On correlation of rheological, thermal, mechanical and morphological properties of chemical assisted mechanically blended ABS-Graphene composite as tertiary recycling for 3D printing applications

ABSTRACT

In past two decades, numerous 3D printing applications of acrylonitrile butadiene styrene (ABS) based mechanically blended composites for secondary (2°) recycling has been reported. But hitherto little has been reported on correlation of rheological, thermal, mechanical and morphological properties of chemical assisted mechanically blended ABS-Graphene (Gr) composite as tertiary (3°) recycling. In the present work chemical assisted mechanical blending of ABS and Gr nano particles (size 5–10 nm in three different weight proportions i.e. 10, 15 and 20%) has been reported. The effect of increasing Gr proportion was studied for establishing the correlation among rheological (melt flow index (MFI)) and viscosity), thermal, mechanical and morphological properties. The results of the MFI and viscosity testing showed that 20%Gr in ABS decreases the MFI and increases the viscosity of the composite matrix. The thermal testing showed that ABS+20%Gr composite have highest heat capacity (0.84 j/g) among selected proportions of matrix. As regards to mechanical properties are concerned, best settings are: ABS+20%Gr, temperature 210°C with 0.5 Nm torque for filament wire preparation on twin screw extruder (TSE). Morphological properties of filament wires were studied on metallurgical microscope to observe porosity percentage (%) in wire samples which was found minimum for ABS+20Gr.

KEYWORDS:

• ABS
• graphene
• chemical assisted blending
• mfi
• viscosity
• 3d printing

Acknowledgments

The authors are grateful to Manufacturing Research Lab, Production Engg. Dept., GNDEC, Ludhiana, Punjab, India; Department of Mechanical Engineering, NITTTR, Chandigarh, India and Department of Mechanical Engineering, Punjabi university, Patiala, India for providing great support and lab facilities in respective departments.

Disclosure statement

No potential conflict of interest was reported by the author(s).

Additional information

Funding

The authors received financial support from Department of Science and Technology (DST), (Govt. of India) under DST SHRI project File No: DST/TDT/SHRI-35/2018 for the present research work; Department of Science and Technology, Ministry of Science and Technology, India [DST/TDT/SHRI-35/2018] .