Abstract
This work was aimed at evaluating the adsorption characteristics of beta-cyclodextrin (β-CD) chars. Char was prepared by pyrolysis in a furnace at 550 °C, while spherical hydrochar was obtained through hydrothermal carbonization in a Teflon autoclave at 180 °C. Both chars are water-insoluble and were prepared without cross-linking agents. They were characterized for functional groups, thermal degradation, and surface morphology. The applicability of chars in adsorption was studied using malachite green solution at varying concentrations, contact times and temperatures. Hydrochar exhibits a better malachite green capacity of 18 mg/g. The adsorption rate and equilibrium data fitted well into pseudo-first-order and pseudo-second-order kinetics, and Langmuir and Dubinin–Radushkevich models, respectively. The thermodynamic parameters suggested that the removal process is spontaneous and endothermic in nature.
Graphical Abstract
Acknowledgements
This work was part of NH Omar’s dissertation for the award of Master of Engineering.
Authors’ contributions
NH Omar (Research Associate): Conceptualization, methodology, experimental work, analysis, first draft. MAA Zaini (Associate Professor): Grant recipient, supervision, conceptualization, review, validation.
Disclosure statement
All authors declare that they have no competing interests.
Data availability statement
Data will be made available upon request.