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Original Articles

Calcium-Ammonium Selectivity of Two Benchmark Soils from Botswana as Assessed by Competing Semi-empirical Ion Exchange Equations

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Pages 2757-2773 | Received 06 Dec 2013, Accepted 10 Aug 2015, Published online: 20 Nov 2015

References

  • Agbenin, J. O. 1995. Laboratory manual for soil and plant analysis: Selected methods and data analysis. Zaria, Nigeria: Department of Soil Science, Ahmadu Bello University.
  • Agbenin, J. O., and L. Modisaemang. 2014. Homovalent cation exchange of two benchmark soils from Botswana: K→NH4 exchange selectivity coefficients and the thermodynamic exchange constant. Archives of Agronomy and Soil Science 60:827–840.
  • Agbenin, J. O., and L. Modisaemang. 2015. Charge characteristics and the interaction of pH and ionic strength effect on phosphate adsorption of two benchmark soils from Botswana. Communications in Soil Science and Plant Analysis (accepted)
  • Agbenin, J. O., and S. Yakubu. 2006. Potassium-calcium and potassium-magnesium exchange in an acid savanna soil from northern Nigeria. Geoderma 136:542–54. doi:10.1016/j.geoderma.2006.04.008.
  • Bremner, J. M., and C. S. Mulvaney. 1982. Nitrogen—Total. In Methods of soil analysis, part 2: Chemical and microbiological properties, ed. A. L. Page, R. H. Miller, and D. R. Keeney, 595–622. Madison, WI: SSSA.
  • Chappell, M. A., and V. P. Evangelou. 2002. Influence of added K+ on inducing ammonium fixation and inhibiting nitrification. Soil Science 165:420–26. doi:10.1097/00010694-200005000-00006.
  • Chung, J.-B., and R. R. Zasoski. 1994. Ammonium-potassium and ammonium-calcium exchange in bulk and rhizosphere soil. Soil Science Society of America Journal 58:1368–1375.
  • Davies, L. E. 1950. Ionic exchange and statistical thermodynamics, I: Equilibria in simple exchange systems. Journal of Colloid Science 5:71–79. doi:10.1016/0095-8522(50)90006-7.
  • DeSutter, T. M., G. M. Pierzynski, and L. R. Baker. 2006. Flow-through and batch methods for determining calcium-magnesium and magnesium-calcium selectivity. Soil Science Society of America Journal 70:550–54. doi:10.2136/sssaj2005.0065N.
  • Dreschsel, P., L. Gyiele, D. Kunze, and O. Cofie. 2001. Population density: Soil nutrient depletion and economic growth in sub-Sahara Africa. Ecological Economics 38:251–58.
  • Elprince, A. M., A. P. Vanselow, and G. Sposito. 1980. Heterovalent ternary cation exchange equilibria: NH4+-Ba2+-La3+ exchange on montmorillonite. Soil Science Society of America Journal 44:964–69. doi:10.2136/sssaj1980.03615995004400050018x.
  • Essington, M. E. 2004. Soil and water chemistry: An integrative approach. Boca Raton, FL: CRC Press.
  • Evangelou, V. P., and J. Lumbanraja. 2002. Ammonium–potassium–calcium exchange on vermiculite and hydroxyl-aluminium vermiculite. Soil Science Society of America Journal 66:445–55. doi:10.2136/sssaj2002.4450.
  • Gaines, G. L., and H. C. Thomas Jr. 1953. Adsorption studies on clay minerals, II: A formulation of the thermodynamics of exchange adsorption. Journal of Chemical Physics 21:714–18. doi:10.1063/1.1698996.
  • Gaston, L. A., and H. M. Selim. 1991. Predicting cation mobility in kaolinitic media based on exchange selectivities of kaolinite. Soil Science Society of America Journal 55:1255–61. doi:10.2136/sssaj1991.03615995005500050010x.
  • Gee, B. W., and J. W. Bauder. 1986. Particle-size analysis. In Methods of soil analysis, part 1: Physical and mineralogical methods, ed. A. Klute, 383–411. Madison, WI: ASA and SSSA.
  • Goulding, K. W. T. 1983. Thermodynamics of potassium exchange in soils and clay minerals. Advances in Agronomy 36:215–64.
  • Heerink, N. 2004. Soil fertility decline and economic policy reform in sub-Sahara Africa. Land Use Policy 22:67–74. doi:10.1016/j.landusepol.2003.08.002.
  • Hulbert, M. H. 1987. Sodium, calcium, and ammonium exchange on clinoptilolite from the Fort Laclede deposit, Sweet Water County, Wyoming. Clays and Clay Minerals 35:458–462.
  • Jones, M. J., and A. Wild. 1975. Soils of the West African Savanna. Harpenden, UK: Commonwealth Bureau of Soils.
  • Laudelout, H., R. Van Bladel, G. H. Bolt, and A. L. Page. 1967. Thermodynamics of heterovalent cation exchange reactions in a montmorillonitic clay. Transactions of the Faraday Society 44:1477–88.
  • Nelson, D. W., and L. E. Sommers. 1982. Total carbon, organic and organic matter. In Methods of soil analysis, part 2: Chemical and microbiological properties, ed. A. L. Page, and R. H. Miller, 339–577. Madison WI: SSSA.
  • Okamura, Y., and K. Wada. 1984. Ammonium-calcium exchange equilibria in soils and weathered pumices that differ in cation exchange materials. Journal of Soil Science 35:387–96. doi:10.1111/ejs.1984.35.issue-3.
  • Pankhurst, D. L., and C. A. J. Appelo. 1999. User’s guide to PHREEQC version 2: A computer program for speciation, batch reaction, one-dimensional and inverse geochemical calculations. Denver, CO: US Department of Interior and US Department of Geological Survey.
  • Pardo, M. T., G. Ristori, L. P. D’Acqui, and G. Almendros. 2003. An assessment of soil fertility and agronomic constraints in southern savannas: A case study of the Pandamatenga area, Botswana. South African Geographical Journal 85:35–41. doi:10.1080/03736245.2003.9713782.
  • Rhoades, J. D. 1982. Cation exchange capacity. In Methods of soil analysis, part 2: Chemical and microbiological properties, ed. A. L. Page, and R. H. Miller, 149–57. Madison, WI: SSSA.
  • Sposito, G. 2008. The chemistry of soils. New York: Oxford University Press.
  • Talibudeen, O. 1981. Cation exchange in soils. In Chemistry of soil processes, ed. D. J. Greeland, and M. H. B. Hayes, 115–177. New York: Wiley.
  • Van Bladel, R. 1967. A short account of a thermodynamic and thermochemical study of potassium for alkali and alkaline earth cations in clay. Potash Review 4:1–12.
  • Vanselow, A. P. 1932. Equilibria of the base exchange reactions of bentonite, permutites, soil colloids, and zeolites. Soil Science 33:95–114. doi:10.1097/00010694-193202000-00002.
  • Verbug, K., and P. Baveye. 1994. Hysteresis in the binary exchange of cations on 2:1 clay minerals: A critical review. Clays and Clay Minerals 42:207–20. doi:10.1346/CCMN.1994.0420211.
  • Wada, S.-I., and M. Masaki. 1990. Thermodynamics of ammonium-calcium exchange on a halloysitic soil clay. Soil Science and Plant Nutrition 36:495–99. doi:10.1080/00380768.1990.10416918.
  • Weatherly, L. R., and N. D. Milaclinovic. 2004. Comparison of ion uptake of ammonium ion onto a New Zealand clinoptilolite and mordenite. Water Research 38:4305–12. doi:10.1016/j.watres.2004.08.026.
  • Yakubu, S., and J. O. Agbenin. 2010. Heterovalent cation exchange in two savanna soils of different lithogenic origin as described by the Rothmund Kornfeld model. Geoderma 158:128–36. doi:10.1016/j.geoderma.2010.04.016.

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