371
Views
11
CrossRef citations to date
0
Altmetric
POTENTIOMETRY

A Simple Potentiometric Titration Method to Determine Concentration of Ferrate(VI) in Strong Alkaline Solutions

, , , , , & show all
Pages 1333-1340 | Received 28 Feb 2010, Accepted 27 Apr 2010, Published online: 14 Jun 2011

REFERENCES

  • Carr , J. D. , P. B. Kelter , A. Tabatabai , D. Spichal , J. Erickson , and C. W. McLaughin . 1985 . Properties of ferrate(VI) in aqueous solution: An alternate oxidant in wastewater treatment . In Proceedings of Conference on Water Chlorination Chemical Environmental Impact Health Effects . New York : R. L. Jolley . Eds.
  • Carr , J. 2008 . Kinetics and product identification of oxidation by ferrate(VI) of water and aqueous nitrogen containing solutes . In ACS Symposium Series Titled “Ferrates: Synthesis, Properties, and Applications in Water and Wastewater Treatment , ed. V. K. Sharma , Vol. 985 . Oxford University Press . Washington , DC .
  • Delaude , L. , and P. Laszlo . 1996 . A novel oxidizing reagent based on potassium ferrate(VI) . J. Org. Chem. 61 : 6360 – 6370 .
  • Hoppe , M. L. , E. O. Schlemper , and R. K. Murmann . 1983 . Structure of dipotassium ferrate(VI) . Acta. Cryst. B 38 : 2237 – 2239 .
  • Jain , A. , V. K. Sharma , and M. S. Mbuya . 2009 . Removal of arsenite by Fe(VI), Fe(VI)/Fe(III), and Fe(VI)/Al(III) salts: Effect of pH and anions . J. Hazardous Mater. 169 : 339 – 344 .
  • Jiang , J. Q. , and B. Lloyd . 2002 . Progress in the development and use of ferrate(VI) salt as an oxidant and coagulant for water and wastewater treatment . Water Res. 36 : 1397 – 1408 .
  • Jiang , J. Q. 2007 . Research progress in the use of ferrate(VI) for the environmental remediation . J. Hazard. Mater. 146 : 617 – 623 .
  • He , C. , X.-Z. Li , V. K. Sharma , and S. Y. Li . 2009 . Elimination of sludge odor by oxidizing sulfur-containing compounds with ferrate(VI) . Environ. Sci. Technol. 43 : 5890 – 5895 .
  • Lee , Y. , J. Yoon , and U. von Gunten . 2005 . Spectrophotometric determination of ferrate (Fe(VI)) in water by ABTS . Water Res. 39 : 1946 – 1953 .
  • Lee , Y. , S. G. Zimmermann , A. T. Kieu , and U. von Gunten . 2009 . Ferrate (Fe(VI)) application for municipal wastewater treatment: A novel process for simultaneous micropollutant oxidation and phosphate removal . Env. Sci. Technol. 43 : 3831 – 3838 .
  • Li , C. ; X. Z. Li , N. Graham , and N. Y. Gao . 2008 . The aqueous degradation of bisphenol A and steroid estrogens by ferrate . Water Res. 42 : 109 – 120 .
  • Licht , S. L. , B. Wang , and S. Ghosh 1999 . Energetic iron(VI) chemistry: The super-iron battery . Science 285 : 1039 – 1042 .
  • Machala , L. , R. Zboril , V. K. Sharma , J. Philip , D. Jancik , and Z. Homonnay . 2009 . Transformation of solid potassium ferrate(VI) (K2FeO4): Mechanism and kinetic effect of air humidity . Eur. J. Inorg. Chem. 2009 : 1060 – 1067 .
  • Mácová , Z. , K. Bouzek , J. Híveš , V. K. Sharma , R. J. Terryn , and J. C. Baum . 2009 . Research progress in electrochemical synthesis of ferrate(VI) . Electrochim Acta 54 : 2673 – 2683 .
  • Mácová , Z. , K. Bouzek , and V. K. Sharma . Forthcoming. The influence of electrolyte composition on electrochemical ferrate(VI) synthesis. Part I: Anodic dissolution kinetics of pure iron . J. Appl. Electrochem. 40 ( 5 ): 1019 – 1028 .
  • Mohammad , A. , Jiang , J.-Q. , and Stanford , C. 2009. On-line production of ferrate with an electrochemical method and its potential application for wastewater treatment – a review. J. Environ. Manag. 90: 1350–1356.
  • Noorhasan , N. N. , V. K. Sharma , and J. C. Baum . 2008 . Fluorescence technique to determine low concentrations of ferrate(VI) in Water . In ACS Symposium Series Titled “Ferrates: Synthesis, Properties, and Applications in Water and Wastewater Treatment . ed. V. K. Sharma , Vol. 985 .
  • Richardson , S. D. 2009 . Water analysis: Emerging contaminants and current issues . Anal. Chem. 81 : 4645 – 4677 .
  • Rush , J. D. , and B. H. J. Bielski . 1986 . Pulse radiolysis studies of alkaline Fe(III) and Fe(VI) solutions. Observation of transient iron complexes with intermediates oxidation states . J. Am. Chem. Soc. 108 : 523 – 525 .
  • Schreyer , J. M. , G. W. Thompson , and L. T. Ockerman . 1950a . Oxidation of chromium(III) with potassium ferrate(VI) . J. Am. Chem. Soc. 22 : 1426 – 1427 .
  • Schreyer , J. M. , G. W. Thompson , and L. T. Ockerman . 1950b . Ferrate oxidimetry. Oxidation of arsenite with potassium ferrate(VI) . Am. Chem. Soc. 22 : 691 – 692 .
  • Sharma , V. K. 2002 . Potassium ferrate(VI): An environmentally friendly oxidant . Adv. Environ. Chem. 6 : 143 – 157 .
  • Sharma , V. K. 2004 . Use of iron(VI) and Iron(V) in water and wastewater treatment . Water Sci. Technol. 49 : 69 – 74 .
  • Sharma , V. K. 2008 . Oxidative transformations of environmental pharmaceuticals by Cl2, ClO2, O3, and Fe(VI): Kinetics assessment . Chemosphere 73 : 203 – 208 .
  • Sharma , V. K. 2010 . Oxidation of nitrogen-containing pollutants by innovative ferrate technology: A review . J. Environ. Sci. Health A 45 : 645 – 667 .
  • Sharma , V. K. , G. Anquandah , R. A. Yngard , H. Kim , J. Fekete , K. Bouzek , A. K. Ray , and D. Golovko . 2009 . Nonylphenol, octylphenol, and bisphenol-A in the aquatic environment: A review on occurrence, fate, and treatment . J. Environ. Sci. Health. Part A 44 : 423 – 442 .
  • Sharma , V. K. , J. T. Bloom , and V. N. Joshi . 1998 . Oxidation of ammonia by ferrate(VI) . J. Environ. Sci. Health. A 33 : 635 – 650 .
  • Sharma , V. K. , P. K. Dutta , and A. K. Ray . 2007 . Review of kinetics of chemical and photocatalytic oxidation of As(III) as influenced by pH . J. Environ. Sci. Health A 42 : 997 – 1004 .
  • Sharma , V. K. , F. Kazama , H. Jiangyong , and A. K. Ray . 2005 . Iron(VI) and iron(V): Environmentally-friendly oxidants and disinfectants . J. Water Health 3 : 45 – 58 .
  • Yngard , R. , V. K. Sharma , J. Philips , and R. Zboril . 2008 . Ferrate(VI) oxidation of weak-acid dissociable cyanides . Environ. Sci. Technol. 42 : 3005 – 3010 .

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.