire, S. Gracia, G. Arrachart, G. Bernier, X. Hérès, C. Hill & S. Pellet-Rostaing. (2015) Water Soluble PDCA Derivatives for Selective Ln(III)/An(III) and Am(III)/Cm(III) Separation. Solvent Extraction and Ion Exchange 33:3, pages 224-235.
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S. Chapron, C. Marie, G. Arrachart, M. Miguirditchian & S. Pellet-Rostaing. (2015) New Insight into the Americium/Curium Separation by Solvent Extraction using Diglycolamides. Solvent Extraction and Ion Exchange 33:3, pages 236-248.
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Michael Carrott, Katie Bell, Jamie Brown, Andreas Geist, Colin Gregson, Xavier Hères, Chris Maher, Rikard Malmbeck, Chris Mason, Giuseppe Modolo, Udo Müllich, Mark Sarsfield, Andreas Wilden & Robin Taylor. (2014) Development of a New Flowsheet for Co-Separating the Transuranic Actinides: The “EURO-GANEX” Process. Solvent Extraction and Ion Exchange 32:5, pages 447-467.
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Yuji Sasaki, Yasuhiro Tsubata, Yoshihiro Kitatsuji, Yumi Sugo, Noriko Shirasu & Yasuji Morita. (2014) Novel Extractant, NTAamide, and its Combination with TEDGA for Mutual Separation of Am/Cm/Ln. Solvent Extraction and Ion Exchange 32:2, pages 179-188.
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M. J. Carrot, C. R. Gregson & R. J. Taylor. (2013) Neptunium Extraction and Stability in the GANEX Solvent: 0.2 M TODGA/0.5 M DMDOHEMA/Kerosene. Solvent Extraction and Ion Exchange 31:5, pages 463-482.
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Jamie Brown, Fiona McLachlan, Mark Sarsfield, Robin Taylor, Giuseppe Modolo & Andreas Wilden. (2012) Plutonium Loading of Prospective Grouped Actinide Extraction (GANEX) Solvent Systems based on Diglycolamide Extractants. Solvent Extraction and Ion Exchange 30:2, pages 127-141.
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M. Yu. Alyapyshev, V. A. Babain, L. I. Tkachenko, I. I. Eliseev, A. V. Didenko & M. L. Petrov. (2011) Dependence of Extraction Properties of 2,6-Dicarboxypyridine Diamides on Extractant Structure. Solvent Extraction and Ion Exchange 29:4, pages 619-636.
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Andreas Wilden, Christian Schreinemachers, Michal Sypula & Giuseppe Modolo. (2011) Direct Selective Extraction of Actinides (III) from PUREX Raffinate using a Mixture of CyMe4BTBP and TODGA as 1-cycle SANEX Solvent. Solvent Extraction and Ion Exchange 29:2, pages 190-212.
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Mudassir Iqbal, Jurriaan Huskens, Willem Verboom, Michal Sypula & Giuseppe Modolo. (2010) Synthesis and Am/Eu extraction of novel TODGA derivatives. Supramolecular Chemistry 22:11-12, pages 827-837.
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Yuji Sasaki, Yasuji Morita, Yoshihiro Kitatsuji & Takaumi Kimura. (2010) Extraction Behavior of Actinides and Metal Ions by the Promising Extractant, N,N,N′,N′-Tetraoctyl-3,6-dioxaoctanediamide (DOODA). Solvent Extraction and Ion Exchange 28:3, pages 335-349.
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A. N. Turanov, V. K. Karandashev, V. E. Baulin, A. N. Yarkevich & Z. V. Safronova. (2009) Extraction of Lanthanides(III) from Aqueous Nitrate Media with Tetra‐(p‐tolyl)[(o‐Phenylene)Oxymethylene] Diphosphine Dioxide. Solvent Extraction and Ion Exchange 27:4, pages 551-578.
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Yuji Sasaki, Masaki Ozawa, Takaumi Kimura & Kousaburo Ohashi . (2009) 2,2′‐(Methylimino)bis(N,N‐dioctylacetamide) (MIDOA), A New Tridentate Extractant for Technetium(VII), Rhenium(VII), Palladium(II), and Plutonium(IV) . Solvent Extraction and Ion Exchange 27:3, pages 378-394.
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María Teresa Murillo, AmparoG. Espartero, Jorge Sánchez‐Quesada, Javier de Mendoza$suffix/text()$suffix/text() & Pilar Prados. (2009) Synthesis of Pre‐Organized Bisdiglycolamides (BisDGA) and Study of their Extraction Properties for Actinides(III) and Lanthanides(III). Solvent Extraction and Ion Exchange 27:2, pages 107-131.
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A. Paulenova, M. Yu. Alyapyshev, V. A. Babain, R. S. Herbst & J. D. Law. (2008) Extraction of Lanthanides with Diamides of Dipicolinic Acid from Nitric Acid Solutions. I. Separation Science and Technology 43:9-10, pages 2606-2618.
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A. N. Turanov, V. K. Karandashev & V. E. Baulin. (2008) Effect of Anions on the Extraction of Lanthanides (III) by N,N′‐Dimethyl‐N,N′‐Diphenyl‐3‐Oxapentanediamide. Solvent Extraction and Ion Exchange 26:2, pages 77-99.
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Yuji SASAKI, Zhi-Xuan ZHU, Yumi SUGO & Takaumi KIMURA. (2007) Extraction of Various Metal Ions from Nitric Acid to n-dodecanen by Diglycolamide (DGA) Compounds. Journal of Nuclear Science and Technology 44:3, pages 405-409.
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E. A. Mowafy & H. F. Aly. (2006) Extraction Behaviors of Trivalent Lanthanides from Nitrate Medium by Selected Substituted Malonamides. Solvent Extraction and Ion Exchange 24:5, pages 677-692.
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Yuji SASAKI & Shigeo UMETANI. (2006) Comparison of Four Bidentate Phosphoric and Diamide Compounds for the Extractability of Actinides. Journal of Nuclear Science and Technology 43:7, pages 794-797.
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Kornelia Matloka, Artem Gelis, Monica Regalbuto, George Vandegrift & Michael J. Scott. (2006) C 3‐Symmetric Tripodal Thio/Diglycolamide‐Based Ligands for Trivalent f‐Element Separations. Separation Science and Technology 41:10, pages 2129-2146.
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Ch. Siva Kesava Raju, S. Srinivasan & M. S. Subramanian. (2005) New Multi‐Dentate Ion‐Selective AXAD‐16‐MOPPA Polymer for the Preconcentration and Sequential Separation of U(VI), Th(IV) from Rare Earth Matrix. Separation Science and Technology 40:11, pages 2213-2230.
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E. P. Horwitz, D. R. McAlister, A. H. Bond & R. E. Barrans$suffix/text()$suffix/text(). (2005) Novel Extraction of Chromatographic Resins Based on Tetraalkyldiglycolamides: Characterization and Potential Applications. Solvent Extraction and Ion Exchange 23:3, pages 319-344.
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M. Akhila Maheswari & M. S. Subramanian. (2005) Amide Grafted Amberlite XAD‐16 Polymer for the Selective and Sequential Separation of U(VI) and Th(IV) from Acidic Waste Effluents. Solvent Extraction and Ion Exchange 23:2, pages 249-263.
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M. Akhila Maheswari & M. S. Subramanian. (2005) Selective Extraction of Actinides Using EEBEHBA Grafted Polymer: A Green Process for Nuclear Reprocessing Program. Separation Science and Technology 39:15, pages 3621-3638.
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Ampika Apichaibukol, Yuji Sasaki & Yasuji Morita. (2004) Effect of DTPA on the Extractions of Actinides(III) and Lanthanides(III) from Nitrate Solution into Todga/n‐Dodecane. Solvent Extraction and Ion Exchange 22:6, pages 997-1011.
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S. Nave, G. Modolo, C. Madic & F. Testard. (2004) Aggregation Properties of N,N,N′,N′‐Tetraoctyl‐3‐oxapentanediamide (TODGA) in n‐Dodecane. Solvent Extraction and Ion Exchange 22:4, pages 527-551.
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A. N. Turanov, V. K. Karandashev, A. N. Yarkevich & Z. V. Safronova. (2004) Extraction of U(VI), Th(IV), Sc(III), and Rare‐Earth Elements from Nitric Acid Solutions by Selected Bifunctional Neutral Organophosphorus Compounds. Solvent Extraction and Ion Exchange 22:3, pages 391-413.
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A. Shimada, T. Yaita, H. Narita, S. Tachimori & K. Okuno. (2004) Extraction Studies of Lanthanide(III) Ions with N,N′‐Dimethyl‐N,N′‐diphenylpyridine‐2,6‐dicarboxyamide (DMDPhPDA) from Nitric Acid Solutions. Solvent Extraction and Ion Exchange 22:2, pages 147-161.
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M. C. Costa, A. Carvalho, A. Uryga & A. P. Paiva. (2003) Solvent Extraction of Iron(III) from Hydrochloric Acid Solutions Using N,N′‐Dimethyl‐N,N′‐diphenylmalonamide and N,N′‐Dimethyl‐N,N′‐diphenyltetradecylmalonamide. Solvent Extraction and Ion Exchange 21:5, pages 653-686.
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I. M. Ismail, M. Nogami & K. Suzuki. (2003) The Utilization of TMMA Chelating Resin for the Adsorption of U(VI) and Some Lanthanide Ions from Acidic Media. Solvent Extraction and Ion Exchange 21:3, pages 465-481.
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