Synthesis and Characterization of Nanorod Magnetic Co–Fe Mixed Oxides and its Catalytic Behavior Towards One-Pot Synthesis of Polysubstituted Pyridine Derivatives

ABSTRACT

The nanorod magnetic Fe₂O₃@Fe₃O₄@Co₃O₄ composite as a novel catalyst was synthesized and fully characterized using X-ray diffraction (XRD), energy-dispersive X-ray spectroscopy (EDS), scanning electron microscopy (SEM), and transmission electron microscopy. Moreover, the prepared nanorod magnetic Fe₂O₃@Fe₃O₄@Co₃O₄ composites were used as an efficient, cheap, and eco-friendly catalyst for the one-pot synthesis of polysubstituted pyridine derivatives. The catalyst is magnetically separable and recyclable up to the fourth run without significant loss of activity. The products were obtained in high yields (78%-97%) and purities via an easy workup procedure.

KEYWORDS:

• Fe₂O₃@Fe₃O₄@Co₃O₄ composite
• green chemistry
• magnetically recyclable
• nanorod magnetic
• polysubstituted pyridines

Acknowledgments

Authors wish to thank Hakim Sabzevari University for financial support to carry out this research.