Mathematical Model of the Emulsion Polymerization Stability for Vinyl Acetate, Methyl Methacrylate, Butyl Acrylate and Acrylic Acid Tetra-polymers

References

• Kane, R. S. Fabricating Complex Polymeric Micro- and Nanostructures: Lithography in Microfluidic Devices. Angew. Chem. Int. Ed. 2008, 47, 1368–1370. DOI:10.1002/anie.200704426.
   PubMed Web of Science ®Google Scholar
• Zhihong, N.; Shengqing, X.; Minseok, S.; Patrick, L. C.; Eugenia, K. C. Polymer Particles with Various Shapes and Morphologies Produced in Continuous Microfluidic Reactors. J. Am. Chem. Soc. 2005, 127, 8058–8063. DOI:10.1021/ja042494w.
   PubMed Web of Science ®Google Scholar
• Pladis, P.; Alexopoulos, A. H.; Kiparissides, C. Mathematical Modeling and Simulation of Vinylidene Fluoride Emulsion Polymerization. Ind. Eng. Chem. Res. 2014, 53, 7352–7364. DOI:10.1021/ie403548m.
   Web of Science ®Google Scholar
• Kang, Y.; Pitto-Barry, A.; Willcock, H.; Quan, W.; Kirby, N.; Sanchez, A. M.; O'Reilly, R. K. Exploiting Nucleobase-containing Materials – from Monomers to Complex Morphologies Using RAFT Dispersion Polymerization. Polym. Chem. 2015, 6, 106–117. DOI:10.1039/C4PY01074D.
   Web of Science ®Google Scholar
• Thickett, S. C.; Gilbert, R. G. Emulsion Polymerization: State of the Art in Kinetics and Mechanisms. Polymer 2007, 48, 6965–6991. DOI:10.1016/j.polymer.2007.09.031.
   Web of Science ®Google Scholar
• Chern, C. S. Emulsion Polymerization Mechanisms and Kinetics. Prog. Polym. Sci. 2006, 31, 443–486. DOI:10.1016/j.progpolymsci.2006.02.001.
   Web of Science ®Google Scholar
• Kawaguchi, H. Functional Polymer Microspheres. Prog. Polym. Sci. 2000, 25, 1171–1210. DOI:10.1016/S0079-6700(00)00024-1.
   Web of Science ®Google Scholar
• Min, K. W.; Ray, W. H. On the Mathematical Modeling of Emulsion Polymerization Reactors. J. Macromol. Sci. Polymer Rev. 1974, 11, 177–255. DOI:10.1080/15583727408546024.
   Web of Science ®Google Scholar
• Fan, S.; Steinke, J. H. G.; Alpay, E. Emulsion Polymerizations in a Pilot-Scale Loop Reactor with Inline Static Mixers. Ind. Eng. Chem. Res. 2005, 44, 5483–5490. DOI:10.1021/ie049783d.
   Web of Science ®Google Scholar
• Nomura, M.; Tobita, H.; S, K. Emulsion Polymerization:Kinetic and Mechanistic Aspects. Adv. Polym. Sci. 2005, 175, 1–128.
   Web of Science ®Google Scholar
• Hodge, S. M.; Rousseau, D. Flocculation and Coalescence in Water-in-oil Emulsions Stabilized by Paraffin Wax Crystals. Food Res. Int. 2003, 36, 695–702. DOI:10.1016/S0963-9969(03)00036-X.
   Web of Science ®Google Scholar
• Liu, S.; Deng, R.; Li, W.; Zhu, J. Polymer Microparticles with Controllable Surface Textures Generated through Interfacial Instabilities of Emulsion Droplets. Adv. Funct. Mater. 2012, 22, 1692–1697. DOI:10.1002/adfm.201103018.
   Web of Science ®Google Scholar
• Guojun, L.; Fumin, W.; Wangfeng, G.; Hang, L.; Xubin, Z. Influences of Addition of Hydrophilic Surfactants on the W/O Emulsions Stabilized by Lipophilic Surfactants. Colloid Surf. A 2014, 457, 441–448. DOI:10.1016/j.colsurfa.2014.06.031.
   Google Scholar
• Jafari, S. M.; Assadpoor, E.; He, Y.; Bhandari, B. Re-coalescence of Emulsion Droplets during High-energy Emulsification. Food Hydrocolloids 2008, 22, 1191–1202. DOI:10.1016/j.foodhyd.2007.09.006.
   Web of Science ®Google Scholar
• Parisi, O. I.; Curcio, M.; Puoci, F. Polymer Chemistry and Synthetic Polymers. In Advanced Polymers in Medicine, Puoci, F., Ed; Springer International Publishing, Berlin, 2015, 1–31.
   Google Scholar
• Dorsey, J.; Schork, F. J.; Poehlein, G. W.; Shoaf, G. L. Surface Active Properties of Polyester Surfactants with Applications to Seeded Emulsion Polymerization. Polym. React. Eng. 1996, 4, 105–134. DOI:10.1080/10543414.1996.10744470.
   Web of Science ®Google Scholar
• Gao, J.; Penlidis, A. Mathematical Modeling and Computer Simulator/database for Emulsion Polymerizations. Prog. Polym. Sci. 2002, 27, 403–535. DOI:10.1016/S0079-6700(01)00044-2.
   Web of Science ®Google Scholar
• Ahmad, A. L.; Kusumastuti, A.; Derek, C. J. C.; Ooi, B. S. Emulsion Liquid Membrane for Cadmium Removal: Studies on Emulsion Diameter and Stability. Desalination 2012, 287, 30–34. DOI:10.1016/j.desal.2011.11.002.
   Web of Science ®Google Scholar
• Nesterenko, A.; Drelich, A.; Lu, H.; Clausse, D.; Pezron, I. Influence of a Mixed Particle/surfactant Emulsifier System on Water-in-oil Emulsion Stability. Colloid Surf. A-Physicochem. Eng. 2014, 457, 49–57. DOI:10.1016/j.colsurfa.2014.05.044.
   Web of Science ®Google Scholar
• Penlidis, A.; Macgregor, J. F.; Hamielec, A. E. Mathematical Modeling of Emulsion Polymerization Reactors. Polimeros 1986, 313, 219–240.
   Google Scholar
• Szkurhan, A. R.; Georges, M. K. Stable Free-Radical Emulsion Polymerization. Macromolecules 2004, 37, 4776–4782. DOI:10.1021/ma049795a.
   Web of Science ®Google Scholar
• Ortega-Vinuesa, J. L.; Mart, N.; Rodr Guez, A.; Hidalgo-Álvarez, R. Colloidal Stability of Polymer Colloids with Different Interfacial Properties: Mechanisms. J. Colloid Interf. Sci. 1996, 184, 259–267. DOI:10.1006/jcis.1996.0619.
   PubMed Web of Science ®Google Scholar
• Miyagawa, Y.; Katsuki, K.; Matsuno, R.; Adachi, S. Effect of Oil Droplet Size on Activation Energy for Coalescence of Oil Droplets in an O/W Emulsion. Biosci. Biotechnol. Biochem. 2015, 79, 1695–1700. DOI:10.1080/09168451.2015.1039482.
   PubMed Web of Science ®Google Scholar
• Vale, H. M.; McKenna, T. F. Modeling Particle Size Distribution in Emulsion Polymerization Reactors. Prog. Polym. Sci. 2005, 30, 1019–1048. DOI:10.1016/j.progpolymsci.2005.06.006.
   Web of Science ®Google Scholar
• Binks, B. P.; Cho, W. G.; Fletcher, P. D. I.; Petsev, D. N. Stability of Oil-in-Water Emulsions in a Low Interfacial Tension System. Langmuir 2000, 16, 1025–1034. DOI:10.1021/la990952m.
   Web of Science ®Google Scholar
• Puertas, A. M.; Nieves, F. Colloidal Stability of Polymer Colloids with Variable Surface Charge. Interface 1999, 184, 1025–1034.
   Google Scholar
• Zeng, F.; F, L. Study on the Preparation Technology of Core Shell Composite Emulsion. Paint. Coat. Ind. 1995, 4, 6–8.
   Google Scholar
• Tongyu, C.; Qingpu, L.; Polymer, J. H. Emulsion Synthesis Principle, Properties and Applications, Chemical Industry Press: Peking, 2007.
   Google Scholar