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Original Articles

An Improved Method for the Preparation of Trialkylchlorosilanes from Trialkylsilanes Using Cupric Chloride

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Pages 23-26 | Received 21 Jun 1973, Accepted 22 Aug 1973, Published online: 13 Dec 2006

References

  • MacDiarmid , A. G. , ed. 1972 . Organometallic Compounds of the Group IV Elements Vol. 2 , 47ff. New York : Marcel Dekker, Inc. . Ed.,‘’, Part 1, p.
  • Anderson , H. H. 1958 . J. Amer. Chem. Soc. , 80 : 5083
  • Citron , J. D. , Lyons , J. E. and Sommer , L. H. 1969 . J. Org. Chem. , 34 : 638
  • Nametkin , N. S. , Chernyshova , T. I. and Krechetova , K. K. 1963 . Izv. Akad. Nauk SSSR, Ser. Khim. , 12 : 2219
  • Davies , M. 142 Identified by a gas infrared spectrum (, ‘Infra-red Spectroscopy and Molecular Structure’, Elsevier Publishing Co., New York, 1963, p.). The quantity of HCl evolved was determined by back-titration of a sodium hydroxide trap of known base titer. Attempts to determine the amount of HCl (if any) remaining in the acetonitrile phase failed because of the CuCl2 present.
  • Allen , A. D. , Charlton , J. C. , Eaborn , C. and Modena , G. 1957 . J. Chem. Soc. , 3668

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