Electron microscopy, XRD, dielectric, and Mossbauer studies of Li-doped Pb(Fe_0.5Nb_0.5)O₃ ceramics sintered from mechanically activated powders

References

• I. P. Raevskii, S. T. Kirillov, M. A. Malitskaya, V. P. Filippenko, S. M. Zaitsev, and L. G. Kolomin: Phase transitions and ferroelectric properties of lead ferroniobate. Inorg Mater. 24: 217–220 (1988).
   Web of Science ®Google Scholar
• A. A. Bokov, L. A. Shpak, and I. P. Rayevsky: Diffuse phase transition in Pb(Fe0.5Nb0.5)O3-based solid solutions. J Phys Chem Solids. 54: 495–498 (1993).
   Web of Science ®Google Scholar
• Yu. N. Zakharov, S. I. Raevskaya, A. G. Lutokhin, V. V. Titov, I. P. Raevski, V. G. Smotrakov, V. V. Eremkin, A. S. Emelyanov, and A. A. Pavelko: Field-induced enhancement of pyroelectric response of PbMg1/3Nb2/3O3-PbTiO3 and PbFe1/2Nb1/2O3-PbTiO3 solid solution ceramics. Ferroelectrics. 399: 20–26 (2010).
   Web of Science ®Google Scholar
• D. Bochenek, P. Kruk, R. Skulski, and P. Wawrzała: Multiferroic ceramics Pb(Fe1/2Nb1/2)O3 doped by Li. J Electroceram. 26: 8–11 (2011).
   Web of Science ®Google Scholar
• E. I. Sitalo, I. P. Raevski, A. G. Lutokhin, A. V. Blazhevich, S. P. Kubrin, S. I. Raevskaya, Yu. N. Zakharov, M. A. Malitskaya, V. V. Titov, and I. N. Zakharchenko: Dielectric and piezoelectric properties of PbFe1/2Nb1/2O3-PbTiO3 ceramics from the morphotropic phase boundary compositional range. IEEE Trans Ultrason Ferroelect Freq Contr. 58: 1914–1919 (2011).
   PubMed Web of Science ®Google Scholar
• I. P. Raevskii, V. V. Eremkin, V. G. Smotrakov, M. A. Malitskaya, S. A. Bogatina, and L. A. Shilkina: Growth and study of PbFe1/2Ta1/2O3 single crystals. Crystallogr Rep. 47: 1007–1011 (2002).
   Web of Science ®Google Scholar
• I. P. Raevski, S. A. Kuropatkina, S. P. Kubrin, S. I. Raevskaya, V. V. Titov, D. A. Sarychev, M. A. Malitskaya, A. S. Bogatin, and I. N. Zakharchenko: Dielectric and Mossbauer studies of high-permittivity BaFe1/2Nb1/2O3 ceramics with cubic and monoclinic perovskite structures. Ferroelectrics. 379: 48–54 (2009).
   Web of Science ®Google Scholar
• I. P. Raevski, S. P. Kubrin, S. A. Kovrigina, V. V. Titov, A. S. Emelyanov, M. A. Malitskaya, and I. N. Zakharchenko: The Effect of PbO nonstoichiometry on dielectric and semiconductive properties of PbFe0.5Nb0.5O3 -based ceramics. Ferroelectrics. 397: 96–101 (2010).
   Web of Science ®Google Scholar
• S. A. Prosandeev, A. V. Fisenko, A. V. Riabchinski, I. A. Osipenko, I. P. Raevski, and N. Safontseva: Study of intrinsic point defects in oxides of the perovskite family. I. Theory. J Phys Condens Matter. 8: 6705–6717 (1996).
   Web of Science ®Google Scholar
• O. Raymond, R. Font, N. Suarez-Almodovar, J. Portelles, and J. M. Siqueiros: Frequency-temperature response of ferroelectromagnet Pb(Fe1/2Nb1/2)O3 ceramics obtained by different precursor: Part I. structural and thermo-electrical characterization. J Appl Phys. 97: 084107 (2005).
   Web of Science ®Google Scholar
• A. Kania, E. Talik, and M. Kruczek: X-Ray photoelectron spectroscopy, magnetic and dielectric studies of PbFe1/2Nb1/2O3 single crystals. Ferroelectrics. 2009: 391: 114–121.
   Web of Science ®Google Scholar
• A. T. Kozakov, A. G. Kochur, K. A. Googlev, A. V. Nikolsky, I. P. Raevski, V. G. Smotrakov, and V. V. Yeremkin: X-ray photoelectron study of the valence state of iron in iron-containing single-crystal (BiFeO3, PbFe1/2Nb1/2O3), and ceramic (BaFe1/2Nb1/2O3) multiferroics. J Electron Spectrosc Related Phenom. 184: 16–23 (2011).
   Web of Science ®Google Scholar
• A. Bharti, S. Dutta, S. N. Shannigrahi, R. K. Choudhary, T. P. Thapa, and T. P. Sinha: Impedance spectroscopy, electronic structure and X-ray photoelectron spectroscopy studies of Pb(Fe1/2Nb1/2)O3. J. Electron Spectrosc Related Phenom. 169: 80–85 (2009).
   Web of Science ®Google Scholar
• V. V. Laguta, J. Rosa, L. Jastrabik, R. Blinc, P. Cevc, B. Zalar, M. Remskar, S. I. Raevskaya, and I. P. Raevski: 93Nb NMR and Fe3+ EPR study of local magnetic properties of disordered magnetoelectric PbFe1/2Nb1/2O3. Mater Res Bull. 45: 1720–1727 (2010).
   Web of Science ®Google Scholar
• V. V. Laguta, M. D. Glinchuk, M. Maryško, R. O. Kuzian, S. A. Prosandeev, S. I. Raevskaya, V. G. Smotrakov, V. V. Eremkin, and I. P. Raevski: Effect of the Ba and Ti-doping on the magnetic properties of multiferroic Pb(Fe1/2Nb1/2)O3. Phys Rev B. 87: 064403 (2013).
   Web of Science ®Google Scholar
• I. P. Raevski, S. P. Kubrin, S. I. Raevskaya, V. V. Stashenko, D. A. Sarychev, M. A. Malitskaya, M. A. Seredkina, V. G. Smotrakov, I. N. Zakharchenko, and V. V. Eremkin: Dielectric and Mossbauer studies of perovskite multiferroics. Ferroelectrics. 373: 121–126 (2008).
   Web of Science ®Google Scholar
• I. P. Raevski, S. P. Kubrin, S. I. Raevskaya, D. A. Sarychev, S. A. Prosandeev, and M. A. Malitskaya: Magnetic properties of PbFe1/2Nb1/2O3: Mossbauer spectroscopy and first principles calculations. Phys Rev B. 85: 224412 (2012).
   Web of Science ®Google Scholar
• R. Demirbilek, A. V. Kutsenko, S. Kapphan, I. Raevski, S. Prosandeev, B. Burton, L. Jastrabik, and V. Vikhnin: Optical Spectra, Properties and First Principles Computations of Ba(Fe,Nb)O3 and Pb(Fe,Nb)O3. Ferroelectrics. 302: 525–529 (2004).
   Web of Science ®Google Scholar
• D. A. Sanchez, N. Ortega, A. Kumar, G. Sreenivasulu, R. S. Katiyar, J. F. Scott, D. M. Evans, M. Arredondo-Arechavala, A. Schilling, and J. M. Gregg: Room-temperature single phase multiferroic magnetoelectrics: Pb(Fe,M)x(Zr,Ti)(1−x)O3 [M = Ta, Nb]. J Appl Phys. 113: 074105 (2013).
   Web of Science ®Google Scholar
• S. P. Singh, S. M. Yusuf, S. Yoon, S. Baik, N. Shin, and D. Pandey: Ferroic transitions in the multiferroic (1−x)Pb(Fe1/2Nb1/2)O3–xPbTiO3 system and its phase diagram. Acta Mater. 58: 5381–5392 (2010).
   Web of Science ®Google Scholar
• I. P. Raevski, S. P. Kubrin, S. I. Raevskaya, S. A. Prosandeev, M. A. Malitskaya, V. V. Titov, D. A. Sarychev, A. V. Blazhevich, and I. N. Zakharchenko: Dielectric and Mossbauer studies of ferroelectric and magnetic phase transitions in A-Site and B-Site substituted multiferroic PbFe0.5Nb0.5O3. IEEE Trans Ultrason Ferroelect Freq Contr. 59: 1872–1878 (2012).
   PubMed Web of Science ®Google Scholar
• I. P. Raevski, S. P. Kubrin, V. V. Laguta, M. Maryško, H. Chen, S. I. Raevskaya, V. V. Titov, C. C. Chou, A. V. Blazhevich, E. I. Sitalo, D. A. Sarychev, T. A. Minasyan, A. G. Lutokhin, Yu. N. Zakharov, L. E. Pustovaya, I. N. Zakharchenko, and M. A. Malitskaya: Comparative studies of ferroelectric and magnetic phase transitions in Pb(Fe1/2Nb1/2)O3-PbMO3 (M-Ti, Zr) multiferroic solid solutions. Ferroelectrics. 475: 20–30 (2015).
   Web of Science ®Google Scholar
• V. V. Laguta, V. A. Stephanovich, M. Savinov, M. Marysko, R. O. Kuzian, N. M. Olekhnovich, A. V. Pushkarev, Yu. V. Radyush, I. P. Raevski, S. I. Raevskaya, and S. A. Prosandeev: Superspin glass phase and hierarchy of interactions in multiferroic PbFe1/2Sb1/2O3: an analog of ferroelectric relaxors?. New J Phys. 16: 11304 (2014).
   Web of Science ®Google Scholar
• I. P. Raevski, V. V. Titov, M. A. Malitskaya, E. V. Eremin, S. P. Kubrin, A. V. Blazhevich, H. Chen, C. C. Chou, S. I. Raevskaya, I. N. Zakharchenko, D. A. Sarychev, and S. I. Shevtsova: Studies of ferroelectric and magnetic phase transitions in multiferroic PbFe0.5Ta0.5O3 – PbTiO3 solid solution ceramics. J Mater Sci. 49: 6459–6466 (2014).
   Web of Science ®Google Scholar
• P. Amonpattaratkit, P. Jantaratana, and S. Ananta. Influences of PZT addition on phase formation and magnetic properties of perovskite Pb(Fe0.5Nb0.5)O3-based ceramics. J Magn Magn Mater. 389: 95–100 (2015).
   Web of Science ®Google Scholar
• I. P. Raevski, M. S. Molokeev, S. V. Misyul, E. V. Eremin, A. V. Blazhevich, S. P. Kubrin, H. Chen, C. C. Chou, S. I. Raevskaya, V. V. Titov, D. A. Sarychev, and M. A. Malitskaya: Studies of ferroelectric and magnetic phase transitions in multiferroic PbFe0.5Ta0.5O3. Ferroelectrics. 475: 52–60 (2015).
   Web of Science ®Google Scholar
• I. O. Troyanchuk, M. V. Bushinsky, A. N. Chobot, O. S. Mantytskaya, N. V. Pushkarev, and R. Szymczak: Crystal-structure and magnetic phase transformations in solid solutions of BiFeO3-AFe0.5Nb0.5O3 (A = Ca, Sr, Ba, Pb). J Exper Theor Phys. 107: 245–250 (2008).
   Web of Science ®Google Scholar
• A. A. Gusev, I. P. Raevski, E. G. Avvakumov, V. P. Isupov, S. P. Kubrin, H. Chen, C. C. Chou, D. A. Sarychev, V. V. Titov, A. M. Pugachev, S. I. Raevskaya, and V. V. Stashenko: The effect of mechanical activation on the synthesis and properties of multiferroic lead iron niobate. Springer Proc in Physics. 152: 15–26 (2014).
   Google Scholar
• X. Gao, J. Xue, J. Wang, T. Yu, and Z. X. Shen: Sequential combination of constituent oxides in the synthesis of Pb(Fe1/2Nb1/2)O3 by mechanical activation. J Am Ceram Soc. 85: 565–572 (2002).
   Web of Science ®Google Scholar
• D. Bochenek, G. Dercz, and D. Oleszak: Application of mechanical activation in synthesizing, multiferroic Pb(Fe0.5 Nb0.5)O3 powders. Arch Metall Mater A. 56: 1015–1020 (2011).
   Web of Science ®Google Scholar
• A. A. Gusev, I. P. Raevski, E. G. Avvakumov, V. P. Isupov, S. I. Raevskaya, H. Chen, V. V. Titov, C. C. Chou, S. P. Kubrin, S. V. Titov, and M. A. Malitskaya: Dielectric properties of undoped and Li-doped Pb(Fe1/2Nb1/2)O3 ceramics sintered from mechanochemically synthesized powders. Ferroelectrics. 475: 61–67 (2015).
   Web of Science ®Google Scholar
• A. A. Gusev, S. I. Raevskaya, V. V. Titov, E. G. Avvakumov, V. P. Isupov, I. P. Raevski, H. Chen, C. C. Chou, S. P. Kubrin, S. V. Titov, M. A. Malitskaya, A. V. Blazhevich, D. A. Sarychev, V. V. Stashenko, and S. I. Shevtsova: Dielectric and Mossbauer studies of Pb(Fe1/2Ta1/2)O3 multiferroic ceramics sintered from mechanoactivated powders. Ferroelectrics. 475: 41–51 (2015).
   Web of Science ®Google Scholar
• A. A. Bokov, V. Yu Shonov, I. P. Rayevsky, E. S. Gagarina, and M. F. Kupriyanov: Compositional ordering and phase transitions in PbYb1/2Nb1/2O3, J Phys: Condens Matter 5: 5491–5504 (1993).
   Google Scholar
• I. P. Rayevsky, A. A. Bokov, A. S. Bogatin, S. M. Emelyanov, M. A. Malitskaya, and O. I. Prokopalo: Electric properties in the range of ferroelectric phase transitions in PbFe0.5Nb0.5O3 crystals and ceramics. Ferroelectrics. 126: 191–196 (1992).
   Web of Science ®Google Scholar
• C. Lei, A. A. Bokov, and Z. G. Ye: Ferroelectric to relaxor crossover and dielectric phase diagram in the BaTiO3–BaSnO3 system. J Appl Phys. 101: 084105 (2007).
   Web of Science ®Google Scholar
• S. I. Raevskaya, A. G. Lutokhin, A. M. Pugachev, I. P. Raevski, V. V. Titov, Yu. N. Zakharov, D. V. Suzdalev, E. M. Panchenko, and S. A. Prosandeev: Bias field effect on the dielectric and pyroelectric response of single crystal of uniaxial relaxor Sr0.75Ba0.25Nb2O6. Ferroelectrics. 440: 59–66 (2012).
   Web of Science ®Google Scholar
• I. P. Raevski, L. A. Reznitchenko, M. A. Malitskaya, L. A. Shilkina, S. O. Lisitsina, S. I. Raevskaya, and E. M. Kuznetsova: NaNbO3-based relaxor. Ferroelectrics. 299: 95–101 (2004).
   Web of Science ®Google Scholar
• S. I. Raevskaya, V. V. Titov, I. P. Raevski, A. G. Lutokhin, Yu. N. Zakharov, V. Yu. Shonov, A. V. Blazhevich, E. I. Sitalo, H. Chen, C. C. Chou, S. A. Kovrigina, and M. A. Malitskaya: Bias field effect on the dielectric and pyroelectric response of Pb(Fe0.5Ta0.5)O3 relaxor multiferroic ceramics. Ferroelectrics. 475: 31–40 (2015).
   Web of Science ®Google Scholar
• A. A. Bokov, Y. H. Bing, W. Chen, Z. G. Ye, S. A. Bogatina, I. P. Raevski, S. I. Raevskaya, and E. V. Sahkar: Empirical scaling of the dielectric permittivity peak in relaxor ferroelectrics. Phys Rev B. 68: 052102 (2003).
   Web of Science ®Google Scholar
• I. P. Raevski, N. M. Olekhnovich, A. V. Pushkarev, Y. V. Radyush, S. P. Kubrin, S. I. Raevskaya, M. A. Malitskaya, V. V. Titov, and V. V. Stashenko: Mössbauer studies of PbFe0.5Nb0.5O3-PbFe0.5Sb0.5O3 multiferroic solid solutions. Ferroelectrics. 444: 47–52 (2013).
   Web of Science ®Google Scholar
• `N. S. Druzhinina, Yu. I. Yuzyuk, I. P. Raevski, M. El Marssi, V. V. Laguta, and S. I. Raevskaya: Raman spectra of PbFe0.5Nb0.5O3 multiferroic single crystals and ceramics. Ferroelectrics. 438: 107–114 (2012).
   Web of Science ®Google Scholar
• S. Y. An, I. B. Shim, and C. S. Kim: Synthesis and magnetic properties of LiFe5O8 powders by a sol-gel process. J Magn Magn Mater. 290–291: 1551–1554 (2005).
   Web of Science ®Google Scholar