Hierarchical Reduced Models for Catalytic Combustion: H₂/Air Mixtures Near Platinum Surfaces

References

• Bui , P. A. , Vlachos , D. G. and Westmoreland , P. R. ( 1995 ) Inhibition of homogeneous ignition by a catalytic surface. Eastern States Section, Chemical and Physical Processes in Combustion , Pittsburgh , The Combustion Institute, p. 147 ,
   Google Scholar
• Bui , P. A. , Vlachos , D. G. and Westmoreland , P. R. ( 1996 ) Homogeneous ignition of hydrogen/air mixtures over platinum. Twenty-Sixth Symposium (International) on Combustion , Pittsburgh , The Combustion Institute, p. 1763 .
   Google Scholar
• Bui , P. A. , Vlachos , D. G. and Westmoreland , P. R. ( 1997 ) Modeling ignition of catalytic reactors with detailed surface kinetics and transport : Combustion of H2/air mixtures over platinum surfaces. Ind. Eng. Chem. Res. , 36 , 2558 .
   Web of Science ®Google Scholar
• Buser , S. , Benz , P. and Schlegel , A. ( 1993 ) Measurements of OH by LIF and temperatures by holographic interferometry in catalytically stabilized combustion of hydrogen: comparison of measurements and numerical simulation. Ber. Busenges. Phys. Chem. , 97 i:( 12 ), 1719 .
   Web of Science ®Google Scholar
• Cho , P. and Law , C. K. ( 1986 ) Catalytic ignition of fuel/oxygen/nitrogen mixtures over platinum. Combust. Flame , 66 , 159 .
   Google Scholar
• Cussler , E. L. ( 1984) Diffusion: Mass transfer in fluid systems , Cambridge University Press.
   Google Scholar
• Deutschmann , O. , Schmidt , R. and Behrendt , F. ( 1995 ) Interaction of transport and chemical kinetics in catalytic combustion of H2/O2 mixtures on Pt. Eighth International Symposium on Transport Phenomena in Combustion , San Francisco, CA , p. 49 .
   Google Scholar
• Enomoto , K. , Furuhama . S. and Kobayashi , Y. ( 1981 ) Ignitability of hydrogen-air mixture by hot surfaces and hot gases. Adv. Hydrogen Energy , 2 , p. 1149 .
   Google Scholar
• Fassihi , M. , Zhdanov , V. P. , Rinnemo , M. , Keck , K.E. and Kasemo , B. ( 1993 ) A theoretical and experimental study of catalytic ignition in the hydrogen-oxygen reaction on platinum. J. Catal. , 141 , 438 .
   Web of Science ®Google Scholar
• Ikeda . H. , Sato , J. and Williams , F. A. ( 1995 ) Surface kinetics for catalytic combustion of hydrogen-air mixtures on platinum at atmospheric pressure in stagnation flows. Surf. Science , 326 , 11 .
   Web of Science ®Google Scholar
• Kalamatianos , S. , Park , Y. K. and Vlachos , D. G. ( 1997 ) Two-parameter continuation algorithms for computing ignitions and extinctions: Sensitivity analysis, parametric dependences, mechanism reduction, and stability criteria. Combust. Flame , (in press).
   Google Scholar
• Kee , R. J. , Dixon-Lewis , C. , Warnatz , J. , Coltrin , M. E. and Miller , J. A. ( 1990 ) A FORTRAN computer code package for the evaluation of gas-phase multicomponent transport properties , Sandia National Laboratories Report, SAND86--8246.
   Google Scholar
• Lam , S. H. and Goussis , D. A. ( 1988 ) Understanding complex chemical kinetics with computational singular perturbation. Twenty-Second Symposium (International) on Combustion , The Combustion Institute, Pittsburgh , p. 931 .
   Google Scholar
• Leal , L. G. ( 1992 ) Laminar flow and convective transport processes , Butterworth-Heinemann.
   Google Scholar
• Maas , U. and Pope , S. B. ( 1992 ) Simplifying chemical kinetics: Intrinsic low-dimensional manifolds in composition space. Combust. Flame , 88 , 239 .
   Web of Science ®Google Scholar
• Markatou , P. , Pfefferle , L. D. and Smooke , M. D. ( 1991 ) The influence of surface chemistry on the development of minor species profiles in the premixed boundary layer combustion of an H2/air mixture. Combust. Sci. Technol. , 79 , 247 .
   Web of Science ®Google Scholar
• Miller , J. A. and Bowman , C. T. ( 1989 ) Mechanism and modeling of nitrogen chemistry in combustion. Prog. Energy Combust. Sci. , 15 , 287 .
   Web of Science ®Google Scholar
• Peters , N. ( 1988 ) Systematic reduction of flame kinetics: Principles and details. Dynamics of reactive systems. Part I: Flames. , A. L. Kuhl et al. Monmouth Junction, Progress in Astronautics and Aeronautics: 67 .
   Google Scholar
• Schefer , R. W. ( 1982 ) Catalyzed combustion of H2/air mixtures in a flat plate boundary layer: II Numerical model. Combust. Flame , 45 , 171 .
   Web of Science ®Google Scholar
• Smooke , M. D. ( 1991 ) (ed.), Reduced kinetic mechanisms and asymptotic approximations for methane-air flames , Springer-Verlag.
   Google Scholar
• Song , X. , Williams , W. R. , Schmidt , L. D. and Aris , R. ( 1990 ) Ignition and extinction of homogeneous-heterogeneous combustion: CH4 and C3H8 oxidation on Pt. Twenty-Third Symposium (International) on Combustion , The Combustion Institute, Pittsburgh , p. 1129 .
   Google Scholar
• Song , X. , Williams , W. R. , Schmidt , L. D. and Aris , R. ( 1991 ) Bifurcation behavior in homogeneous-heterogeneous combustion: II. Computations for stagnation-point flow. Combust. Flame , 84 , 292 .
   Web of Science ®Google Scholar
• Vajda , S. , Valko , P. and Turanyi , T. ( 1985 ) Principal component analysis of kinetic models. International Journal of Chemical Kinetics , 17 , 55 .
   Web of Science ®Google Scholar
• Vlachos , D. G. ( 1995 ) The interplay of transport, kinetics, and thermal interactions in the stability of premixed hydrogen/air flames near surfaces. Combust. Flame , 103 ( 1 – 2 ), 59 .
   Google Scholar
• Vlachos , D. G. ( 1996 ) Reduction of detailed kinetic mechanisms for ignition and extinction of premixed hydrogen/air flames. Chem. Engng Sci. , 51 , 3979 .
   Web of Science ®Google Scholar
• Vlachos , D, G. and Bui , P.A. ( 1996 ) Catalytic ignition and extinction of hydrogen: Comparison of simulations and experiments. Surf. Science , 364 , L625 .
   Web of Science ®Google Scholar
• Vlachos , D. G. , Schmidt , L. D. and Aris , R. ( 1993 ) Ignition and extinction of flames near surfaces: Combustion of H2 in air. Combust. Flame , 95 , 313 .
   Web of Science ®Google Scholar
• Warnatz , J. , Allendorf , M. D. , Kee , R. J. and Coltrin , M. E. ( 1994 ) A model of elementary chemistry and fluid mechanics in the combustion of hydrogen on flat platinum surfaces. Combust. Flame , 96 , 393 .
   Web of Science ®Google Scholar
• Williams , W. R. , Marks , C. M. and Schmidt , L. D. ( 1992 ) Steps in the reaction H2+O2 = H2O on Pt : OH desorption at high temperatures . J. Phys. Chem. , 96 . 5922 .
   Web of Science ®Google Scholar
• ∗ Corresponding author. E-mail: [email protected]
   Google Scholar