Solvothermal syntheses and structures of three clusters based on (1H-benzoimidazol-2-yl)-methanethiol

References

• (a) S. Leininger, B. Olenyuk, P.J. Stang. Chem. Rev., 100, 853 (2000); (b) M. Fujita, K. Umemoto, M. Yoshizawa, N. Fujita, T. Kusukawa, K. Biradha. Chem. Commun., 36, 509 (2001); (c) B.J. Holliday, C.A. Mirkin. Angew. Chem. Int. Ed., 40, 2022 (2001).
   Google Scholar
• Chen , C.L. , Zhang , J.Y. and Eur , C. 2007 . J. Inorg. Chem. , 2007 : 2997
   Web of Science ®Google Scholar
• (a) D. Gatteschi, R. Sessoli. Angew. Chem., Int. Ed., 42, 268 (2003); (b) C.C. Beedle, J.J. Henderson, P.C. Ho, T. Sayles, M. Nakano, J.R. O’Brien, K.J. Heroux, E.D. Barco, M.B. Maple, D.N. Hendrickson. Inorg. Chem., 49, 5780 (2010).
   Google Scholar
• (a) Y.N. Guo, G.F. Xu, P. Gamez, L. Zhao, S.Y. Lin, R.P. Deng, J.K. Tang, H.J. Zhang. J. Am. Chem. Soc., 132, 8538 (2010); (b) J.D. Rinehart, K.R. Meihaus, J.R. Long. J. Am. Chem. Soc., 132, 7572 (2010).
   Google Scholar
• (a) P.N. Bourosh, E.B. Coropceanu, A.P. Rija, O.A. Bologa, M. Gdaniec, I.I. Bulhac. J. Mol. Struct., 998, 198 (2011); (b) M.Y. Wu, W. Wei, Q. Gao, D.Q. Yuan, Y.G. Huang, F.L. Jiang, M.C. Hong. Cryst. Growth Des., 9, 1584 (2009).
   Google Scholar
• (a) H.Q. Yuan, A. Igashira-Kamiyama, K. Tsuge, T. Konno. Chem. Lett., 38, 704 (2009); (b) N. Roy, S. Sproules, E. Bothe, T. Weyhermuller, K. Wieghardt. Eur. J. Inorg. Chem., 2655 (2009); (c) E. Fujiwara, K. Hosoya, A. Kobayashi, H. Tanaka, M. Tokumoto, Y. Okano, H. Fujiwara, H. Kobayashi, Y. Fujishiro, E. Nishibori, M. Takata, M. Sakata. Inorg. Chem., 47, 863 (2008).
   Google Scholar
• (a) J. Zhou, M.J. Scott, Z.G. Hu, G. Peng, E. Munck, R.H. Holm. J. Am. Chem. Soc., 114, 10843 (1992); (b) Z.N. Chen, B.S. Kang, Z.Y. Zhou, W.J. Li, Y.X. Tong, Z.L. Lu, C.Y. Su. Bull. Chem. Soc. Jpn., 71, 1805 (1998); (c) A. Neuba, U. Florke, W. Meyer-Klaucke, M. Salomone-Stagni, E. Bill, E. Bothe, P. Hofer, G. Henkel. Angew. Chem. Int. Ed. Engl., 50, 4503 (2011).
   Google Scholar
• (a) G. Christou, K.S. Hagen, J.K. Bashkin, R.H. Holm. Inorg. Chem., 24, 1010 (1985); (b) G. Christou, K.S. Hagen, R.H. Holm. J. Am. Chem. Soc., 104, 1744 (1982).
   Google Scholar
• M.H. Zeng, M.X. Yao, H. Liang, W.X. Zhang, X.M. Chen. Angew. Chem. Int. Ed., 46, 1832 (2007).
   Google Scholar
• Zhang , S.H. , Ma , L.F. , Zou , H.H. , Wang , Y.G. , Liang , H. and Zeng , M.H. 2011 . Dalton Trans. , 40 : 11402
   PubMed Web of Science ®Google Scholar
• (a) R.A. Reynolds III, W.O. Yu, W.R. Dunham, D. Coucouvanis. Inorg. Chem., 35, 2721 (1996); (b) S.H. Zhang, Y. Song, H. Liang, M.H. Zeng. Cryst. Eng. Comm., 11, 865 (2009); (c) S.H. Zhang, N. Li, C.M. Ge, C. Feng, L.F. Ma. Dalton Trans., 40, 3000 (2011).
   Google Scholar
• Sheldrick , G.M. 2008 . Acta Crystallogr. , A64 : 112
   Web of Science ®Google Scholar
• a can be prepared in the process of synthesizing 3 and green crystals were collected by filtration, washed with ethanol and dried in air, the phase pure a was obtained by manual separation, but the yield is very low. Crystal data for complex a: H12NiO10S, Mr = 262.87 g M−1 Tetragonal, P41212, a = b = 6.8100(5), c = 18.355(3) Å, V = 851.24(15) Å3, θ = 28.20°, λ = 0.71073 Å, μ(Mo Kα) = 2.554 mm−1, 5083 reflections were collected of which 1051 were unique (R int = 0.0177). The structure was solved by direct methods and refined by full-matrix least-squares of F 2, R 1 = 0.0147(I > 2σ(I)), wR 2 = 0.0376 (all data). Max/min residual electron density 0.176 / –0.258 e Å3 and the structure of a see figure S3.
   Google Scholar
• Brown , I.D. 2009 . Chem. Rev. , 109 : 6858
   PubMed Web of Science ®Google Scholar
• T. Ama, M.M. Rashid, T. Yonemura, H. Kawaguchi, T. Yasui, Coord. Chem. Rev. 198, 101 (2000).
   Google Scholar
• (a) Q. Chen, M.H. Zeng, L.Q. Wei, M. Kurmoo. Chem. Mater., 22, 4328 (2010); (b) X.T. Wang, B.W. Wang, Z.M. Wang, W. Zhang, S. Gao. Inorg. Chim. Acta, 361, 3895 (2008); (c) Y.G. Li, Q. Wu, L. Lecren, R. Clerac. J. Mol. Struct., 890, 339 (2008); (d) T.C. Stamatatos, A.K. Boudalis, K.V. Pringouri, C.P. Raptopoulou, A. Terzis, J. Wolowska, E.J.L. McInnes, S.P. Perlepes. Eur. J. Inorg. Chem., 5098 (2007).
   Google Scholar
• (a) C. Canada-Vilalta, W.E. Streib, J.C. Huffmann, T.A. O’Brian, E.R. Davidson, G. Christou. Inorg. Chem., 43, 101 (2004); (b) A.J. Tasiopoulos, T.A. O’Brien, K.A. Abboud, G. Christou. Angew. Chem. Int. Ed. Engl., 43, 345 (2004); (c) S. Mukhopadhyay, W.H. Armstrong. J. Am. Chem. Soc., 125, 13010 (2003); (d) G. Rajaraman, M. Murugesu, E.C. Sanudo, M. Soler, W. Wernsdorfer, M. Helliwell, C. Muryn, J. Raftery, S.J. Teat, G. Christou, E.K. Brechin. J. Am. Chem. Soc., 126, 15445 (2004).
   Google Scholar
• (a) C. Zhang, S. Takada, M. Kolzer, T. Matsumoto, K. Tatsumi. Angew. Chem. Int. Ed. Engl., 45, 3768 (2006); (b) H.L. Xiao, F.F. Jian, K.J. Zhang. Bull. Korean Chem. Soc., 30, 846 (2009); (c) B.W. Sun, X.D. Chen, Z.S. Li, L. Zhang, Q.H. Zhao. New J. Chem., 34, 190 (2010); (d) A. Mustapha, C. Busche, J. Reglinski, A.R. Kennedy. Polyhedron, 30, 1530 (2011); (e) A.N. Georgopoulou, C.P. Raptopoulou, V. Psycharis, R. Ballesteros, B. Abarca, A.K. Boudalis. Inorg. Chem., 48, 3167 (2009); (f) S.T. Zheng, J. Zhang, G.Y. Yang. Angew. Chem. Int. Ed. Engl., 47, 3909 (2008).
   Google Scholar
• (a) M. Martinez-Calvo, M.V. Lopez, R. Pedrido, A.M. Gonzalez-Noya, M.R. Bermejo, E. Monzani, L. Casella, L. Sorace. Chem. - A Eur. J., 16, 14175 (2010); (b) E.V. Govor, A.B. Lysenko, D. Quinonero, E.B. Rusanov, A.N. Chernega, J. Moellmer, R. Staudt, H. Krautscheid, A. Frontera, K.V. Domasevitch. Chem. Commun., 47, 1764 (2011); (c) M. Stricker, T. Linder, B. Oelkers, J. Sundermeyer. Green Chem., 12, 1589 (2010); (d) A.A. Mohamed, S. Ricci, A. Burini, R. Galassi, C. Santini, G.M. Chiarella, D.Y. Melgarejo, J.P. Fackler Jr. Inorg. Chem., 50, 1014 (2011).
   Google Scholar
• (a) T. Ama, Md. M. Rashid, T. Yonemura, H. Kawaguchi, T. Yasui. Coord. Chem. Rev., 198, 101 (2000), and references therein; (b) J. Park, K. Lang, K.A. Abboud, S Hong. J. Am. Chem. Soc., 130, 16484 (2008); (c) B.H. Xu, X.Q. Peng, Z.W. Xu, Y.Z. Li, H. Yan. Inorg. Chem., 47, 7928 (2008); (d) T.V. Mitkina, N.F. Zakharchuk, D.Y. Naumov, O.A. Gerasko, D. Fenske, V.P. Fedin. Inorg. Chem., 47, 6748 (2008).
   Google Scholar
• (a) R. Spezia, C. Bresson, C.D. Auwer, M.P. Gaigeot. J. Phys. Chem. B, 112, 6490 (2008); (b) W. Galezowski, J. Kuta, P.M. Kozlowski. J. Phys. Chem. B, 112, 3177 (2008); (c) S.K. Gupta, P.B. Hitchcock, Y.S. Kushwah, G.S. Argal. Inorg. Chim. Acta, 360, 2145 (2007); (d) A.A. Khander, B. Shaabani, F. Belaj, A. Bakhtiari. Polyhedron, 25, 1893 (2006), and references therein.
   Google Scholar
• Brown , I.D. and Altermatt , D. 1985 . Acta Crystallogr. , B41 : 244
   Web of Science ®Google Scholar
• Zhang , Y.Z. , Wernsdorfer , W. , Pan , F. , Wang , Z.M. and Gao , S. 2006 . Chem. Commun. , 46 : 3302
   Web of Science ®Google Scholar
• Milios , J. , Prescimone , A. , Sanchez-Benitez , J. , Parsons , S. , Murrie , M. and Brechin , E.K. 2006 . Inorg. Chem. , 45 : 7053
   PubMed Web of Science ®Google Scholar
• Zhang , S.H. , Tang , M.F. and Ge , C.M. 2009 . Z. Anorg. Allg. Chem. , 635 : 1442
   Web of Science ®Google Scholar
• Brese , N.E. and O’Keeffe , M. 1991 . Acta Crystallogr. , B47 : 192
   Web of Science ®Google Scholar