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OPPI BRIEFS

AN IMPROVED SYNTHESIS OF MONOESTERS OF PHOSPHORIC ACID

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Pages 57-60 | Received 19 Sep 1991, Published online: 18 Feb 2009

References

  • Sasse , K. 1964 . “Organische Phosphorverbindungen” , Vol. 2 , 143 – 158 . Stuttgart : G. Thieme Verlag .
  • Yamaguchi , H. , Ogura , F. , Otsubo , T. and Ikeura , Y. 1981 . Bull. Chem. Soc. Jpn. , 54 : 1891
  • Obata , T. and Mukaiyama , T. 1967 . J. Org. Chem. , 32 : 1063
  • Khwaja , T. A. , Reese , C. B. and Stewart , J. C. M. 1970 . J. Chem. Soc. (C) , : 2092
  • Sasse , K. 1964 . “Organische Phosphorverbindungen” , Vol. 2 , 212 – 219 . Stuttgart : G. Thieme Verlag .
  • Cramer , F. and Winter , M. 1959 . Chem. Ber. , 92 : 2761
  • Edmundson , R. S. 1988 . “Dictionary of Organophosphorus Compounds” , 610 London : Chapman and Hall .
  • With benzyl and tert-butyl alcohol as substrates, treatment with POCl3 (with or without a tertiary amine) led to the formation of the corresponding chloroalkane as the only isolable organic product. With cyclohexanol, high yield of cyclohexene was obtained. We believe that the spontaneous decomposition of the product 1 involves fragmentation to the corresponding carbonium ion and of the metaphosphate species, CIPO2.9
  • Cocks , S. and Modro , T. A. 1985 . Tetrahedron Lett. , 26 : 945

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