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Spectroscopy Letters
An International Journal for Rapid Communication
Volume 15, 1982 - Issue 5
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Original Articles

Structure Elucidation with Lanthanide Induced Shifts. 14. Structural Effects on Equilibria between Nitriles and EU(fod)3

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Pages 329-340 | Received 04 Feb 1982, Accepted 01 Mar 1982, Published online: 05 Dec 2006

References

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  • The σ∗ constants for nitriles 1–22 were calculated on the basis of the appropriate contributions from the alkyl groups on the α, β and γ carbons; cf. ref. 20, p. 601. The σ constants for the aromatic nitriles were calculated by considering the contributions from each alkyl group to be additive. Since the cyano group has axial symmetry, an ortho substituent is not expected to alter the interaction between the cyano group and the aromatic ring. Consequently the σ constant for a para methyl was used for both ortho and para substituents.
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