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Research Article

Enhancement of optical and piezoelectric properties of P(Vinylidene fluoride-hexafluoropropylene)/N,N-Dimethyl-4-nitro-4-Stilbenamine composites for optoelectronic applications

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Pages 2001-2015 | Received 06 Apr 2022, Accepted 02 Jun 2022, Published online: 28 Jun 2022
 

ABSTRACT

XRD, FTIR, optical morphology, and UV spectroscopy are used to investigate (PVDF-HFP)/DANS composites. Analysis of XRD and FTIR revealed that β-phase of (PVDF-HFP) is enhanced. UV analysis revealed that, indirect and direct optical bandgap values were decreased from 4.01 to 1.32 eV and from 5.41 to 3.68 eV of pure and dye doped composite samples. Linear and nonlinear optical parameters values are calculated. The piezoelectric properties of (PVDF-HFP)/DANS composite samples have been investigated and the high piezoelectric coefficient value of composite samples (d33 ≈ 44 PC/N) makes us consider these composites as one of the most promising piezoelectric materials.

Disclosure statement

No potential conflict of interest was reported by the author(s).

Additional information

Notes on contributors

A. Habib

A. Habib got PhD degree in 2017 from Mansoura University in cooperation with the Institute of Microelectronics Technology (TIM), University of Basque country, Spain. He is working now as assistant professor of experimental physics (Polymer Physics) at Physics Dept., Faculty of Science, Mansoura University, Mansoura, Egypt. Currently, his research interests focus on studying the phenomenon of dielectric relaxation spectroscopy, optical, electrical properties, piezoelectricity of polymers and their nanocomposites and silicon solar cell.

M. M. Metwally

M. M. Metwally got PhD degree in 2021 from Mansoura University with a six months PhD training at the Max Planck Partner Group on Colloidal Methods for Multifunctional Materials (CM3-Lab), Valencia University, Valencia, Spain. She is working now as assistant professor of Organic Polymer Chemistry at Chemistry Dept., Faculty of Science, Mansoura University, Mansoura, Egypt. Currently, her research interests focus on studying preparation of polymeric nanomaterials by miniemulsion, nanocomposites and complexes for water treatment, drug delivery, antimicrobial, catalysis, coating, peizoelectic and other biological applications.

T. Fahmy

T. Fahmy got PhD degree in 1996 from Mansoura University in cooperation with the Max Planck Institute (Stuttgart) in Germany. He is working now a professor of experimental physics (Polymer Physics) at Physics Dept., Faculty of Science, Mansoura University, Mansoura, Egypt. Currently, his research interests focus on studying the phenomenon of dielectric relaxation spectroscopy, optical, electrical properties, piezoelectricity and antibacterial activity of polymers and their nanocomposites.

A. Sarhan

A. Sarhan got PhD degree in 2013 from Mansoura University Physics department, Faculty of Science, Egypt. She is working now Associated Professor of Experimental Physics. Currently, her research interests focus on studying the phenomenon of relaxation, optical, electrical properties, radiology and antibacterial activity of polymers and their nanocomposites.

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