ABSTRACT
TATB and TATB-d6 were synthesized using phloroglucinol as raw material. Their molecular structure and micromorphology of them were well characterized by FTIR, NMR spectroscopy, XRD and FE-SEM. The thermal behaviors of these compounds were studied with TG-DSC, and the non-isothermal kinetic decomposition parameters of the two compounds were gained using the method of Friedman (FM). The apparent activation energy value of TATB-d6 was larger than that of TATB, which indicated the heat stabilization of deuterated TATB particles was improved. Finally, the thermal detonation critical temperatures of these two products were also calculated and discussed.
Availability of Data and Material
We confirm the availability of all the data and materials in this manuscript. The manuscript has full control of all primary data, and the authors agree to allow the journal to review their data if requested.
Consent to Participate
All the authors agree to participate in this investigation.
Disclosure statement
No potential conflict of interest was reported by the author(s).
Ethical Statement
We allow the journal to review all the data, and we confirm the validity of results. There is none of the financial relationships. This work was not published previously and it is not submitted to more than one journal. It is also not split up into several parts to submit. No data have been fabricated or manipulated.