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Original Articles

EXTRACTION BEHAVIOURS OF Nd(III), Eu(III), La(III), Am(III), AND U(VI) WITH SOME SUBSTITUTED MALONAMIDES FROM NITRATE MEDIUM

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Pages 177-194 | Published online: 15 Feb 2007

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Mahmoud A. Mosleh, Elham H. El-Hakim, Anwar Z. Ahmed, Mohamed S. Abd El-Ghany & Akram M. El-Didamony. (2022) Equilibrium and kinetic studies on uranium sorption from aqueous sulphate medium using tri-n-octylamine impregnated resin. International Journal of Environmental Analytical Chemistry 102:14, pages 3255-3270.
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E. A. Mowafy, A. Alshammari & D. Mohamed. (2022) Extraction Behaviors of Critical Rare Earth Elements with Novel Structurally Tailored Unsymmetrical Diglycolamides from Acidic Media. Solvent Extraction and Ion Exchange 40:4, pages 387-411.
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Andreas Geist, Laurence Berthon, Marie-Christine Charbonnel & Udo Müllich. (2020) Extraction of Nitric Acid, Americium(III), Curium(III), and Lanthanides(III) into DMDOHEMA Dissolved in Kerosene. Solvent Extraction and Ion Exchange 38:7, pages 681-702.
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M. A. Gado. (2018) Sorption of thorium using magnetic graphene oxide polypyrrole composite synthesized from natural source. Separation Science and Technology 53:13, pages 2016-2033.
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Emily Campbell, Vanessa E. Holfeltz, Gabriel B. Hall, Kenneth L. Nash, Gregg J. Lumetta & Tatiana G. Levitskaia. (2018) Extraction Behavior of Ln(III) Ions by T2EHDGA/n-Dodecane from Nitric Acid and Sodium Nitrate Solutions. Solvent Extraction and Ion Exchange 36:4, pages 331-346.
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Elena Macerata, Annalisa Ossola, Walter Panzeri, Marco Giola, Federica Faroldi, Dario Alberto Tinonin, Andrea Mele, Alessandro Casnati & Mario Mariani. (2018) Actinide–lanthanide co-extraction by rigidified diglycolamides. Solvent Extraction and Ion Exchange 36:1, pages 41-53.
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Emily L Campbell, Vanessa E Holfeltz, Gabriel B Hall, Kenneth L Nash, Gregg J Lumetta & Tatiana G Levitskaia. (2017) Nitric Acid and Water Extraction by T2EHDGA in n-Dodecane. Solvent Extraction and Ion Exchange 35:7, pages 586-603.
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E. A. Mowafy & D. Mohamed. (2017) Extraction of rare earth elements from nitrate solution using novel unsymmetrical diglycolamide. Separation Science and Technology 52:6, pages 1006-1014.
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Ajay B. Patil, P. N. Pathak, V. S. Shinde & P. K. Mohapatra. (2014) Synthesis and Evaluation of N,N′-dimethyl-N,N′-dicyclohexyl-Malonamide (DMDCMA) as an Extractant for Actinides. Separation Science and Technology 49:18, pages 2927-2932.
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M. J. Carrot, C. R. Gregson & R. J. Taylor. (2013) Neptunium Extraction and Stability in the GANEX Solvent: 0.2 M TODGA/0.5 M DMDOHEMA/Kerosene. Solvent Extraction and Ion Exchange 31:5, pages 463-482.
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Mohsen M. Aly & Mohammed F. Hamza. (2013) A Review: Studies on Uranium Removal Using Different Techniques. Overview. Journal of Dispersion Science and Technology 34:2, pages 182-213.
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Sun Guoxin, Liu Min, Cui Yu, Yuan Meilong & Yin Shaohong. (2010) Synthesis of N,N′-Dimethyl-N,N′-Dioctyl-3-Oxadiglycolamide and its Extraction Properties for Lanthanides. Solvent Extraction and Ion Exchange 28:4, pages 482-494.
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Gregg J. Lumetta, Artem V. Gelis & George F. Vandegrift. (2010) Review: Solvent Systems Combining Neutral and Acidic Extractants for Separating Trivalent Lanthanides from the Transuranic Elements. Solvent Extraction and Ion Exchange 28:3, pages 287-312.
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B.N. Kokare, S.H. Han & M.A. Anuse. (2009) Solvent extraction of lanthanum(III) by N-n-octylaniline from salicylate media. Desalination and Water Treatment 12:1-3, pages 79-86.
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A. Paulenova, M. Yu. Alyapyshev, V. A. Babain, R. S. Herbst & J. D. Law. (2008) Extraction of Lanthanides with Diamides of Dipicolinic Acid from Nitric Acid Solutions. I. Separation Science and Technology 43:9-10, pages 2606-2618.
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M. C. Costa, I. Pêczek, Z. Sadowski, S. Natu & A. P. Paiva. (2007) The Solvent Extraction of Iron(III) from Chloride Solutions by N,N′‐Tetrasubstituted Malonamides: Structure‐Activity Relationships. Solvent Extraction and Ion Exchange 25:4, pages 463-484.
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E. A. Mowafy & H. F. Aly. (2007) Synthesis of some N,N,N′,N′‐Tetraalkyl‐3‐Oxa‐Pentane‐1,5‐Diamide and their Applications in Solvent Extraction. Solvent Extraction and Ion Exchange 25:2, pages 205-224.
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E. A. Mowafy & H. F. Aly. (2006) Extraction Behaviors of Trivalent Lanthanides from Nitrate Medium by Selected Substituted Malonamides. Solvent Extraction and Ion Exchange 24:5, pages 677-692.
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Yuji SASAKI & Shigeo UMETANI. (2006) Comparison of Four Bidentate Phosphoric and Diamide Compounds for the Extractability of Actinides. Journal of Nuclear Science and Technology 43:7, pages 794-797.
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Ch. Siva Kesava Raju, S. Srinivasan & M. S. Subramanian. (2005) New Multi‐Dentate Ion‐Selective AXAD‐16‐MOPPA Polymer for the Preconcentration and Sequential Separation of U(VI), Th(IV) from Rare Earth Matrix. Separation Science and Technology 40:11, pages 2213-2230.
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M. Akhila Maheswari & M. S. Subramanian. (2005) Amide Grafted Amberlite XAD‐16 Polymer for the Selective and Sequential Separation of U(VI) and Th(IV) from Acidic Waste Effluents. Solvent Extraction and Ion Exchange 23:2, pages 249-263.
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M. Akhila Maheswari & M. S. Subramanian. (2005) Selective Extraction of Actinides Using EEBEHBA Grafted Polymer: A Green Process for Nuclear Reprocessing Program. Separation Science and Technology 39:15, pages 3621-3638.
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M. C. Costa, M. Martins & A. P. Paiva. (2005) Solvent Extraction of Iron(III) from Acidic Chloride Media Using N,N′‐Dimethyl‐N,N′‐dibutylmalonamide. Separation Science and Technology 39:15, pages 3573-3599.
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I. M. Ismail, M. Nogami & K. Suzuki. (2003) The Utilization of TMMA Chelating Resin for the Adsorption of U(VI) and Some Lanthanide Ions from Acidic Media. Solvent Extraction and Ion Exchange 21:3, pages 465-481.
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Gregg J. Lumetta, Brian M. Rapko, Benjamin P. Hay, Priscilla A. Garza, James E. Hutchison & Robert D. Gilbertson. (2003) A Novel Bicyclic Diamide with High Binding Affinity for Trivalent f‐Block Elements. Solvent Extraction and Ion Exchange 21:1, pages 29-39.
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Articles from other publishers (39)

E. Makombe, D. Bourgeois, L. Berthon & D. Meyer. (2022) Uranium(VI) and thorium(IV) extraction by malonamides: Impact of ligand molecular topology on selectivity. Journal of Molecular Liquids 368, pages 120701.
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Nitesh Kumar & Aurora E. Clark. (2021) Unexpected inverse correlations and cooperativity in ion-pair phase transfer. Chemical Science 12:41, pages 13930-13939.
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Cesar L. Usma, S. Dourdain, G. Arrachart & S. Pellet-Rostaing. (2021) Solvent extraction of rare earths elements from nitrate media in DMDOHEMA/ionic liquid systems: performance and mechanism studies. RSC Advances 11:50, pages 31197-31207.
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Abiodun D. Aderibigbe & David P. Day. (2020) Syntheses and Applications of Malonamide Derivatives – A Minireview. ChemistrySelect 5:48, pages 15222-15232.
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E. A. Mowafy, A. M. Al Shammari & D. Mohamed. (2019) Extraction of Uranium, Thorium, and Certain Lanthanides from Nitric Acid Medium with a Series of Substituted Glutaramides as Novel Extractants. Radiochemistry 61:6, pages 681-688.
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Mikhail S. Tyumentsev, Mark R.St.J. Foreman, Britt-Marie Steenari & Christian Ekberg. (2019) Temperature effect on the distribution of lanthanides(III) in the perchlorate-malonamide-methyl isobutyl ketone systems. The Journal of Chemical Thermodynamics 131, pages 133-148.
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Masashi Kaneko, Hideya Suzuki & Tatsuro Matsumura. (2018) Theoretical Elucidation of Am(III)/Cm(III) Separation Mechanism with Diamide-type Ligands Using Relativistic Density Functional Theory Calculation. Inorganic Chemistry 57:23, pages 14513-14523.
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D. Mohamed. (2017) Extraction of U(VI) and Th(IV) ions from nitric acid solutions with N,N,N′,N′-tetra-2-ethylhexylglutaramide. Radiochemistry 59:4, pages 354-359.
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Masashi Kaneko, Masayuki Watanabe, Sunao Miyashita & Satoru Nakashima. (2017) Roles of d- and f-orbital electrons in the complexation of Eu(III) and Am(III) ions with alkyldithiophosphinic acid and alkylphosphinic acid using scalar-relativistic DFT calculations. Journal of Nuclear and Radiochemical Sciences 17:0, pages 9-15.
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Zong-Bo Xie, Hai-Tao Kang, Zhong-Sheng Chen, Sui-Hong Zhang & Zhang-Gao Le. (2015) Liquid–liquid extraction of U(VI) using malonamide in room temperature ionic liquid. Journal of Radioanalytical and Nuclear Chemistry 308:2, pages 573-578.
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D. Mohamed, A. Alshammari & E. A. Mowafy. (2015) Liquid–liquid extraction of certain trivalent lanthanides from nitrate solutions with N,N,N',N'-tetrabutylsuccinamide as new extractant. Radiochemistry 57:6, pages 602-609.
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Aniruddha M. Mandhare, Sung-H Han, Mansing A. Anuse & Sanjay S. Kolekar. (2015) Liquid–liquid anion exchange extraction studies of samarium(III) from salicylate media using high molecular weight amine. Arabian Journal of Chemistry 8:4, pages 456-464.
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Ajay B. Patil, Vaishali S. Shinde, Priyanath Pathak & Prasanta K. Mohapatra. (2015) New extractant N,N′-dimethyl-N,N′-dicyclohexyl-2,(2′-dodecyloxyethyl)-malonamide (DMDCDDEMA) for radiotoxic acidic waste remediation: Synthesis, extraction and supported liquid membrane transport studies. Separation and Purification Technology 145, pages 83-91.
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Abolfazl Rahmani-Sani, Ahmad Hosseini-Bandegharaei, Seyyed-Hossein Hosseini, Keivan Kharghani, Hossein Zarei & Ayoob Rastegar. (2015) Kinetic, equilibrium and thermodynamic studies on sorption of uranium and thorium from aqueous solutions by a selective impregnated resin containing carminic acid. Journal of Hazardous Materials 286, pages 152-163.
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E.A. Mowafy & D. Mohamed. (2015) Extraction and separation of Nd(III), Sm(III), Dy(III), Fe(III), Ni(II), and Cs(I) from concentrated chloride solutions with N,N,N′,N′-tetra(2-ethylhexyl) diglycolamide as new extractant. Journal of Rare Earths 33:4, pages 432-438.
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Travis S. Grimes, Peter R. Zalupski & Leigh R. Martin. (2014) Features of the Thermodynamics of Trivalent Lanthanide/Actinide Distribution Reactions by Tri- n -octylphosphine Oxide and Bis(2-ethylhexyl) Phosphoric Acid . The Journal of Physical Chemistry B 118:44, pages 12725-12733.
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Tayebeh Hosseinnejad, Saeed Dehghanpour & Sara Basiri-nasab. (2014) A DFT study on the complexation of La3+ ion with malonamide and diglycolamide ligands. Russian Journal of Physical Chemistry A 88:11, pages 2004-2011.
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Mohammad Saeid Hosseini & Fatemeh Abedi. (2014) Comparison of adsorption behavior of Th(IV) and U(VI) on mixed-ligands impregnated resin containing antraquinones with that conventional one. Journal of Radioanalytical and Nuclear Chemistry.
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E.A. Mowafy & D. Mohamed. (2014) Extraction behavior of trivalent lanthanides from nitric acid medium by selected structurally related diglycolamides as novel extractants. Separation and Purification Technology 128, pages 18-24.
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Alok Rout & Koen Binnemans. (2014) Liquid–liquid extraction of europium( iii ) and other trivalent rare-earth ions using a non-fluorinated functionalized ionic liquid . Dalton Trans. 43:4, pages 1862-1872.
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Ajay B. Patil, Pankaj Kandwal, V.S. Shinde, P.N. Pathak & P.K. Mohapatra. (2013) Evaluation of DMDOHEMA based supported liquid membrane system for high level waste remediation under simulated conditions. Journal of Membrane Science 442, pages 48-56.
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Ajay B. Patil, Vaishali S. Shinde, P. N. Pathak, P. K. Mohapatra & V. K. Manchanda. (2013) Modified synthesis scheme for N , N ´-dimethyl- N , N ´-dioctyl-2,(2´-hexyloxyethyl) malonamide (DMDOHEMA) and its comparison with proposed solvents for actinide partitioning . Radiochimica Acta 101:2, pages 93-100.
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Alok Rout, K.A. Venkatesan, T.G. Srinivasan & P.R. Vasudeva Rao. (2012) Liquid–liquid extraction of Pu(IV), U(VI) and Am(III) using malonamide in room temperature ionic liquid as diluent. Journal of Hazardous Materials 221-222, pages 62-67.
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Gracy Elias, Gary S. Groenewold, Bruce J. Mincher & Stephen P. Mezyk. (2012) Determination of CMPO using HPLC–UV. Journal of Chromatography A 1243, pages 47-52.
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Balasaheb N. Kokare, Ganesh S. Kamble, Balasaheb M. Sargar & Mansing A. Anuse. (2012) Development of a Reliable Analytical Method for Liquid Anion-Exchange Extraction and Separation of Neodymium(III). The Scientific World Journal 2012, pages 1-7.
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Mohammad Saeid Hosseini & Ahmad Hosseini-Bandegharaei. (2011) Comparison of sorption behavior of Th(IV) and U(VI) on modified impregnated resin containing quinizarin with that conventional prepared impregnated resin. Journal of Hazardous Materials 190:1-3, pages 755-765.
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Yu Cui, Yufen Hu, Yanju Zhang, Shaohong Yin & Guoxin Sun. (2010) Extraction of U(VI) with N,N′-dimethyl-N,N′-dioctylmalonamide from nitrate media. Russian Journal of Inorganic Chemistry 55:3, pages 468-471.
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Yijia Yang & Spiro D. Alexandratos. (2009) Affinity of Polymer-Supported Reagents for Lanthanides as a Function of Donor Atom Polarizability. Industrial & Engineering Chemistry Research 48:13, pages 6173-6187.
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María Teresa Murillo, Amparo Glez Espartero, Marta Almaraz, Jorge Sánchez-Quesada, Margarita Segura, José-Carlos Iglesias-Sánchez, Javier de Mendoza & Pilar Prados. (2008) Bismalonamides (BISMA) as new extractants for Am(III) and Eu(III) from aqueous high-level wastes. Radiochimica Acta 96:4-5, pages 241-257.
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Fangli Fan, Fuan Lei, Huajie Ding, Jing Bai, Lina Zhang, Maosheng Lin, Xiaolei Wu & Zhi Qin. (2008) Solvent extraction of americium and europium ions by amide-derivatized polyethers from picric acid aqueous solution. Radiochimica Acta 96:3.
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E. A. Mowafy. (2007) Evaluation of selectivity and radiolysis behavior of some promising isonicotinamids and dipicolinamides as extractants. Radiochimica Acta 95:9, pages 539-545.
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Ch. Siva Kesava Raju & M.S. Subramanian. (2007) A novel solid phase extraction method for separation of actinides and lanthanides from high acidic streams. Separation and Purification Technology 55:1, pages 16-22.
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Mark P. Jensen, Tsuyoshi Yaita & Renato Chiarizia. (2007) Reverse-Micelle Formation in the Partitioning of Trivalent f-Element Cations by Biphasic Systems Containing a Tetraalkyldiglycolamide. Langmuir 23:9, pages 4765-4774.
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Cui Yu, Sun Guoxin, Zhang Zhenwei, Hu Yufen & Sun Sixiu. (2007) Extraction of U(VI) with N,N’-dimethyl-N,N’-dioctylsuccinylamide in toluene. Journal of Radioanalytical and Nuclear Chemistry 272:1, pages 199-201.
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M. Akhila Maheswari & M.S. Subramanian. (2006) Polymer based ion-sensor for the selective recognition of and Th4+ ions. Reactive and Functional Polymers 66:12, pages 1452-1461.
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Ch. Siva Kesava Raju, M. S. Subramanian, T. G. Srinivasan & P. R. Vasudeva Rao. (2006) BEHSA grafted polymer for selective extraction of U(VI), Th(IV) and La(III) from acidic matrices and environmental samples – a green process. Radiochimica Acta 94:6-7, pages 351-356.
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Romain Diss & Georges Wipff. (2005) Lanthanide cationextraction by malonamideligands: from liquid–liquid interfaces to microemulsions. A molecular dynamics study. Phys. Chem. Chem. Phys. 7:2, pages 264-272.
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M.A. Maheswari & M.S. Subramanian. (2005) AXAD-16-3,4-dihydroxy benzoyl methyl phosphonic acid: a selective preconcentrator for U and Th from acidic waste streams and environmental samples. Reactive and Functional Polymers 62:1, pages 105-114.
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Guo-Xin Sun, Yu Cui, Zhen-Wei Zhang, Rong-Qi Xu, Run-Tian Jiang & Si-Xiu Sun. (2004) The effect of diluents on the extraction of Sm(III) using N, N, N’, N’-tetrabutylmalonamide. Journal of the Serbian Chemical Society 69:8-9, pages 675-681.
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