94
Views
1
CrossRef citations to date
0
Altmetric
Original Articles

Synthesis and Crystal Structure of a New Anderson‐Type Complex [Na(H2O)2]6[MoCo6O12(H2O)12] · 4.3H2O

, , &
Pages 407-410 | Received 16 Jan 2006, Accepted 27 Feb 2006, Published online: 15 Feb 2007

References

  • Kumagai , H. , Oka , Y. , Kawata , S. , Ohba , M. Lnoue , K. 2003 . Hydrothermal synthesis, crystal structure and characterization of a new hexanuclear cobalt(II) comprised of octahedral and tetrahedral cobalt Ions . Polyhedr. , 22 : 1917 – 1920 .
  • Kumagai , H. , Oka , Y. , Ohba , M. , Inoue , K. and Okawa , H. 2002 . Synthesis and characterization of a tetrahedral and octahedral cobalt(II) alternate chain complex . Chem. Lett. , : 1006 – 1007 .
  • Botto , I. L. , Cabello , C. I. , Minelli , G. and Occhiuzzi , M. 1994 . Reductibility and spectroscopic behaviors of the (NH4)4[CuMo6O24H6] · 4H2O Anderson phase . Chem. Phys. , 39 ( 1 ) : 21 – 28 .
  • Liu , T. , Asakura , K. , Lee , U. , Matsui , Y. and Iwasawa , Y. 1992 . Structure and crystalytic activity of Pt‐Mo bimetallic ensembles derived from a new planar [PtMo6O24]8− heteropolyanion supported on Al2O3 and SiO2 . J. Catal. , 135 ( 2 ) : 367 – 385 .
  • Anderson , J. S. 1937 . Constitution of the polyacids . Nature , 140 : 850 – 850 .
  • Evans , H. T. and Gatehouse , B. M. 1975 . Crystal structure of the heptamolybdate(VI) (paramolybdate) ion [Mo7O24]6−, in the ammonium and potassium tetrahydrate . J. Chem. Soc. Dalton. Trans. , 2 : 505 – 514 .
  • Botto , I. L. , Cabello , C. I. and Thomas , H. J. 1997 . (NH4)6[TeMo6O24] ·4H2O Anderson phase as precursor of the TeMo5O16 catalytic phase: Thermal and spectroscopic studies . Mater. Chem. Phys. , 47 : 37 – 45 .
  • Botto , I. L. , Cabello , C. I. , Thomas , H. J. , Cordischi , D. , Minelli , G. and Porta , P. 2000 . Mater. reduction process of the (NH4)3[CrMo6O24H6] · 7H2O Anderson phase: Spectroscopic, structural and morphological properties . Chem. Phy. , 62 : 254 – 262 .
  • Martin , C. , Lamonier , C. , Fournier , M. , Mentre , Q. , Harle , V. , Guillaume , D. and Payen , E. 2004 . Preparation and characterization of 6‐molybdocobaltate and 6‐molybdoaluminate cobalt salt, evidence of a new heteropolymolybdate structure . Inorg. Chem. , 43 ( 15 ) : 4636 – 4644 .
  • Cabello , C. I. , Cabrerizo , F. M. , Alvarez , A. and Thomas , H. J. 2000 . Anderson type heteropolyoxomolybdates in catalysis: 1. (NH4)3[CoMo6O24H6] · 7H2O/γ‐Al2O3 as alternative of Co‐Mo/γ‐Al2O3 hydrotreating catalysis . App. Cat. A: General , 197 : 79 – 86 .
  • Cabello , C. I. , Cabrerizo , F. M. , Alvarez , A. and Thomas , H. J. 2002 . Decamolybdodicobaltate(III) heteropolyanion: Structural, spectroscopical, thermal and hydrotreating catalytic properties . J. Mol. Cat. A: Chem. , 186 : 89 – 100 .
  • Sheldrick , G. M. 1997 . “ SHELXS‐97, Program for the solution of crystal structures ” . In Göttingen
  • Sheldrick , G. M. 1997 . “ SHELXL‐97, Program for the refinement of crystal structures ” . In Göttingen
  • Cabello , C. I. , Botto , I. L. and Thomas , H. J. 1994 . Reducibility and thermal behaviour of some Anderson phase . Thermochim. Acta , 232 : 183 – 193 .

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.