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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 50, 2020 - Issue 20
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Articles

Palladium-catalyzed decarbonylative C–N coupling to convert arylcarbamoyl chlorides to urea derivatives

, , , &
Pages 3113-3124 | Received 24 Apr 2020, Published online: 20 Jul 2020
 

Abstract

This paper describes the development of a palladium-catalyzed decarbonylative C–N coupling reaction that transforms arylcarbamoyl chlorides into tetrasubstituted ureas under a nitrogen atmosphere. A broad range of functional groups are compatible with this reaction, and diverse urea derivatives can be obtained with good to high yields.

Graphical Abstract

Disclosure statement

The authors declare no conflict of interest.

Additional information

Funding

The authors are grateful for financial support from the Fundamental Research Funds for the Central Universities (2572017DB07), and Natural Science Foundation of Heilongjiang Province (B2017002, LC2018003).

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