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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 21, 1991 - Issue 8-9
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Original Articles

Dealkoxycarbonylations of Gem Diesters and β-Ketoesters via an Enzyme Catalyzed Hydrolysis

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Pages 1071-1074 | Received 06 Mar 1991, Published online: 23 Sep 2006

References

  • Krapcho , A. P. 1982 . Synthesis , : 805 and references therein, For a review see
  • Tsuji , J. , Nisar , M. and Shimizu , I. 1985 . J. Org. Chem. , 50 : 3416
  • Mandai , T. , Imaji , M. , Takada , H. , Kawata , M. , Nokami , J. and Tsuji , J. 1989 . J. Org. Chem. , 54 : 5395
  • Schneider , M. , Engel , N. and Boensmann , H. 1984 . Angew. Chem. Int. Ed. , 23 : 66
  • Bojörkling , F. , Boutelje , J. , Gatenbeck , S. , Hult , K. , Norin , T. and Szmulik , P. 1985 . Tetrahedron , 41 : 1347
  • Gopalan , A. S. and Jacobs , H. K. 1897 . J. Chem. Soc. Perkin l , For example the compound 1990 3i obrained in this work in 52% yield from diethlmalonate has been obtained only in 43% yield via dealkoxycarbonylation using the Krapcho reaction. See
  • When acid sensitive functionnal groups are present, acidification was performed after addition of the organic solvent to the aqueous solution

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