Process modeling of direct Red-28 dye eradication by biopolymeric composite of polyaniline with mango leafy biowaste material

Abstract

The use of biopolymers and synthetic adsorbents for wastewater treatment is gaining more importance due to their ease of preparation and nontoxic nature. This study focuses on developing a new biopolymeric composite using Polyaniline and a leafy mulch of mango plants (PANI/ML) and applied to remove an anionic dye, i.e.: Direct Red-28 from water on a lab scale. Samples were characterized by various spectrochemical methods, like FT-IR, UV–Vis, and SEM analysis, and then used for adsorption studies. Results indicated that PANI/ML nanomaterial removed 203.25 ± 0.57 mg/g of Direct Red-28 dye, following chemisorption and pseudo-2nd order kinetic model with inter-layer diffusion mode. Desorption studies indicated that it can be recycled three times effectively. So, this composite can be used for adsorptive bioremediation of synthetic anionic pollutants.

Graphical Abstract

Keywords:

• Anionic dye
• biopolymer
• composites
• polyaniline
• adsorption

Acknowledgment

The authors are thankful to Taif University, Saudi Arabia, for supporting this work through project number (TU-DSPP-2024-232).

Disclosure statement

No potential conflict of interest was reported by the authors.

Data availability statement

All data is given with references.