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Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry Volume 36, 2006 - Issue 5
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Original Articles

Synthesis and Crystal Structure of a New Anderson‐Type Complex [Na(H2O)2]6[MoCo6O12(H2O)12] · 4.3H2O

Yan‐Mei Chen Department of Chemistry, Lanzhou University, Lanzhou, P.R. China
,
Zheng‐Hua Ju Department of Chemistry, Lanzhou University, Lanzhou, P.R. China
,
Ji‐Gui Wu Department of Chemistry, Lanzhou University, Lanzhou, P.R. China
&
Ka‐Ling Yao Department of Chemistry, Lanzhou University, Lanzhou, P.R. ChinaCorrespondence[email protected]
Pages 407-410 | Received 16 Jan 2006, Accepted 27 Feb 2006, Published online: 15 Feb 2007
 
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Abstract

A new complex with the formula [Na(H2O)2]6[MoCo6O12 (H2O)12] · 4.3H2O has been synthesized and characterized by single crystal X‐ray diffraction, thermal study, infrared spectrum. The complex is rose rhombic crystal and space group R‐3 m with a=11.9396(15) Å, b=11.9396(15) Å, c=22.995(3) Å, α=90°, β=90°, γ=120°, V=2838.9(9) Å3, Z=3, and R1=0.0612. The structure of the anion [MoCo6O12(H2O)12]6− has a hexagonal plane structure composed of a central Mo ion surrounded by six octahedron CoO6 groups. Each CoO6 shares an edge with each of its two neighboring CoO6 and another edge with the MoO6 octahedron. This is similar to the Anderson‐type strucure. This new complex is colbaltmolybdate described.

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