Agglomeration of 10 nm amine-functionalized nano-magnetite does not hinder its efficiency as an environmental adsorbent

Abstract

Amine-functionalized magnetite (nFe₃O₄-NH₂) of two different sizes, 10 nm and 250 nm, were compared as environmental adsorbents. They were synthesized by co-precipitation (10 nm-nFe₃O₄-NH₂) and solvothermal (250 nm-nFe₃O₄-NH₂) methods, respectively. The prepared amine-functionalized magnetite was characterized by scanning electron microscope, transmission electron microscope, X-ray diffraction, vibrating sample magnetometer, Fourier transform infrared spectroscopy, size distribution analysis and surface area analysis to compare the properties of different sizes of nFe₃O₄-NH₂. Both nFe₃O₄-NH₂ contained cubic Fe₃O₄ crystalline structure. The 250 nm-nFe₃O₄-NH₂ exhibited higher magnetic saturation value than the 10 nm-nFe₃O₄-NH₂, but both could be separated from an aqueous solution using an external magnet. The surface area and pore volume of the smaller-sized 10 nm-nFe₃O₄-NH₂ was larger than that of 250 nm-nFe₃O₄-NH₂, but stronger aggregation was observed in the 10 nm-nFe₃O₄-NH₂. Batch adsorption of lead indicated that the 10 nm-nFe₃O₄-NH₂ was a better adsorbent than the 250 nm-nFe₃O₄-NH₂. The maximum adsorption capacity of lead for the 10 nm-nFe₃O₄-NH₂ and the 250 nm-nFe₃O₄-NH₂ were 74.48 mg g^–1 and 54.54 mg g^–1, respectively. The stronger aggregation of nanoparticles with a smaller particle size did not affect the superior performance of the 10 nm-nFe₃O₄-NH₂ as an environmental adsorbent.

Keywords:

• Magnetite
• amine
• nano
• adsorption
• aggregation

Additional information

Funding

This study was supported by the Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Science, ICT, & Future Planning (NRF-2018R1A2A1A05023555). The authors claim no conflicts of interest.