107
Views
0
CrossRef citations to date
0
Altmetric
Research Article

Continuous Solvothermal Synthesis of Metal-Organic Framework (Cu-BTC) Nanoparticles Using a Microstructured Mixer Equipped with Double-Tube, Swirl, and Contraction Flow Channels

Article: 2362797 | Received 14 Mar 2024, Accepted 28 May 2024, Published online: 06 Jun 2024

References

  • Bayliss PA, Ibarra IA, Pérez E, Yang SH, Tang CC, Poliakoff M, Schröder M. 2014. Synthesis of metal-organic frameworks by continuous flow. Green Chem. 16:3796–3802. doi: 10.1039/C4GC00313F.
  • Ehrling S, Miura H, Senkovska I, Kaskel S. 2021. From macro- to nanoscale: finite size effects on metal-organic framework switchability. Trends in Chem. 3:291–304.
  • Faustini M, Kim J, Jeong GY, Kim JY, Moon HR, Ahn WS, Kim DP. 2013. Microfluidic approach toward continuous and ultrafast synthesis of metal-organic framework crystals and hetero structures in confined microdroplets. J Am Chem Soc. 135:14619–14626. doi: 10.1021/ja4039642.
  • Furukawa S, Reboul J, Diring S, Sumida K, Kitagawa S. 2014. Structuring of metal-organic frameworks at the mesoscopic/macroscopic scale. Chem Soc Rev. 43:5700–5734. doi: 10.1039/c4cs00106k.
  • Gimeno-Fabra M, Munn AS, Stevens LA, Drage TC, Grant DM, Kashtiban RJ, Sloan J, Lester E, Walton RI. 2012. Instant MOFs: continuous synthesis of metal-organic frameworks by rapid solvent mixing. Chem Comm. 48:10642–10644.
  • Howarth AJ, Liu YY, Li P, Li ZY, Wang TC, Hupp J, Farha OK. 2016. Chemical, thermal and mechanical stabilities of metal-organic frameworks. Nat Rev Mat. 1:15018.
  • Kim KJ, Li YJ, Kreider PB, Chang CH, Wannenmacher N, Thallapally PK, Ahn HG. 2013. High-rate synthesis of Cu-BTC metal-organic frameworks. Chem Comm. 49:11518–11520.
  • Kubo M, Ishimura M, Shimada M. 2021. Improvement of production efficiency of spray-synthesized HKUST-1. Adv Powder Technol. 32:2370–2378. doi: 10.1016/j.apt.2021.05.024.
  • Mae K, Suzuki A, Maki T, Hakuta Y, Sato H, Arai K. 2007. A new micromixer with needle adjustment for instant mixing and heating under high pressure and high temperature. J. Chem. Eng. Jpn. 40:1101–1107.
  • Meek ST, Greathouse JA, Allendorf MD. 2011. Metal-organic frameworks: a rapidly growing class of versatile nanoporous materials. Adv Mater. 23:249–267. doi: 10.1002/adma.201002854.
  • Rubio-Martinez M, Batten MP, Polyzos A, Carey KC, Mardel JI, Lim KS, Hill MR. 2014. Versatile, high quality and scalable continuous flow production of metal-organic frameworks. Sci Rep. 4:5443. doi: 10.1038/srep05443.
  • Sani NAA, Lau WJ, Ismail AF. 2015. Polyphenylsulfone-based solvent resistant nanofiltration (srnf) membrane incorporated with copper-1,3,5-benzenetricarboxylate (Cu-BTC) nanoparticles for methanol separation. RSC Adv. 5:13000–13010. doi: 10.1039/C4RA14284E.
  • Schroeder JA, Penoncello SG, Schroeder JS. 2014. A fundamental equation of state for ethanol. J Phys Chem Ref Data. 43:043102.
  • Sue K, Hakuta U, Furuya T, inventors; National Institute of Advanced Industrial Science and Technology, assignee. 2015. Mixing device of high temperature and high pressure fluids. Japan patent JP5649066B2.
  • Takahashi A, Minami N, Tanaka H, Sue K, Minami K, Parajuli D, Lee K-M, Ohkoshi S-I, Kurihara M, Kawamoto T. 2015. Efficient synthesis of size-controlled open-framework nanoparticles fabricated with a micro-mixer: route to the improvement of Cs adsorption performance. Green Chem. 17:4228–4233. doi: 10.1039/C5GC00757G.
  • Wang SZ, McGuirk CM, d‘Aquino A, Mason JA, Mirkin CA. 2018. Metal-organic framework nanoparticles. Adv Mater. 30:e1800202. doi: 10.1002/adma.201800202.
  • Wang L, Fang M, Liu J, He J, Deng L, Li J, Lei J. 2015. The influence of dispersed phases on polyamide/ZIF-8 nanofiltration membranes for dye removal from water. RSC Adv. 5:50942–50954. doi: 10.1039/C5RA06185G.
  • Wakashima Y, Suzuki A, Kawasaki S, Matsui K, Hakuta Y. 2007. Development of a new swirling micro mixer for continuous hydrothermal synthesis of nano-size particles. J Chem Eng Jpn. 40:622–629.
  • Wakashima Y, Hatakeda K, Kawasaki S, Suzuki A. 2008. Performance evaluation of a high pressure microtube as a high-speed heating device for supercritical state generation. J Chem Eng Jpn. 41:76–83.
  • Yuan S, Feng L, Wang KC, Pang JD, Bosch M, Lollar C, Sun YJ, Qin JS, Yang XY, Zhang P, et al. 2018. Stable metal-organic frameworks: design, synthesis, and applications. Adv. Mater. 30:1704303.