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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 23, 1993 - Issue 13
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Original Articles

Selective Esterification Reaction Involving Hexaalkyl Guanidinium Chloride Catalyst

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Pages 1835-1842 | Received 08 Feb 1993, Published online: 23 Sep 2006

References

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  • Barcelo , G. , Grenouillat , D. , Senet , J. P. and Sennyey , G. 1990 . Tetrahedron , 46 : 1839
  • Gauthier , P. , Gros , P. , Le Perchec , P. and Senet , J. P. 1992 . Bull. Soc. Chim. Fr. , Submitted for publication in
  • Equimolar quantities of pivaloyl chloride and benzyl alcohol in absence of catalyst have been heated at 120°C and yielded quantitatively benzylpivalate within 20 min.
  • 2-ethyl hexanoyl chloride and 2-ethyl hexanoïc acid (in equimolar amounts) have been reacted at 120°C in the presence or not of PBGSiCl (1%), the reaction was followed by GC during 6H and less than 20% of anhydride were produced.
  • “Handbook of Chemistry and Physics” , 58th Ed. , CRC press .
  • Applequist , D. E. and Kaplan , L. 1965 . J. Am. Chem. Soc. , 87 : 2194

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