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Sensors

The Application of Microelectrodes for the Measurements of Trace Metals in Water

, &
Pages 2281-2300 | Received 16 Jun 2005, Accepted 21 Jul 2005, Published online: 02 Feb 2007

References

  • Abdelsalam , M. E. , Denuault , G. and Daniele , S. 2002 . Calibrationless determination of cadmium, lead and copper in rain samples by stripping voltammetry at mercury microelectrodes effect of natural convection on the deposition step . Anal. Chim. Acta. , 452 : 65 – 75 .
  • Achterberg , E. P. and Braungardt , C. 1999 . Stripping voltammetry for the determination of trace metals speciation and in‐situ measurements of trace metal distributions in marine waters . Anal. Chim. Acta. , 400 : 381 – 397 .
  • Allen , L. A. , Laech , J. J. and Houk , R. S. 1997 . Spatial location of the space charge effect in individual ion clouds using monodisperse dried microparticulate injection with a twin spectrometer . Anal. Chem. , 69 : 2384 – 2391 .
  • Alloway , B. J. 1996 . Schadstoff in der Umwelt Heidelberg : Spektrum Akademischer .
  • Amatore , C. A. and Fosset , B. 1992 . Space variables well fitted the study of steady‐state and near steady‐state diffusion at microdisk . J. Electroanal. Chem. , 328 : 21 – 32 .
  • Anderson , J. L. and Bowden , E. F. 1996 . Dynamic electrochemistry: methodology and application . Anal. Chem. , 68 : 379R – 444R .
  • Andrews , M. K. and Harris , P. D. 1998 . Fabrication and sensing applications of microelectrodes on silicon substrates . Electroanal. , 10 : 1112 – 1118 .
  • Aoki , K. 1993 . Theory of ultramicroelectrodes . Electroanal. , 5 : 627 – 639 .
  • Bartlett , P. N. and Taylor , S. L. 1998 . An accurate microdisc simulation model for recessed microdisc electrodes . J. Electroanal. Chem. , 453 : 49 – 60 .
  • Belmont , C. , Tercier , M. L. , Buffle , J. , Fiaccabrino , C. C. and Koudelka‐Hep , M. 1996 . Mercury‐plated iridium‐based microelectrode arrays for trace metals detection by voltammetry: optimum conditions and reliability . Anal. Chim. Acta. , 329 : 203 – 214 .
  • Belmont‐Hebert , C. , Tercier , M. L. , Buffle , J. , Fiaccabrino , G. C. , Rooij , N. F. and Koudelka‐Hep , M. 1998 . Gel‐integrated microelectrode arrays for direct voltammetric measurements of heavy metals in natural waters and other complex media . Anal. Chem. , 70 : 2949 – 2956 .
  • Beriet , C. , Ferrigno , R. and Girault , H. H. 2000 . Simulation of the chronoamperometric response of a regular array of micro‐disc electrodes . J. Electroanal. Chem. , 486 : 56 – 64 .
  • Bond , A. M. , Luscombe , D. , Oldham , K. B. and Zoski , C. G. 1988 . A comparison of the chronoamperometric response at inlaid and recessed disc microelectrodes . J. Electroanal. Chem. , 249 : 1 – 14 .
  • Bond , M. A. 1994 . Past, present and future contribution of microelectrodes to analytical studies employing voltammetric detection, a review . Analyst , 119 : R1 – R20 .
  • Brainina , K. Z. , Malakhova , N. A. and Stojko , N. Y. 2000 . Stripping voltammetry in environmental and food analysis . Fresenius J. Anal. Chem. , 368 : 307 – 325 .
  • Brenner , I. B. and Taylor , H. E. 1992 . A critical review of inductively coupled plasma‐mass spectrometry for geoanalysis, geochemistry, and hydrology. Part I: analytical performance . Criti. Rev. Anal. Chem. , 23 : 355 – 367 .
  • Brett , C. M.A. 1999 . Electroanalytical techniques for the future: the challenges of miniaturization and of real‐time measurements . Electroanal. , 11 : 1013 – 1016 .
  • Brett , C. M.A. , Garcia , M. B.Q. and Lima , J. L.F.C. 1996 . On the suppression of Zinc‐Copper interactions in square wave anodic stripping voltammetry in flowing solution by addition of gallium ions . Anal. Chim. Acta. , 339 : 167 – 172 .
  • Brett , C. M.A. , Lima , J. F.C. and Garcia , B. Q. 1994 . Square‐wave anodic stripping voltammetry in stationary and flowing solution: a comparative study . Analyst , 119 : 1229 – 1233 .
  • Buffle , J. and Horvai , H. 2000 . Situ Monitoring of Aquatic Systems—Chemical Analysis and Speciation Chichester : John Wiley & Sons .
  • Buffle , J. , Tercier , M. L. , Parthasarathy , N. and Wilkinson , K. J. 1997a . Analytical techniques for the in situ measurement and speciation of trace compounds in natural waters . Chimia , 51 : 690 – 693 .
  • Buffle , J. , Wilkinson , K. J. , Tercier , M.‐L. and Parthasarathy , N. 1997b . In situ monitoring and speciation of trace metals in natural waters . Annali di Chimica. , 87 : 67 – 83 .
  • Cai , X. , Glidle , A. and Cooper , J. M. 2000 . Miniaturized electroanalytical sensor systems in micromachined structures . Electroanal. , 12 : 631 – 639 .
  • Cammann , K. , Lemke , U. , Rohen , J. , Wilken , H. and Winter , B. 1991 . Chemo‐und biosensoren‐grundlagen und anwendungen . Angew. Chem. , 103 : 519 – 541 .
  • Cassidy , J. , Ghoroghchian , J. , Sarfarazi , F. , Smith , J. J. and Pons , S. 1986 . Simulation of edge effects in electroanalytical experiments by orthogonal collocation‐vi. Cyclic voltammetry at ultramicroelectrode ensembles . Electrochim. Acta. , 31 : 629 – 636 .
  • Caudill , W. L. , Howell , J. O. and Wightman , R. M. 1982a . Flow rate independent amperometric cell . Anal. Chem. , 54 : 2532 – 2535 .
  • Caudill , W. L. , Howell , J. O. and Wightman , R. M. 1982b . Flow rate independent amperometric cell . Anal. Chem. , 54 : 2532 – 2535 .
  • Christie , J. H. , Turner , J. A. and Osteryoung , R. A. 1977 . Square wave voltammetry at the dropping mercury electrode: theory . Anal. Chem. , 49 : 1899 – 1903 .
  • Ciszkowska , M. and Osteryoung , J. G. 1995 . Voltammetry of metals at mercury film microelectrodes in the absence and the presence of varying concentrations of supporting electrolyte . Anal. Chem. , 67 : 1125 – 1131 .
  • Daniel , S. , Baldo , M. A. , Ugo , P. and Mazzocchin , A. 1989 . Determination of heavy metals in real samples by anodic stripping voltammetry with mercury microelectrodes, Part 2: Application to rain and seawaters . Anal. Chim. Acta. , 219 : 19 – 26 .
  • Daniel , S. , Baldo , M. A. , Ugo , P. and Mazzochin , G. 1989 . Determination of heavy metals in real samples by anodic stripping voltammetry with mercury microelectrodes, Part 1: Application to wine . Anal. Chim. Acta. , 319 : 9 – 18 .
  • Daniele , S. , Baldo , M. A. and Bragato , C. 2002 . In situ monitoring of electroactive species by using voltammetry at microelectrodes . J. Braz. Chem. Soc. , 13 : 425 – 432 .
  • Daniele , S. , Bragato , C. , Baldo , M. A. , Wang , J. and Lu , J. 2000 . The use of a remote stripping sensor for the determination of copper and mercury in the Lagoon of Venice . Analyst , 125 : 731 – 735 .
  • Datta , M. and Landolt , D. 2000 . Fundamental aspects and applications of electrochemical microfabrication . Electrochim. Acta. , 45 : 2535 – 2558 .
  • Deutscher , R. L. and Fletcher , S. 1988 . Nucleation on active sites. 4. Invention of an electronic method of counting the number of crystals as a function of time and the discovery of nucleation rate dispersion . J. Electroanal. Chem. , 239 : 17 – 54 .
  • Emons , H. , Baade , A. and Schöning , M. J. 2000 . Voltammetric determination of heavy metals in microvolumes of rainwater . Electroanal. , 12 : 1171 – 1175 .
  • Feeney , R. , Herdan , J. , Nolan , M. A. , Tan , S. H. , Tarasov , V. V. and Kounaves , S. P. 1998 . Analytical characterization of microlithographically fabricated iridium‐based ultramicroelectrode arrays . Electroanalysis , 10 : 89 – 93 .
  • Feeney , R. and Kounaves , S. P. 2000 . On‐site analysis of arsenic in groundwater using a microfabricated gold ultramicroelectrode array . Anal. Chem. , 72 : 2222 – 2228 .
  • Feeney , R. and Kounaves , S. P. 2002 . Voltammetric measurement of arsenic in natural waters . Talanta , 58 : 23 – 31 .
  • Ferrigno , R. , Brevet , P. F. and Girault , H. H. 1997 . Finite element simulation of the chronoamperometric response of recessed and protruding microdisc electrodes . Electrochim. Acta. , 42 : 1895 – 1903 .
  • Fiaccabrino , G. C. and Koudelka‐Hep , M. 1998 . Thin‐film microfabrication of electrochemical transducers . Electroanal. , 10 ( 4 ) : 217 – 222 .
  • Fiedler , H. J. and Roesler , H. J. 1993 . Spurenelemente in der Umwelt Jena : Gustav Fischer Verlag .
  • Fleischmann , S. , Pons , Rolison , D. and Schmidt , P. P. 1987 . Ultramicroelectrodes Morganton, NC : Datatech Science .
  • Fletcher , S. 1994 . Microelectrodes . Chemistry in Australia. February , : 80 – 82 .
  • Fletcher , S. and Horne , M. D. 1999 . Random assemblies of microelectrode (RAM electrodes) for electrochemical studies . Electrochem. Comm. , 1 : 502 – 512 .
  • Florence , T. M. 1986 . Electrochemical approaches to trace element speciation in waters a review . Analyst , 111 : 489 – 503 .
  • Forster , R. J. 1994 . Microelectrodes: new dimensions in electrochemistry . Chemical Society Reviews , : 289 – 297 .
  • Gao , X. , Lee , J. and White , H. S. 1995 . Natural convection at microelectrodes . Anal. Chem. , 67 : 1541 – 1545 .
  • Gao , Y. , Oshita , K. , Lee , K. H. , Oshima , M. and Motomizu , S. 2002 . Development of column‐pretreatment chelating resins for matrix elimination/muti‐element determination by inductively coupled plasma‐mass spectrometry . Analyst , 127 : 1713 – 1719 .
  • Grasshoff , K. , Kremling , K. and Ehrhardt , M. 1999 . Methods of Seawater Analysis , 3rd ed. 253 – 364 . Weinheim : Wiley‐Vch .
  • Guenat , O. T. , Fiaccabrino , G. C. , Morf , W. E. , Koudelka‐Hep , M. and Rooij , N. F. 1999 . Microfabricated chemical analysis systems for environmental applications . Chimia , 53 : 87 – 90 .
  • Gueshi , T. , Tokuda , K. and Matsuda , H. 1978 . Voltemmetry at partially covered electrodes. 1. Chronopotentiometry and chronoamperometry at model electrodes . J. Electroanal. Chem. , 89 : 247 – 260 .
  • Guminski , C. and Galus , Z. 1986 . “ Solubility Data Series—Metals in Mercury ” . Edited by: Hirayama , C. , Guminski , C. and Galus , Z. Oxford, , UK : Pergamon Press .
  • Hansen , P. 1991 . “ Heavy metal determination using potentiometric stripping analysis ” . In Am. LabApril 52 – 58 .
  • Hart , J. P. and Wring , S. A. 1997 . Recent developments in the design and application of screen‐printed electrochemical sensors for biomedical, environmental and industrial analyses . Trends in Anal. Chem. , 16 : 89 – 103 .
  • Haswell , J. S. 1997 . Development and operating characteristics of micro flow injection analysis systems based on electroosmotic flow . Analyst , 122 : 1R – 10R .
  • Heinze , J. 1993 . Ultramicroelectrodes in electrochemistry . Angew. Chem. Int. Ed. Engl. , 32 : 1268 – 1288 .
  • Herdan , J. , Feeney , R. and Kounaves , S. P. 1998 . Field evaluation of an electrochemical probe for in situ screening of heavy metals in groundwater . Environ. Sci. Technol. , 32 : 131 – 136 .
  • Hill , S. J. 1997 . Speciation of trace metals in the environment . Chem. Soc. Rev. , 26 : 291 – 298 .
  • Howell , J. O. and Wightman , M. 1984 . Ultrafast voltammetry and voltammetry in highly resistive solutions with microvoltammetric electrodes . Anal. Chem. , 56 : 524 – 529 .
  • Howell , K. A. , Achterberg , E. P. , Braungardt , C. B. , Tappin , A. D. , Worsfold , P. J. and Turner , D. R. 2003 . Voltemmetric in situ measurements of trace metals in coastal waters . Trend Anal. Chem. , 22 : 828 – 835 .
  • Hoyer , B. , Florence , T. M. and Bailey , G. E. 1987 . Application of polymer‐coated glassy carbon electrodes in anodic stripping voltammetry . Anal. Chem. , 59 : 1608 – 1614 .
  • Jagner , D. and Sweden , G. 1983 . Computerised flow potentiometric stripping analysis . Trends Anal. Chem. , 2 : 53 – 56 .
  • Jagner , D. , Sahlin , E. and Axelsson , B. 1993 . Method for the determination of copper and lead (II) in tap water using a portable potentiometric stripping analyser . Anal. Chim. Acta. , 278 : 237 – 242 .
  • Jagner , D. , Sahlin , E. and Renman , L. 1996 . Apparent formation of an oxidant by electrochemical reduction in the mercury (O, I, II) chloride system . Anal. Chem. , 68 : 1616 – 1622 .
  • Janata , J. , Josowicz , M. , Vanysek , P. and Devaney , D. M. 1998 . Chemical sensors . Anal. Chem. , 70 : 179R – 208R .
  • Kalvoda , R. 1994 . Review of adsorptive stripping voltammetry—assessment and prospects . Fresenius J. Anal. Chem. , 349 : 565 – 570 .
  • Khakani , M. A.E. , Chaker , M. and Drogoff , B. L. 1998 . Iridium thin films deposited by radio‐frequency magnetron sputtering . J. Vac. Sci. Technol. A , 16 : 885 – 888 .
  • Kissinger , P. T. and Heineman , W. R. 1984 . Laboratory Techniques in Electroanalytical Chemistry New York : Marcel Dekker .
  • Kounaves , S. P. , Deng , W. and Hallock , P. R. 1994 . Iridium‐based ultramicroelectrode array fabricated by microlithography . Anal. Chem. , 66 : 418 – 423 .
  • Kounaves , S. P. and Buffle , J. 1987 . An iridium‐based mercury‐film electrode . J. Electronal. Chem. , 216 : 53 – 69 .
  • Kounaves , S. P. and Buffle , J. 1986 . Deposition and stripping properties of mercury on iridium electrodes . J. Electrochem. Soc. , 133 : 2495 – 2497 .
  • Kounaves , S. P. and Deng , W. 1993 . Analytical utility of the iridium‐based mercury ultramicroelectrode with square‐wave anodic stripping voltammetry . Anal. Chem. , 65 : 375 – 379 .
  • Lafleur , R. D. , Myland , J. C. and Oldbam , K. B. 1990 . Analytical microelectrode voltammetry with minimal instrumentation . Electroanal. , 2 : 223 – 228 .
  • Lee , H. J. , Beriet , C. , Ferrigno , R. and Girault , H. H. 2001 . Cyclic voltmmetry at a regular microdisc electrode array . J. Electroanal. Chem. , 502 : 138 – 145 .
  • Lindemann , J. and Landsberg , R. 1971 . Potentiostatic start measurements on partially blocked model electrodes . J. Electroanal. Chem. , 30 : 79
  • Lopez‐Avila , V. and Hill , H. H. 1997 . Field analytical chemistry . Anal. Chem. , 69 : 289R – 305R .
  • Mart , L. 1982 . Minimization of accuracy risks in voltammetric ultratrace determination of heavy metals in natural waters . Talenta , 29 : 1035 – 1040 .
  • Millero , F. and Pierrot , D. “ Speciation of metals in natural waters. Chemistry of marine water and sediments ” . In International School on Marine Chemistry , 3rd ed 193 – 220 . Palermo, , Italy Meeting Data Sept 2000
  • Montenegro , M. I. , Queiros , M. A. and Daschbach , J. L. 1991 . “ Microelectrodes: theory and applications. NATO ASI series ” . 3 – 16 . Dordrecht : Kluwer Academic Publishers .
  • Moore , J. W. and Ramamoorthy , S. 1984 . Heavy Metals in Natural Waters—Applied Monitoring and Impact Assessment New York : Springer‐Verlag .
  • Morf , W. E. 1996 . Theoretical treatment of the amperometric current response of multiple microelectrode arrays . Anal. Chim. Acta. , 330 : 139 – 149 .
  • Morf , W. E. 1997 . Theoretical treatment of the current vs. time response of microelectrode arrays to changes of potential, concentration, or flow . Anal. Chim. Acta. , 341 : 121 – 127 .
  • Morf , W. E. and Rooij , N. F.D. 1997 . Performance of amperometric sensors based on multiple microelectrode arrays . Sensors and Actuators B , 44 : 538 – 541 .
  • Nascimento , V. B. , Augelli , M. A. , Pedrotti , J. J. , Gutz , I. G.R. and Angnes , L. 1997 . Arrays of microelectodes made from split integrated circuit chips . Electroanal , 9 ( 4 ) : 335 – 339 .
  • Nolan , M. A. and Kounaves , S. P. 1998a . Effects of mercury electrodeposition on the surface degradation of microlithographically fabricated iridium ultramicroelectrodes . J. Electroanal. Chem. , 453 : 39 – 48 .
  • Nolan , M. A. and Kounaves , S. P. 1998b . Failure analysis of microfabricated iridium ultramicroelectrodes in chloride media . Sensor Actuator B , 50 : 117 – 124 .
  • Nolan , M. A. and Kounaves , S. P. 1999a . Effects of chloride ion concentration on mercury (I) chloride formation during ex situ and in situ mercury deposition with selected electrode substrates and electrodes . Anal. Chem. , 71 : 1176 – 1182 .
  • Nolan , M. A. and Kounaves , S. P. 1999b . Microfabricated array of iridium microdisks as a substrate for direct determination of Cu2+ or Hg2+ using square‐wave anodic stripping voltammetry . Anal. Chem. , 71 : 3567 – 3573 .
  • Nolan , M. A. and Kounaves , S. P. 2000 . The source of the anomalous cathodic peak during ASV with in situ mercury film formation in chloride solutions . Electroanal. , 12 : 96 – 99 .
  • Nurnberg , H. W. 1984 . Trace analytical procedures with modern voltammetric determination methods for the investigation and monitoring of ecotoxic heavy‐metals in natural waters and atmospheric precipitates . Sci. Tot. Environ. , 37 : 9 – 34 .
  • Ostapczuk , P. 1983 . Present potentials and limitations in the determination of trace elements by potentiometric stripping analysis . Anal. Chim. Acta. , 273 : 35 – 40 .
  • Osteryoung , J. G. and Osteryoung , R. A. 1985 . Square wave voltammetry . Anal. Chem. , : 101A – 110A .
  • Palchetti , I. , Cagnini , A. , Mascini , M. and Turner , A. P.F. 1999 . Characterization of screen‐printed electrodes for detection of heavy metals . Mikrochim Acta. , 131 : 65 – 73 .
  • Palchetti , I. , Marrazza , G. I. and Maschini , M. 2001 . New procedures to obtain electrochemical sensors for heavy metal determination . Anal. Lett. , 34 : 813 – 824 .
  • Pons , S. and Fleischmann , M. 1987 . The behavior of microelectrodes . Anal. Chem. , 59 : 1391 – 1399 .
  • Prodenziati , M. “ Thick film sensors ” . In Handbook of sensors and actuators Amsterdam : Elsevier .
  • Reay , R. J. , Flannery , A. F. , Storment , C. W. , Kounaves , S. P. and Kovacs , G. T.A. 1997 . Microfabricated electrochemical analysis system for heavy metal detection . Sensor. Actuator B , 34 : 450 – 455 .
  • Reller , H. , Kirowa‐Eisner , E. and Gileadi , E. 1982 . Ensembles of microelectrodes a digital simulation . J. Electroanal. Chem. , 138 : 65 – 77 .
  • Ryan , M. D. , Bowden , E. F. and Chambers , J. Q. 1994 . Dynamic electrochemistry: methodology and application . Anal. Chem. , 66 : 360R – 427R .
  • Samuel , B. and Kounaves , P. 1990a . Iridium based ultramicroelectrodes, development and use in electrochemical analysis . Platinum Metals Rev. , 34 : 131 – 134 .
  • Samuel , B. and Kounaves , P. 1990b . Iridium based ultramicroelectrodes, development and use in electrochemical analysis . Platinum Metals Rev. , 34 : 131 – 134 .
  • Sandison , M. E. , Anicet , N. , Glidle , A. and Cooper , J. M. 2002 . Optimization of the geometry and porosity of microelectrode arrays for sensor design . Anal. Chem. , 74 : 5717 – 5725 .
  • Scharifker , P. 1991 . “ Ensembles of microelectrodes ” . In Microelectrodes: Theory and Applications Edited by: Montenegro , M. I. , Queiros , M. A. and Daschbach , J. L. 228 – 240 . Dordrecht : Kluwer Academic Publishers . NATO ASI series
  • Scharifker , B. R. 1988 . Diffusion to ensembles of microelectrodes . J. Electroanal. Chem. , 240 : 61 – 76 .
  • Schultze , J. W. and Bressel , A. 2001 . Principles of electrochemical micro‐ and nano‐system technologies . Electrochimica Acta. , 47 : 3 – 21 .
  • Seddon , B. J. , Shao , Y. and and Girault , H. H. 1994 . Printed microelectrode array and amperometric sensor for environmental monitoring . Electrochim. Acta. , 39 : 2377 – 2386 .
  • Shoup , D. and Szabo , A. 1984 . Chronoamperometry at an ensemble of microdisk electrodes . J. Electroanal. Chem. , 160 : 19 – 26 .
  • Silva , P. R.M. , Khakani , M. A.E.L. , Chaker , M. , Champagne , G. Y. , Chevalet , J. , Gastonguay , L. , Lacasse , R. and Ladouceur , M. 1999 . Development of Hg‐electroplated‐iridium based microelectrode arrays for heavy metal traces analysis . Anal. Chim. Acta. , 385 : 249 – 255 .
  • Statham , P. J. 1985 . The determination of dissolved manganese and cadmium in sea water at low nmol 1–1 concentrations by chelation and extraction flowed by electrothermal atomic absorption spectrometry . Anal. Chim. Acta. , 169 : 149 – 159 .
  • Stojek , Z. 1991 . New possibilities in analytical chemistry connected with voltammetric applications of microelectrodes . Mikrochim. Acta. [Wien] , 11 : 353 – 361 .
  • Stulik , K. , Amatore , C. , Holub , K. , Mareceek and Kutner , W. 2000 . Microelectrodes. Definitions, characterization, and applications . Pure Appl. Chem. , 72 : 1483 – 1492 .
  • Stumm , W. and Morgan , J. J. 1996 . Aquatic Chemistry—Chemical Equilibria and Rates in Natural Waters , 3rd ed. New York : John Wiley & Sons .
  • Suzuki , H. 2000 . Advances in the microfabrication of electrochemical sensors . Electroanal. , 12 : 703 – 715 .
  • Swan , P. N. 1980 . University of Southampton . Dissertation
  • Taillefert , M. , Luther III , G. W. and Nuzzio , D. B. 2000 . The application of electrochemical tools for in situ measurements in aquatic systems . Electroanal. , 12 ( 6 ) : 401 – 412 .
  • Tallman , D. E. and Petersen , S. L. 1990 . Composite electrodes for electroanalysis: principles and applications . Electroanal. , 2 : 499 – 510 .
  • Tan , S. H. and Kounaves , S. P. 1998 . Determination of selenium (IV) at a microfabricated gold ultramicroelectrode array using square wave anodic stripping voltammetry . Electroanal. , 10 : 364 – 368 .
  • Teillefert , M. , Luther III , G. W. and Nuzzio , D. B. 2000 . The application of electrochemical tools for in situ measurements in aquatic systems . Electroanal. , 12 ( 6 ) : 401
  • Tercier , M. L. and Buffle , J. 1993 . In situ voltammetric measurements in natural waters: future prospects and challenges . Electroanal. , 5 : 187 – 200 .
  • Tercier , M. L. and Buffle , J. 1996 . Antifouling membrane‐covered voltammetric microsensor for in situ measurements in natural waters . Anal. Chem. , 68 : 3670 – 3678 .
  • Tercier , M. L. , Parthasarathy , N. and Buffle , J. 1995 . Reproducible, reliable and rugged Hg‐plated Ir‐based microelectrode for in situ measurements in natural waters . Electroanal. , 7 : 55 – 63 .
  • Tercier‐Waeber , M.‐L. and Buffle , J. 2000 . Submersible online oxygen removal system coupled to an in situ voltammetric probe for trace element monitoring in freshwater . Environ. Sci. Technol. , 34 : 4018 – 4024 .
  • Tercier‐Waeber , M. L. , Buffle , J. , Confalonieri , F. , Riccardi , G. , Sina , A. , Graziottin , F. , Fiaccabrino , G. C. and Koudelka‐Hep , M. K. 1999 . Submersible voltammetric probes for in situ real‐time trace element measurements in surface water, groundwater and sediment‐water interface . Meas. Sci. Technol. , 10 : 1202 – 1213 .
  • Tessier , A. and Turner , D. R. 1995 . Metal Speciation and Bioavailability in Aquatic Systems Chichester : John Wiley & Sons .
  • Vitre , R. R.D. , Tercier , M.‐L. and Buffle , J. 1991 . In situ voltammetric measurements in natural waters: the advantages of microelectrodes . Anal. Proc. , 28 : 74 – 75 .
  • Wang , J. 1996 . Laboratory Techniques in Electroanalytical Chemistry Edited by: Kissinger , P. T. and Heineman , W. R. 719 – 738 . New York : Marcel Dekker .
  • Wang , J. 2000 . Analytical Electrochemistry 75 New York : John Wiley & Sons .
  • Wang , J. 2000b . In situ electrochemical monitoring: from remote sensors to submersible microlaboratories . LRA , 12 : 178 – 182 .
  • Wang , J. , Adeniyi , W. K. and Kounaves , S. P. 1999 . Adsorptive stripping analysis of trace nickel at iridium‐based ultramicroelectrode arrays . Electroanal. , 12 : 44 – 47 .
  • Wang , J. , Brennsteiner , A. and Sylwester , A. P. 1990 . Composite electrodes based on carbonized poly (acrylonitrile) foams . Anal. Chem. , 62 : 1102 – 1104 .
  • Wang , J. , Foster , N. , Armalis , S. , Larson , D. , Zirino , A. and Olsen , K. 1995 . Remote stripping electrode for in situ monitoring of labile copper in the marine environment . Anal. Chim. Acta. , 310 : 223 – 231 .
  • Wang , J. , Lu , J. , Tian , B. and Yarnitzky , C. 1993 . Screen‐printed ultramicroelectrode arrays for on‐site stripping measurements of trace metals . Electroanal. Chem. , 361 : 77 – 83 .
  • Wang , J. , Tian , B. , Lu , J. , Wang , J. , Luo , D. and MacDonald , D. 1998a . Remote electrochemical sensor for monitoring trace mercury . Electroanal. , 10 : 399 – 402 .
  • Wang , J. , Tlan , B. , Wang , J. , Lu , J. , Olsen , C. , Yarnitzky , C. , Olsen , K. , Hammerstrom , D. and Bennett , W. 1999 . Stripping analysis into the 21st century: faster, smaller, cheaper, simpler and better . Anal. Chim. Acta. , 385 : 429 – 435 .
  • Weber , S. G. 1989 . Signal‐to‐noise ratio in microelectrode‐array‐based electrochemical detectors . Anal. Chem. , 61 : 295 – 302 .
  • Wechter , C. and Osteryoung , J. 1989 . Square wave and linear scan anodic stripping voltammetry at iridium‐based mercury film electrodes . Anal. Chem. , 61 : 2092 – 2097 .
  • Wehmeyer , K. R. , Deakin , M. R. and Wightman , M. 1985 . Eletroanalytical properties of band electrodes of submicrometer width . Anal. Chem. , 57 : 1913 – 1916 .
  • Weisshaar , D. E. and Tallman , D. E. 1983 . Chronoamperometric response at carbon‐based composite electrodes . Anal. Chem. , 55 : 1146 – 1151 .
  • Wightman , R. M. 1981a . Microvoltammetric electrodes . Anal. Chem. , 53 : 1125A – 1134A .
  • Wightman , R. M. 1988 . Voltammetry with microscopic electrodes in new domains . Science , 240 : 415 – 420 .
  • Wightman , R. M. 1988 . Voltammetry with microscopic electrodes in new domains . Science , 240 : 415 – 420 .
  • Wightman , R. M. and Wipf , D. O. 1989 . “ Voltammetry at ultramicroelectrodes ” . In Electroanalytical Chemistry Edited by: Bard , A. J. Vol. 15 , New York : Marcel Dekker .
  • Wojciechowski , M. and Balcerzak , J. 1990a . Square‐wave anodic stripping voltammetry of lead and cadmium at cylindrical graphite fiber microelectrodes with in situ plated mercury films . Anal. Chim. Acta. , 249 : 433 – 445 .
  • Wojciechowski , M. and Balcerzak , J. 1990b . Square‐wave anodic stripping voltammetry at glassy carbon‐based thin mercury film electrodes in solutions containing dissolved oxygen . Anal. Chem. , 62 : 1325 – 1331 .
  • Wollenberger , U. , Hintsche , R. and Scheller , F. 1995 . Biosensors for analytical microsystems . Microsyst. Technol , 1 : 75
  • Wong , D. K.Y. and Ewing , A. G. 1990 . Anodic stripping voltammetry at mercury films deposited on ultrasmall carbon‐ring electrodes . Anal. Chem. , 62 : 2697 – 2702 .
  • Wring , S. A. and Hart , J. P. 1992 . Chemically modified, screen‐printed carbon electrodes . Analyst , 117 : 1281 – 1286 .
  • Wu , H. P. 1993 . Fabrication and characterization of a new class of microelectrode arrays exhibiting steady‐state current behavior . Anal. Chem. , 65 : 1643 – 1646 .
  • Xie , X. , Berner , Z. , Albers , J. and Stüben , D. 2005 . Electrochemical behavior and analytical performance of a novel iridium based ultramicroelectrode array (UMEA) sensor . Microchem. Acta. , 150 : 137 – 145 .
  • Xie , X. , Stüben , D. , Berner , Z. , Albers , J. , Hintsche , R. and Jantzen , E. 2004 . Development of an ultramicroelectrode arrays (UMEAs) sensor for trace heavy metal measurement in water . Sensor Actuator B , 97 : 168 – 173 .
  • Yarnitzky , C. , Wang , J. and Tian , B. 2000 . Hand‐held lead analyzer . Talanta , 51 : 333 – 338 .
  • Zuhri , A. and Voelter , W. 1998 . Applications of adsorptive stripping voltammetry for the trace analysis of metals, pharmaceuticals and biomolecules . Fresenius J. Anal. Chem. , 360 : 1 – 9 .

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