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Molecular Physics
An International Journal at the Interface Between Chemistry and Physics
Volume 44, 1981 - Issue 5
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Original Articles

Thermodynamics of a one-dimensional hard rod mixture with non-additive lengths

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Pages 1137-1143 | Received 14 Apr 1981, Accepted 27 Jul 1981, Published online: 23 Aug 2006

References

  • Tenne , R. and Bergmann , E. 1978 . Phys. Rev. A , 17 : 2036 – 2036 . (b) Bergmann, E., and Tenne, R., 1978, Chem. Phys. Lett., 56, 310.
  • Tenne , R. and Bergmann , E. 1980 . Phys. Rev. B , 22 : 702 – 702 .
  • Lebowitz , J.L. and Zomic , D. 1971 . J. chem. Phys. , 54 : 3335 – 3335 .
  • Longuet-Higgins , H.C. 1958 . Molec. Phys. , 1 : 83 – 83 .
  • Barboy , B. and Tenne , R. manuscript in preparation
  • The interest in systems of high non-additivity and particularly mixtures of particles differing largely in their sizes (σ11≫σ22) stems from study of adsorption phenomena (see, for example, Tenne R. Bergmann E. Phys. Rev. B 1980 22 702 702 [2] on partially localized adsorption). It has also been shown elsewhere that there exists an equivalence between the mixture of hard spheres with σ22 = 0 and a system of attracting hard spheres (so-called Widom-Rowlinson correspondence, see [7]).
  • Barboy , B. and Gelbart , W.M. 1980 . J. statist. Phys. , 22 : 709 – 709 .
  • Tonks , L. 1936 . Phys. Rev. , 50 : 955 – 955 .
  • Rushbrooke , G.S. and Ursell , H.D. 1948 . Proc. Camb. phil. Soc. math. phys. Sci. , 44 : 263 – 263 . (b) Landau, L. D., and Lifshitz, E. M., 1980, Statistical Physics, Vol. 1 (Pergamon Press), p. 537.
  • We must note here that the orderings and separations in mixtures of high dimensionality are significantly different from those found in our model Namely, an order-disorder phenomena or demixing in two and three dimensions have a character of an abrupt phase transition while for our one-dimensional system the ‘transition’ proceeds smoothly.
  • Lovett , R. , Ortoleva , P. and Ross , J. 1978 . J. chem. Phys. , 69 : 947 – 947 .
  • Azaroff , L.V. 1960 . Introduction to Solids , McGraw-Hill . chap. 11.

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