SnO wrap on SnS reinforced thermoelectric properties of CF/EG cement matrix composites

Abstract

In this study, SnO wrap on SnS was prepared and incorporated into carbon fiber/expanded graphite (CF/EG) cementitious composites by the coating process. The effects of different SnO wrap on SnS coating ratios and contents on the microstructures of CF/EG cementitious composites were investigated and discussed, and the thermoelectric properties of SnO wrap on SnS CF/EG cementitious composites were systematically investigated in the temperature range of 35–70 °C. The results show that the coating ratio and content of SnO wrap on SnS have a significant effect on the thermoelectric properties of CF/EG cementitious composites. It is noteworthy that when the SnO wrap on SnS is 2:1, the thermoelectric properties of its cementitious composites are greatly improved. For example, when it is added at 1.0 wt%, the conductivity is 2.27 S/cm, the Seebeck coefficient is 41.90 µV/°C and the power factor is 0.38 µW·m⁻¹K⁻². The addition of SnO wrap on SnS to CF/EG cementitious materials generates a large number of interfaces, and the presence of high-density interfaces hinders the motion of carriers, which leads to the scattering of carriers at the interfaces and enhances the Seebeck effect in cementitious composites. Therefore, SnO wrap on SnS has great potential for thermoelectric applications.

Keywords:

• Cementitious composites
• carbon fiber/expanded graphite
• metalsulfides
• thermoelectric properties

Disclosure statement

No potential conflict of interest was reported by the author(s).

Additional information

Funding

This study was supported by the National Natural Science Foundation of China General Project (51578448 and 52272089), National Natural Science Youth Fund Project (51308447), Shaanxi Province Outstanding Youth Science Foundation (2021JC-43), Shaanxi Province Natural Science Basic Research Program-Major Basic Research Project (2017ZDJC-18), and Scientific Research Program Funded by Shaanxi Provincial Education Department (Grant/Award Number: 20JY042).