An Overview of Green Analytical Techniques in the Spectrometric Analysis of Environmental and Biological Samples

REFERENCES

• Armenta , S. ; Garrigues , S. ; de la Guardia , M. Green analytical chemistry . Trends Anal. Chem. 2008 , 27 ( 6 ), 497 – 511 .
   Web of Science ®Google Scholar
• Anastas , P. T. ; Warner , J. C. Green Chemistry, Theory and Practice ; Oxford University Press : New York , 1998 .
   Google Scholar
• Lancaster , M. Green chemistry . Education in Green Chem., 2000 , 37 , 40 – 46 .
   Google Scholar
• Hoyle , W. ; Lancaster , M. (eds), Clean Technology or the Manufacture of Speciality Chemicals ; Royal Society of Chemistry , 2001 .
   Google Scholar
• Melchert , W. R. ; Rocha , F. R. P. A green analytical procedure for flow-injection determination of nitrate in natural waters . Talanta 2005 , 65 , 461 – 465 .
   PubMed Web of Science ®Google Scholar
• de la Guardia , M. ; Ruzicka , J. Towards environmentally conscientious analytical-chemistry through miniaturization, containment and reagent replacement . Analyst 1995 , 120 ( 2 ), N17 – N17 .
   Google Scholar
• de la Guardia , M. An integrated approach of analytical chemistry . J. Braz. Chem. Soc. 1999 , 10 ( 6 ), 429 – 437 .
   Google Scholar
• Anastas , P. T. Green chemistry and the role of analytical methodology development . Crit. Rev. Anal. Chem. 1999 , 29 , 167 – 175 .
   Web of Science ®Google Scholar
• Lopez-Avila , V. Sample preparation for environmental analysis . Crit. Rev. Anal. Chem. 1999 , 29 , 195 – 230 .
   Web of Science ®Google Scholar
• Namiesnik , J. Trends in environmental analytics and monitoring . Crit. Rev. Anal. Chem. 2000 , 30 , 221 – 269 .
   Web of Science ®Google Scholar
• Keith , L. H. ; Gron , L. U. ; Young , J. L. Green analytical methodologies . Chem. Rev. 2007 , 107 , 2695 – 2708 .
   PubMed Web of Science ®Google Scholar
• He , Y. ; Tang , L. ; Wu , X. ; Hou , X. D. ; Lee , Y. I. Spectroscopy: The best way toward green analytical chemistry? . Appl. Spectrosc. Rev. 2007 , 42 ( 2 ), 119 – 138 .
   Web of Science ®Google Scholar
• Namiesnik , J. Green analytical chemistry-some remarks . J. Sep. Sci. 2001 , 24 , 151 – 153 .
   Web of Science ®Google Scholar
• Morales-Muñoz , S. ; Luque-Garcia , J. L. ; Luque-de-Castro , M. D. Screening method for linear alkylbenzene sulfonates in sediments based on water Soxhlet extraction assisted by focused microwaves with on-line preconcentration/derivatization/detection . J. Chromatogr. A 2004 , 1026 , 41 – 46 .
   PubMedGoogle Scholar
• Priego-Lopez , E. ; Luque-de-Castro , M. D. Superheated water extraction of linear alquilbenzene sulfonates from sediments with on-line preconcentration/derivatization/detection . Anal. Chim. Acta 2004 , 511 , 249 – 254 .
   Google Scholar
• Luque-Garcia , J. L. ; Luque-de-Castro , M. D. Comparison of the static, dynamic and static-dynamic pressurised liquid extraction modes for the removal of nitrated polycyclic aromatic hydrocarbons from soil with on-line filtration-preconcentration . J. Chromatogr. A 2003 , 1010 , 129 – 140 .
   PubMedGoogle Scholar
• Ayano , E. ; Kanazawa , H. Aqueous chromatography system using temperature-responsive polymer-modified stationary phases . J. Sep. Sci. 2006 , 29 , 738 – 749 .
   PubMed Web of Science ®Google Scholar
• He , H. Z. ; Li , H. B. ; Jiang , Y. ; Chen , F. Determination of paralytic shellfish poisoning toxins in cultured microalgae by high-performance liquid chromatography with fluorescence detection . Anal. Bioanal. Chem. 2005 , 383 , 1014 – 1017 .
   PubMedGoogle Scholar
• Bergeron , C. ; Gafner , S. ; Clausen , E. ; Carrier , D. J. Comparison of the chemical composition of extracts from Scutellaria lateriflora using accelerated solvent extraction and supercritical fluid extraction versus standard hot water or 70% ethanol extraction . J. Agric. Food Chem. 2005 , 53 , 3076 – 3080 .
   PubMed Web of Science ®Google Scholar
• Bone , J. R. ; Smith , R. M. Solid phase extraction and thermal desorption of acetophenone and m-cresol using superheated water or steam as the sole eluent . Anal. Commun. 1999 , 36 , 375 – 377 .
   Google Scholar
• Furusawa , N. Clean and rapid liquid chromatographic technique for monitoring of oxytetracycline and sulphadimidine in milk without use of organic solvents . Chromatographia 2003 , 57 , 317 – 320 .
   Google Scholar
• Padron-Sanz , C. ; Sosa-Ferrera , Z. ; Santana-Rodriguez , J. J. An approach to the application of microwave-assisted micellar extraction and liquid chromatography with ultraviolet detection to the extraction and determination of organophosphorus pesticides in tomato samples . J. AOAC Int. 2005 , 88 , 1485 – 1490 .
   PubMed Web of Science ®Google Scholar
• Sun , Y. ; Takaoka , M. ; Takeda , N. ; Matsumoto , T. ; Oshita , K. Application of water as a solvent in microwave-assisted extraction for analysis of PCBs and CBzs in fly ash . J. Sep. Sci. 2005 , 28 , 585 – 588 .
   PubMed Web of Science ®Google Scholar
• Diaz-Reinoso , B. ; Moure , A. ; Dominguez , H. ; Parajo , J. C. Supercritical CO2 extraction and purification of compounds with antioxidant activity . J. Agric. Food Chem. 2006 , 54 , 2441 – 2469 .
   PubMed Web of Science ®Google Scholar
• Zuin , V. G. ; Yariwake , J. H. ; Bicchi , C. Fast supercritical-fluid extraction and high-resolution gas chromatography with electron-capture and flame photometric detection for multiresidue screening of organochlorine and organophosphorus pesticides in Brazil's medicinal plants . J. Chromatogr. A 2003 , 985 , 159 – 166 .
   PubMed Web of Science ®Google Scholar
• Allen , D. L. ; Oliver , J. S. The application of supercritical fluid extraction to cocaine and its metabolites in blood and urine . J. Anal. Toxicol. 2000 , 24 , 228 – 232 .
   PubMed Web of Science ®Google Scholar
• Zhu , L. Y. ; Ee , K. H. ; Zhao , L. M. ; Lee , H. K. Analysis of phenoxy herbicides in bovine milk by means of liquid–liquid–liquid microextraction with a hollow-fiber membrane . J. Chromatogr. A 2002 , 963 , 335 – 343 .
   PubMed Web of Science ®Google Scholar
• Kos , G. ; Ariya , P. A. Determination of a wide range of volatile and semivolatile organic compounds in snow by use of microextraction (SPME) . Anal. Bioanal. Chem. 2006 , 385 , 57 – 66 .
   PubMed Web of Science ®Google Scholar
• Pastor , A. ; Vazquez , E. ; Ciscar , R. ; de la Guardia , M. Efficiency of the microwave-assisted extraction of hydrocarbons and pesticides from sediments . Anal. Chim. Acta 1997 , 344 ( 3 ), 241 – 249 .
   Google Scholar
• Richter , B. E. ; Ezzell , J. L. ; Felix , D. ; Roberts , K. A. ; Later , D. W. Determination of environmental organic compounds in soil . Am. Lab. 1995 , 27 , 24 – 28 .
   Web of Science ®Google Scholar
• Marx , S. ; Everson , R. C. ; Neomagus , H. W. J. P. Organic–organic separation by pervaporation. II. Separation of methanol from tame by an alpha-alumina supported nay-zeolite membrane . Sep. Sci. Technol. 2005 , 40 , 1047 – 1065 .
   Web of Science ®Google Scholar
• Li , X. N. ; Ma , R. Y. ; Su , H. H. ; Sun , H. H. ; Ma , G. H. ; Su , Z. G. ; Zha , S. H. Rapid purification of huperzine A and B with two polystyrene based resins by preparative low-pressure liquid chromatography . J. Liq. Chromatogr. Relat. Technol. 2006 , 29 , 569 – 582 .
   Web of Science ®Google Scholar
• Oliveira , H. M. ; Segundo , M. A. ; Reis , S. ; Lima , J. L. F. C. Multi-syringe flow injection system with in-line preconcentration for the determination of total phenolic compounds. Michrochim. Acta 2005, 150, 187–196.
   Google Scholar
• Mahugo-Santana , C. ; Sosa-Ferrera , Z. ; Santana-Rodriguez , J. J. An environmentally friendly method for the extraction and determination of priority phenols in soils using microwave-assisted micellar extraction . Anal. Bioanal. Chem. 2005 , 382 , 125 – 133 .
   PubMedGoogle Scholar
• Zhang , J. ; Su , T. ; Lee , H. K. Headspace water-based liquid-phase microextraction . Anal. Chem. 2005 , 77 , 1988 – 1992 .
   PubMed Web of Science ®Google Scholar
• Ward , T. L. C. ; Moran , J. W. ; Turner , J. M. ; Coleman , M. R. Validation of a method for the determination of narasin in the edible tissues of chickens by liquid chromatography . J. AOAC Int. 2005 , 88 , 95 – 101 .
   PubMedGoogle Scholar
• Ting , K. C. ; Zhou , E. G. ; Saini , N. Determination of imidacloprid in fruits and vegetables by liquid chromatography with diode array and nitrogen-specific chemiluminescence detection . J. AOAC Int. 2004 , 87 , 997 – 1002 .
   PubMed Web of Science ®Google Scholar
• Zuin , V. G. ; Lopez , A. L. ; Yariwake , J. H. ; Augusto , F. Application of novel sol-gel polydimethylsiloxanepoly(vinyl alcohol) solid-phase microextraction fiber for gas chromatographic determination of pesticide residues in herbal infusions . J. Chromatogr. A 2004 , 1056 , 21 – 26 .
   PubMedGoogle Scholar
• Ozel , M. Z. ; Clifford , A. A. Superheated water extraction of fragrance compounds Rosa canina . Flavour Fragrance J. 2004 , 19 , 354 – 359 .
   Web of Science ®Google Scholar
• Ju , Z. Y. ; Howard , L. R. Effects of solvent and temperature on pressurized liquid extraction of anthocyanins and total phenolics from dried red grape skin . J. Agric. Food Chem. 2003 , 51 , 5207 – 5213 .
   PubMed Web of Science ®Google Scholar
• Armenta , S. ; Garrigues , S. ; de la Guardia , M. Sweeteners determination in table-top formulations using FT Raman spectrometry and chemometric analysis . Anal. Chim. Acta 2004 , 521 , 149 – 155 .
   Web of Science ®Google Scholar
• Quintas , G. ; Garrigues , S. ; de la Guardia , M. FT-Raman spectrometry determination of malathion in pesticide formulations . Talanta 2004 , 63 , 345 – 350 .
   PubMed Web of Science ®Google Scholar
• Furusawa , N. Isolation of tetracyclines in milk using a solid-phase extracting column and water eluent . Talanta 2003 , 59 , 155 – 159 .
   PubMed Web of Science ®Google Scholar
• Lawrence , J. F. ; Niedzwiadek , B. ; Scott , P. M. Effect of temperature and solvent composition on extraction of fumonisins B1 and B2 from corn products . J. AOAC Int. 2000 , 83 , 604 – 611 .
   PubMed Web of Science ®Google Scholar
• Luque-Garcia , J. L. ; Luque-de-Castro , M. D. Static pressurized liquid extraction of nitrated polycyclic aromatic hydrocarbons from soils with online filtration-preconcentration prior to gas chromatography-mass spectrometry detection . Analyst 2003 , 128 , 980 – 985 .
   PubMed Web of Science ®Google Scholar
• Setiowaty , G. ; Man , Y. B. C. A rapid Fourier-transform infra-red spectroscopic method for the determination of 2-TBARS in palm olein . Food Chem. 2003 , 81 , 147 – 154 .
   Google Scholar
• Ellington , E. ; Bastida , J. ; Viladomat , F. ; Codina , C. Supercritical carbon dioxide extraction of colchicines and related alkaloids from seeds of Colchicum autumnale L . Phytochem. Anal. 2003 , 14 , 164 – 169 .
   PubMed Web of Science ®Google Scholar
• Morales-Muñoz , S. ; Luque-Garcia , J. L. ; Luque-de-Castro , M. D. Static extraction with modified pressurized liquid and online fluorescence monitoring. Independent matrix approach for the removal of polycyclic aromatic hydrocarbons from environmental solid samples . J. Chromatogr. A 2002 , 978 , 49 – 57 .
   PubMed Web of Science ®Google Scholar
• Kagan , M. Z. Normal-phase high-performance liquid chromatographic separations using ethoxynonafluorobutane as hexane alternative. I. Analytical and chiral applications . J. Chromatogr. A 2001 , 918 , 293 – 302 .
   Web of Science ®Google Scholar
• New , A. P. ; Freitas-dos-Santos , L. M. ; Lo-Biundo , G. ; Spicq , A. Analytical techniques used for monitoring the biodegradation of fluorinated compounds in waste streams from pharmaceutical production . J. Chromatogr. A 2000 , 889 , 177 – 184 .
   PubMedGoogle Scholar
• Visser , A. E. ; Griffin , S. T. ; Hartman , D. H. ; Rogers , R. D. Naphtol- and resorcinol-based azo dyes as metal ion complexans in aqueous biphasic systems . J. Chromatogr. (B) Biomed. Appl. 2000 , 743 , 107 – 114 .
   PubMed Web of Science ®Google Scholar
• Ichinoki , S. ; Yamazaki , M. ; Ogawa , E. ; Kashihara , M. ; Ishizaki , J. Aliphatic alcohols as components of mobile phase for reversed-phase HPLC . Bunseki Kagaku 1998 , 47 , 591 – 598 .
   Google Scholar
• Smith , R. M. Supercritical-fluid extraction of natural products . LC GC Int. 1996 , 9 , 10 – 15 .
   Google Scholar
• Henner , P. ; Swartz , C. ; Lichtfouse , E. Pasteur-pipette extraction: A fast, convenient, exhaustive and environmentally friendly method for the extraction of solid samples . Analusis 1997 , 25 , 51 – 52 .
   Google Scholar
• Toda , K. Development of miniature key devices for flow analysis and their applications . Bunseki Kagaku 2004 , 53 , 207 – 219 .
   Google Scholar
• Ramos , L. ; Ramos , J. J. ; Brinkman , U. A. T. Miniaturization in sample treatment for environmental analysis . Anal. Bioanal. Chem. 2005 , 381 , 119 – 140 .
   PubMed Web of Science ®Google Scholar
• Escuriola , M. J. ; Morales-Rubio , A. ; de la Guardia , M. A clean analytical method for the spectrophotometric determination of formetanate incorporating an on-line microwave assisted hydrolysis step . Anal. Chim. Acta 1999 , 390 , 147 – 154 .
   Web of Science ®Google Scholar
• de la Guardia , M. ; Khalaf , K. D. ; Carbonell , V. ; Morales-Rubio , A. Clean analytical method for the determination of propoxur . Anal. Chim. Acta 1995 , 308 , 462 – 468 .
   Google Scholar
• Rocha , F. R. P. ; Rodenas-Torralba , E. ; Morales-Rubio , A. ; de la Guardia , M. A clean method for flow injection spectrophotometric determination of cyclamate in table sweeteners . Anal. Chim. Acta 2005 , 547 , 204 – 208 .
   Google Scholar
• Bouhsain , Z. ; Garrigues , S. ; de la Guardia , M. Clean method for the simultaneous determination of propyphenazone and caffeine in pharmaceuticals by flow-injection Fourier transform infrared spectrometry . Analyst 1997 , 122 , 441 – 445 .
   PubMed Web of Science ®Google Scholar
• de la Guardia , M. ; Khalaf , K. D. ; Hasan , B. A. ; Morales-Rubio , A. ; Carbonell , V. In-line titanium dioxide catalysed, ultraviolet mineralization of toxic aromatic compounds in the waste stream from a flow injection based resorcinol analyzer . Analyst 1995 , 120 , 231 – 235 .
   Web of Science ®Google Scholar
• Song , Z. H. ; Hou , S. ; Zhang , N. A new green analytical procedure for monitoring subnanogram amounts of chlorpyrifos on fruits using flow injection chemiluminescence with immobilized reagents . J. Agric. Food Chem. 2002 , 50 , 4468 – 4474 .
   PubMed Web of Science ®Google Scholar
• Armenta , S. ; Moros , J. ; Garrigues , S. ; de la Guardia , M. Automated Fourier transform near infrared determination of buprofezin in pesticide formulation . J. Near Infrared Spectrosc. 2005 , 13 , 161 – 168 .
   Google Scholar
• Rodenas-Torralba , E. ; Morales-Rubio , A. ; de la Guardia , M. Determination of phenols in waters using micro pumped multicommunication and spectrophotometric detection: An automated alternative to the standard procedure . Anal. Bioanal. Chem. 2005 , 383 , 138 – 144 .
   PubMed Web of Science ®Google Scholar
• Moros , J. ; Armenta , S. ; Garrigues , S. ; de la Guardia , M. Near infrared determination of Diuron in pesticide formulation . Anal. Chim. Acta 2005 , 543 , 124 – 129 .
   Web of Science ®Google Scholar
• Rodenas-Torralba , E. ; Reis , B. F. ; Morales-Rubio , A. ; de la Guardia , M. An environmentally friendly multicommutated alternative to the reference method for anionic surfactant determination in water . Talanta 2005 , 66 , 591 – 599 .
   PubMed Web of Science ®Google Scholar
• Goicoechea , H. C. ; Yu , S. J. ; Olivieri , A. C. ; Campiglia , A. D. Four way data coupled to parallel factor model applied to environmental analysis: determination of 2,3,7,8- tetrachloro-dibenzo-para-dioxin in highly contaminated waters by solid–liquid extraction laser excited time resolved Shpol'skii . Anal. Chem. 2005 , 77 , 2608 – 2616 .
   PubMed Web of Science ®Google Scholar
• Yu , S. J. ; Campiglia , A. D. Direct determination of dibenzo[a,l]pyrene and its four dibenzopyrene isomers in water samples by solid liquid extraction and laser excited time resolved Shpol'skii spectrometry . Anal. Chem. 2005 , 77 , 1440 – 1447 .
   PubMed Web of Science ®Google Scholar
• Esteve-Turrillas , F. A. ; Armenta , S. ; Moros , J. ; Garrigues , S. ; Pastor , A. ; de la Guardia , M. Validated non-destructive and environmentally friendly determination of cocaine in euro bank notes . J. Chromatogr. A 2005 , 1065 , 321 – 325 .
   PubMedGoogle Scholar
• Kishida , K. ; Nishinari , K. ; Furusawa , N. Liquid chromatographic determination of sulfamonomethoxine, sulfadimethoxine, and their N4-acetyl metabolities in chicken plasma . Chromatographia 2005 , 61 , 81 – 84 .
   Web of Science ®Google Scholar
• Muñoz , A. H. S. ; Puga , M. P. ; Wrobel , K. ; Sevilla , M. E. G. ; Wrobel , K. Micro assay for malondialdehyde in human serum by extraction-spectrophotometry using an internal standard . Microchim. Acta 2004 , 148 , 285 – 291 .
   Google Scholar
• Quintas , G. ; Morales-Noe , A. ; Armenta , S. ; Garrigues , S. ; de la Guardia , M. Fourier transform infrared spectrometric determination of malathion in pesticide formulations. Anal. Chim. Acta 2004, 502, 213–220.
   Google Scholar
• Ohnsmann , J. ; Quintas , G. ; Garrigues , S. ; de la Guardia , M. Determination of caffeine in tea samples by Fourier transform infrared spectrometry . Anal. Bioanal. Chem. 2002 , 374 , 561 – 565 .
   PubMedGoogle Scholar
• Reis , B. F. ; Morales-Rubio , A. ; de la Guardia , M. Environmentally friendly analytical chemistry through automation: Comparative study of strategies for carbaryl determination with p-aminophenol . Anal. Chim. Acta 1999 , 392 , 265 – 272 .
   Google Scholar
• Jarvenpaa , E. P. ; Taylor , S. L. ; King , J. W. ; Huopalahti , R. The use of supercritical-fluid extraction for the determination of 4-deoxynivalenol in grains: The effect of the sample clean-up and analytical methods on quantitative results . Chromatographia 1997 , 46 , 33 – 39 .
   Web of Science ®Google Scholar
• Settheeworrarit , T. ; Hartwell , S. K. ; Lapanatnoppakhun , S. ; Jakmunee , J. ; Christian , G. D. ; Grudpan , K. Exploiting guava leaf extract as an alternative natural reagent for flow injection determination of iron . Talanta 2005 , 68 , 262 – 267 .
   PubMedGoogle Scholar
• Soylak , M. ; Narin , I. On-line precocentration system for cadmium determination in environmental samples by flame atomic absorption spectrometry . Chem. Anal. 2005 , 50 , 705 – 715 .
   Web of Science ®Google Scholar
• Rodenas-Torralba , E. ; Cava-Montesinos , P. ; Morales-Rubio , A. ; Cervera , M. L. ; de la Guardia , M. Multicommutation as an environmentally friendly analytical tool in the hydride generation atomic fluorescence determination of tellurium in milk . Anal. Bioanal. Chem. 2004 , 379 , 83 – 89 .
   PubMedGoogle Scholar
• Cava-Montesinos , P. ; Rodenas-Torralba , E. ; Morales-Rubio , A. ; Cervera , M. L. ; de la Guardia , M. Cold-vapour atomic-fluorescence determination of mercury in milk by slurry sampling using multicommutation . Anal. Chim. Acta 2004 , 506 , 145 – 153 .
   Web of Science ®Google Scholar
• Thomaidis , N. S. , Georgiou , C. A. Direct parallel flow-injection multichannel spectrophotometric determination of olive oil iodine value . Anal. Chim. Acta 2000 , 405 , 239 – 245 .
   Web of Science ®Google Scholar
• Morales-Muñoz , S. ; Luque-Garcia , J. L. ; Luque-de-Castro , M. D. Pressurized liquid–liquid extraction. An approach to the removal of inorganic non-metal species from used industrial oils . Chemosphere 2004 , 56 , 943 – 947 .
   PubMedGoogle Scholar
• Morales-Muñoz , S. ; Luque-Garcia , J. L. ; Luque-de-Castro , M. D. Demetallization of oils resulting from recycled tires by liquid–liquid extraction using modified superheated water: An environmentally friendly approach . Talanta 2004 , 63 , 391 – 396 .
   PubMedGoogle Scholar
• Cathun , S. ; Velicogna , D. ; Obenauf , A. ; Dumouchel , A. ; Punt , M. ; Brown , C. E. ; Ridal , J. Detoxification of mercury in the environment . Anal. Bioanal. Chem. 2005 , 381 , 1491 – 1498 .
   PubMedGoogle Scholar
• An invited paper submitted to a special issue on Green Spectroscopy and Analytical Techniques, organized by Professor Miguel de la Guardia, of the Department of Chemistry, University of Valencia, Spain, and Professor Arabinda Kumar Das, of the Department of Chemistry, University of Burdwan, West Bengal, India.
   Google Scholar