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Molecular Physics
An International Journal at the Interface Between Chemistry and Physics
Volume 41, 1980 - Issue 5
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Original Articles

The microwave spectrum of thietan-2,2,4,4-d4

Vibration-rotation coupling in several ring puckering states

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Pages 1081-1089 | Received 23 Jun 1980, Published online: 22 Aug 2006

References

  • Harris , D.O. , Harrington , H.W. , Luntz , A.C. and Gwinn , W.D. 1966 . J. chem. Phys. , 44 : 3467 – 3467 .
  • Sont , W.N. 1977 . Ph.D. Thesis , The University of Calgary .
  • Nielsen , C.J. 1977 . Acta chem. scand. A , 31 : 791 – 791 .
  • Watson , J.K.G. 1968 . Molec. Phys. , 15 : 479 – 479 .
  • Mills , I.M. 1972 . Molecular Spectroscopy: Modern Research , Edited by: Rao , K.N. and Mathews , C.W. Academic Press .
  • Watson , J.K.G. 1977 . Vibrational Spectra and Structure , Edited by: Durig , J.R. Vol. 6 , Elsevier Scientific Publishing .
  • Pickett , H. 1972 . J. chem. Phys. , 56 : 1715 – 1715 .
  • Luntz , A.C. 1969 . J. chem. Phys. , 50 : 1109 – 1109 .
  • Halonen , L. , Friz , E. , Robiette , A.G. and Mills , I.M. 1980 . J. molec. Spectrosc. , 79 : 432 – 432 .
  • Wieser , H. , Duckett , J.A. and Kydd , R.A. 1974 . J. molec. Spectrosc. , 51 : 115 – 115 . The earlier calculations for fitting the observed far infrared transitions were carried out in terms of the reduced puckering coordinate Z, yielding V (Z)/cm-1=19·330 (Z 4-7·306 Z 2). The transformation to the coordinate Q p is achieved by the conversion Z=[(19·330 cm-1) (8π2 c/h]1/2 Q p=(1·07082 u-1/2 Å-1)Q p. Using the same data base and an assumed reduced mass of 172·0 u, the corresponding potential function in the dimensional puckering coordinate x is V(x)/cm-1=751900 (x/Å)4-27853 (x/Å)2.
  • Creswell , R.A. and Mills , I.M. 1974 . J. molec. Spectrosc. , 52 : 392 – 392 .
  • Mallinson , P.D. and Robiette , A.G. 1974 . J. molec. Spectrosc. , 52 : 413 – 413 .

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