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Original Articles

Reaction of Phosphorus Chlorides with Ammonium Bicarbonate

Pages 297-309 | Received 18 Jan 1977, Accepted 10 Mar 1977, Published online: 13 Dec 2006

References

  • Van Wazer , J. R. 1958 . Phosphorus and Its Compounds, I. 626 New York, NY : Interscience Publishers, Inc. .
  • 1961 . Ibid. 1098 New York, NY : Interscience Publishers, Inc. . II, pp., 1099.
  • Emsley , J. , Moore , J. and Udy , P. B. 1971 . J. Chem. Soc. (A) , : 2863
  • Ephraim , F. 1954 . Inorganic Chemistry, , 6th Ed. rev. 841 New York, NY : Interscience Publishers, Inc. . P. The decomposition of ammonium bicarbonate to form ammonium carbamate, water and carbon dioxide is known: however, ammonium carbamate is known to decompose to ammonia and carbon dioxide, thus not changing the overall reaction. A test tube experiment showed that ammonium carbamate reacted vigorously with dry phosphorus pentachloride.
  • Van Wazer , J. R. 1958 . Phosphorus and Its Compounds, I. 450 New York, NY : Interscience Publishers, Inc. . pp. and 459.
  • Sansoni , B. 1955 . Angew. Chem. , 67 : 327
  • Roche , J. 1946 . Helv. Chim. Acta. , 29 : 1253
  • Roche , J. , van Thoal , N. and Danzas , E. 1945 . Compt. rend. , 220 : 834

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