Molecular interaction study through experimental and theoretical volumetric, transport and refractive properties of N-ethylaniline with aryl and alkyl ethers at several temperatures

Abstract

To investigate the molecular interaction study between secondary amine with aryl and alkyl ether, we report densities, speeds of sound, viscosities and refractive indices of N-ethylaniline (NEA) with aryl (anisole, phenetole) and alkyl (tert-butyl methyl ether) ether over the entire composition regime and in the temperature range of 293.15–323.15 K at 5 K intervals. Various excess and transport properties were derived from the experimental data and the excess parameters were fitted to the Redlich–Kister polynomial equation using multiparametric non-linear regression analysis to derive the binary coefficients and to estimate the standard deviation. Molecular interactions between the unlike molecules were analysed through dipole–dipole interactions, cross-association between the components of the mixtures and H-bond formation. Viscosity and refractive index of the mixtures were predicted through several empirical equations and compared with the experimental results. Prigogine–Flory–Patterson statistical theory was used to predict the excess molar volume results.

Keywords:

• Excess molar volume
• molar isentropic compressibilities
• deviation in viscosity
• Prigogine–Flory–Patterson theory

ORCID

Naved I. Malek http://dx.orcid.org/0000-0002-2164-5268

Additional information

Funding

N.I.M. acknowledges the Department of Science and Technology, New Delhi, for providing the financial assistance [grant number SR/FT/CS-014/2010] to carry out this work. Financial assistance by the Council of Scientific and Industrial Research (CSIR), New Delhi [grant number 01 (2545) /11/EMR-II], is also acknowledged. Financial assistance through the Institute Research Grants to the assistant professors by SVNIT is also acknowledged.